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    Deciphering the Role of Internal Donors in Shaping Heterogeneous Ziegler–Natta Catalysts Based on Nonempirical Structural Determination by João Marcos da Silveira (17871851)

    Published 2024
    “…The addition of internal donors (IDs) to the heterogeneous Ziegler–Natta catalyst for propylene polymerization is fundamental to obtain highly isotactic polypropylene, but its role in shaping the stereospecific structure of the catalyst is still not comprehended. …”