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    Reversible Adsorption and Interfacial Photoisomerization of Azobenzene Surfactants Studied by QCM by Maren Umlandt (9638121)

    Published 2025
    “…Using quartz crystal microbalance (QCM) measurements, we show that the interfacial mass change is governed by the isomeric composition in the bulk solution: the <i>trans</i> isomer exhibits strong adsorption, while the <i>cis</i> isomer is significantly less surface-active. We further quantify the photoisomerization kinetics at the interface, revealing that the isomerization rate constant decreases with a lower <i>trans</i> isomer concentration due to a transition from a diffuse multilayer to a confined double-layer structure. …”
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