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point decrease » point increase (Expand Search)
we decrease » _ decrease (Expand Search), nn decrease (Expand Search), teer decrease (Expand Search)
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Electronic and Electrochemical Control of Isostructural Ruthenium Hydricities and the Implications for Catalytic Overpotentials
Published 2024“…The rate constants for hydride transfer and protonation of the catalyst were, in some cases, extracted from the analysis of cyclic voltammetry data. A key finding is a 400 mV decrease in the catalytic overpotential for H<sub>2</sub> production by using a doubly reduced electron-poor metal hydride instead of a singly reduced electron-rich metal hydride. …”
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