Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir by Rajshekhar Ghosh (1812388)

“…C−C elimination from complexes with the common d⁶ six-coordinate configuration generally proceeds via prior ligand loss, which greatly complicates any attempt to directly measure the rates of the specific elimination step. We report the synthesis of a series of five-coordinate d⁶ iridium complexes, (^tBuPCP)Ir(R)(R′), where R and R′ are Me, Ph, and (phenyl-substituted) vinyl and alkynyl groups. …”

Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir by Rajshekhar Ghosh (1812388)

“…C−C elimination from complexes with the common d⁶ six-coordinate configuration generally proceeds via prior ligand loss, which greatly complicates any attempt to directly measure the rates of the specific elimination step. We report the synthesis of a series of five-coordinate d⁶ iridium complexes, (^tBuPCP)Ir(R)(R′), where R and R′ are Me, Ph, and (phenyl-substituted) vinyl and alkynyl groups. …”

Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir by Rajshekhar Ghosh (1812388)

“…C−C elimination from complexes with the common d⁶ six-coordinate configuration generally proceeds via prior ligand loss, which greatly complicates any attempt to directly measure the rates of the specific elimination step. We report the synthesis of a series of five-coordinate d⁶ iridium complexes, (^tBuPCP)Ir(R)(R′), where R and R′ are Me, Ph, and (phenyl-substituted) vinyl and alkynyl groups. …”

Combined Experimental and Computational Studies on Carbon−Carbon Reductive Elimination from Bis(hydrocarbyl) Complexes of (PCP)Ir by Rajshekhar Ghosh (1812388)

“…C−C elimination from complexes with the common d⁶ six-coordinate configuration generally proceeds via prior ligand loss, which greatly complicates any attempt to directly measure the rates of the specific elimination step. We report the synthesis of a series of five-coordinate d⁶ iridium complexes, (^tBuPCP)Ir(R)(R′), where R and R′ are Me, Ph, and (phenyl-substituted) vinyl and alkynyl groups. …”

DataSheet_1_Climate drivers of Southern Ocean phytoplankton community composition and potential impacts on higher trophic levels.pdf by Kristen M. Krumhardt (13233483)

“…Guided by a large ensemble of Earth system model simulations run under a high emission scenario (RCP8.5), we present hypotheses for how anthropogenic climate change may drive shifts in phytoplankton community structure in two regions of the Southern Ocean: the Antarctic Circumpolar Current (ACC) region and the sea ice zone (SIZ). …”

<i>raw</i> and <i>acal</i> act together to counteract JNK signaling. by Luis Daniel Ríos-Barrera (695330)

“…Arrow in (E) points to decreased <i>acal</i> expression in the lateral epidermis. …”

Supplementary Material for: Effect of Conventional Medical Therapy or Laparoscopic Sleeve Gastrectomy on Urinary Albumin in Japanese Subjects with Severe Obesity: An Observational... by Watanabe Y. (4129684)

Data_Sheet_1_New Insights Into the Relationship Between Drought and Mental Health Emerging From the Australian Rural Mental Health Study.docx by Tuyen T. Luong (11369262)

“…These effects were maintained after controlling for demographic, social, and environmental factors. We also found that while psychological distress decreases in the later stages of drought, this does not necessarily mean people have good mental health because, for example, factors such as life satisfaction decreased as drought persisted. …”

Data_Sheet_1_New Insights Into the Relationship Between Drought and Mental Health Emerging From the Australian Rural Mental Health Study.docx by Tuyen T. Luong (11369262)

“…These effects were maintained after controlling for demographic, social, and environmental factors. We also found that while psychological distress decreases in the later stages of drought, this does not necessarily mean people have good mental health because, for example, factors such as life satisfaction decreased as drought persisted. …”

The multimerization of <i>D4Z4</i> abrogates CTCF binding and insulation activity. by Alexandre Ottaviani (249884)

“…The binding of CTCF was investigated by ChIP on the different populations of cells carrying different number of <i>D4Z4</i> element downstream of the <i>eGFP</i> reporter gene. Input DNA and DNA fraction immunoprecipitated with antibodies to CTCF were amplified by a real-time Q-PCR method (<i>x</i>-axis) using primers encompassing the 5′ CTCF site. …”

Time evolution of parallel (left) and anti-parallel (right) Phe-Nap-ⁱPr arylamide conformations. by Jonathan C. Fuller (141611)

“…<p>a) the number of intermolecular pairs of atoms between <i>h</i>DM2 and the ligand that are within 3.5 Å for parallel conformations; b) the number of intermolecular pairs of atoms between <i>h</i>DM2 and the ligand that are within 3.5 Å for anti-parallel conformations; c) difference in protein-arylamide center of mass distance (Å) from a minimized parallel starting conformation; and d) difference in protein-arylamide center of mass distance (Å) from a minimized anti-parallel starting conformation. …”

Data_Sheet_1_Are there effects of light exposure on daytime sleep for rotating shift nurses after night shift?: an EEG power analysis.docx by Soonhyun Yook (10769833)

“…We also observed that light exposure during daytime sleep could additionally decrease N2 sleep spindle activity and N3 waves in the last sleep cycle.…”

Sustainable mobility at the EU level – in the new transport white paper by Tamas Fleischer (409919)

“…Funded by the European Commission in FP7. Szentendre, Hungary, 5/6 May 2011</p> <p>The main message of the contribution in four points:</p> <p>(1) The environmental targets for 2050 (sixty percent emission decrease, oil dependence decrease) are based on a very progressive vision, clear target.…”

Examples demonstrating instances where the minimum number of mt protein-coding (PC) genes is either apparent or ambiguous. by Justin C. Havird (507301)

“…In these cases, the minimum number of genes that statistically recreated the “supergene” topology was chosen (e.g., a single gene, NAD5, for Haplorrhini). This alternative trend was atypical of the data (6.5% and 7.0% of lineages when utilizing amino acid and nucleotide data, respectively). …”

Global divergent responses of soil heterotrophic respiration to nitrogen deposition by Peng Guo (13816147)

“…Δ<i>R</i>_H significantly increased in alkaline soils (pH > 7.5) but decreased in acidic soils (pH < 5.5). Furthermore, Δ<i>R</i>_H significantly increased in soils with high total organic carbon (TOC > 15 g/kg) or low available N contents (NH4+ < 19 mg/kg or NO3− < 15 mg/kg), but decreased in soils with high total N (TN > 11 g/kg). …”

Endogenous BDNF and TrkB levels in retina and SC at various time points after ONC. by Eline Dekeyster (825249)

“…<p>(A) In the retina, the total BDNF levels, analyzed via ELISA, rise upon ONC, reaching a peak at 3 to 5 d, attenuating afterwards. …”

Smooth muscle differentiation and Notch target genes are down regulated in Notch2 and Notch2/Notch3 double mutants. by Qingqing Wang (141110)

“…Notch signaling target gene Heyl shows a robust decrease at E10.5 and E11.5 in the <i>Notch2^−/− (N2^−/−;N3^+/+)</i> and <i>Notch2^−/−;Notch3^−/− (N2^−/−;N3^−/−)</i> yolk sacs, while Hey2 shows a slight decrease and Hes1 expression is unaffected in the mutant genotypes. …”

Effect of RNAi depletion of selected hits on lipid droplet formation and TOR pathway activation. by Vangelis Kondylis (229490)

“…Red and blue columns indicate proteins whose depletion leads to a significant decrease or increase in the number of lipid droplets (marked with double asterisk; p<0.05). …”

Lack of oligodendrocytes after DTA-mediated ablation of <i>C1ql1</i>-expressing OPCs. by Shayan Moghimyfiroozabad (19066182)

“…Scale bars = 100 μm. Quantification shows a massive decrease in OL density in the <i>C1ql1</i>^<i>pos</i> OPC-ablated brains. …”

Cytoprotective gene regulation is essential to lifespan extension by diverse mechanisms. by David E. Shore (123998)

“…Lifespan was measured in three replicates comprising an average of 103 worms per condition. Data is presented as mean lifespan (columns 1–4), change mean lifespan in comparison to an empty vector RNAi control (column 5), or as the change in the extension of lifespan induced by each long-lived mutant (columns 6–8; for clarity, only decreases >15% are shown). …”