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nn decrease » _ decrease (Expand Search), mean decrease (Expand Search), gy decreased (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
a step » _ step (Expand Search)
step decrease » sizes decrease (Expand Search), teer decrease (Expand Search)
we decrease » _ decrease (Expand Search), mean decrease (Expand Search), teer decrease (Expand Search)
nn decrease » _ decrease (Expand Search), mean decrease (Expand Search), gy decreased (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
a step » _ step (Expand Search)
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Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster
Published 2016“…On the basis of kinetic data, Δ<i>H</i><sup>⧧</sup>, Δ<i>S</i><sup>⧧</sup>, and Δ<i>G</i><sup>⧧</sup> of the additions were determined, showing a 4 order-of-magnitude decrease in reactivity from the hydroxyguanidine to the aromatic ketoxime as entering nucleophiles. …”
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570
Nucleophilicity of Oximes Based upon Addition to a Nitrilium <i>closo</i>-Decaborate Cluster
Published 2016“…On the basis of kinetic data, Δ<i>H</i><sup>⧧</sup>, Δ<i>S</i><sup>⧧</sup>, and Δ<i>G</i><sup>⧧</sup> of the additions were determined, showing a 4 order-of-magnitude decrease in reactivity from the hydroxyguanidine to the aromatic ketoxime as entering nucleophiles. …”
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571
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572
Ab Initio Prediction of Proton Exchange Barriers for Alkanes at Brønsted Sites of Zeolite H‑MFI
Published 2018“…A change to the indirect proton exchange mechanism, in which a hydride ion is transferred between the alkane and a <i>tert</i>-butyl carbenium ion can be excluded, because we confirm previous findings that the barrier for dehydrogenation that would create a <i>tert</i>-butyl cation from <i>i</i>-butane is much too high, 188 and 132 kJ/mol for the intrinsic and apparent enthalpy barriers, respectively, at 500 K. …”
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573
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577
Elementary Steps in Olefin Metathesis: Nickelacyclobutanes via Cycloaddition to Nickel Carbenes
Published 2025“…This is the sole example to date of an obervable NiCB generated via cycloaddition, beyond the fluorinated examples. Computations pinpoint a decreased energy barrier to cycloreversion, relative to reductive elimination or β-H elimination, as the core requirement to achieve metathesis. …”
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578
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