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    Impact of Carbene Ligands on the Properties and Reactivity of Diazoboranes by Chonghe Zhang (10798948)

    Published 2025
    “…The results demonstrate that increasing carbene π-acidity weakens the B–N bond while strengthening the N–N bond, significantly decreasing thermal stability. Kinetic studies reveal that less π-acidic carbenes promote a second-order decay mechanism, leading to dibora-azine formation, whereas more π-acidic carbenes favor first-order dinitrogen dissociation, facilitating borylene generation. …”
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