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larger decrease » marked decrease (Expand Search)
linear decrease » linear increase (Expand Search)
large decrease » marked decrease (Expand Search), large increases (Expand Search), large degree (Expand Search)
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981
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984
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986
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987
Large Effects of Ion Pairing and Protonic−Hydridic Bonding on the Stereochemistry and Basicity of Crown-, Azacrown-, and Cryptand-222-potassium Salts of Anionic Tetrahydride Comple...
Published 2002“…The [K(cryptand)]<sup>+</sup> salt of [<i>trans-</i>IrH<sub>4</sub>(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub>]<sup>-</sup> reacts with WH<sub>6</sub>(PMe<sub>2</sub>Ph)<sub>3</sub> (p<i>K</i><sub>α</sub><sup>THF</sup> 42) to give an equilibrium (<i>K</i><sub>eq</sub> = 1.6) with IrH<sub>5</sub>(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> and [WH<sub>5</sub>(PMe<sub>2</sub>Ph)<sub>3</sub>]<sup>-</sup> while the same reaction of WH<sub>6</sub>(PMe<sub>2</sub>Ph)<sub>3</sub> with the [K(18-crown-6)]<sup>+</sup> salt of [<i>cis-</i>IrH<sub>4</sub>(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub>]<sup>-</sup> has a much larger equilibrium constant (<i>K</i><sub>eq</sub> = 150) to give IrH<sub>5</sub>(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> and [WH<sub>5</sub>(PMe<sub>2</sub>Ph)<sub>3</sub>]<sup>-</sup>; therefore, the tetrahydride anion displays an unprecedented increase (about 100-fold) in basicity with a change from [K(crypt)]<sup>+</sup> to [K(crown)]<sup>+</sup> countercation and a change from <i>trans</i> to <i>cis</i> stereochemistry. …”
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988
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989
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990
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991
Average sensitivity to social influence 〈<i>S</i>〉 against (a) the number of shared estimates <i>τ</i> and (b) the average dispersion of estimates received 〈<i>σ</i>〉, in the Rando...
Published 2021“…This is due to the similarity effect, as shown in (b): a linear decrease of 〈<i>S</i>〉 with 〈<i>σ</i>〉 when <i>τ</i> > 1. …”
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992
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993
Threading Behavior and Dynamics of Ring-Linear Polymer Blends under Poiseuille Flow
Published 2024“…When the flow field strength exceeds this critical value, ring-linear polymer blends will aggregate into a cluster due to the combination of entanglement between polymers and the large differences in the velocities of the polymers. …”
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994
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995
CsA reduces Flk1 protein expression and significantly decreases the percentages of Flk1+ cells.
Published 2015“…(C) Representative flow cytometry profiles showing the decreased percentages of Flk1+ cells in P19 cells treated with 0.32 μM CsA during EB formation for 48 and 96 h, respectively. …”
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996
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997
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998
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999
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1000