Side-Chain Engineering for Modulating the Mechanical and Thermosalient Behavior of Elastic Crystals of Triple-Helix Coordination Polymers by Shu-Wen An (7450172)

“…Potential energy surface analysis and variable-temperature single-crystal X-ray diffraction analysis are used to figure out the effect of side-chain groups on their mechanically responsive and thermosalient properties, which demonstrate that the regulation of side-chain groups from <b>phen</b> to <b>bpy</b> and then to <b>dmbpy</b> in these triple-helix CPs can lead to a gradual decrease in interchain π–π interactions but an increase in the steric hindrance and subsequently exert a significant influence on the apparent mechanical properties and thermosalient behaviors.…”

Side-Chain Engineering for Modulating the Mechanical and Thermosalient Behavior of Elastic Crystals of Triple-Helix Coordination Polymers by Shu-Wen An (7450172)

“…Potential energy surface analysis and variable-temperature single-crystal X-ray diffraction analysis are used to figure out the effect of side-chain groups on their mechanically responsive and thermosalient properties, which demonstrate that the regulation of side-chain groups from <b>phen</b> to <b>bpy</b> and then to <b>dmbpy</b> in these triple-helix CPs can lead to a gradual decrease in interchain π–π interactions but an increase in the steric hindrance and subsequently exert a significant influence on the apparent mechanical properties and thermosalient behaviors.…”

Side-Chain Engineering for Modulating the Mechanical and Thermosalient Behavior of Elastic Crystals of Triple-Helix Coordination Polymers by Shu-Wen An (7450172)

“…Potential energy surface analysis and variable-temperature single-crystal X-ray diffraction analysis are used to figure out the effect of side-chain groups on their mechanically responsive and thermosalient properties, which demonstrate that the regulation of side-chain groups from <b>phen</b> to <b>bpy</b> and then to <b>dmbpy</b> in these triple-helix CPs can lead to a gradual decrease in interchain π–π interactions but an increase in the steric hindrance and subsequently exert a significant influence on the apparent mechanical properties and thermosalient behaviors.…”

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Fig 4 - by Farshid Maleki (20521649)

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