Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

The Role of Neutral Coligands on the Stabilization of Mono-Tp^{^<i>i</i>Pr}_² U(III) Complexes by Leonor Maria (1527661)

“…The other complexes (<b>1</b>, <b>4</b>, and <b>5</b>) are fluxional, but the dynamic processes involved can be slowed by decreasing the temperature.…”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Anterior Ischemic VSD Repair After Failed Percutaneous Device Closure by Rishav Aggarwal (14191566)

“…</p> <p>The patient’s postoperative course was uncomplicated, and she was discharged home on day six from her operation. A transthoracic echocardiogram showed a trace residual shunt near the apical portion of the repair. …”

Transition Metal Substitution Effects on Metal-to-Polyoxometalate Charge Transfer by Elliot N. Glass (1648816)

“…A series of hetero-bimetallic transition metal-substituted polyoxometalates (TMSPs) were synthesized based on the Co^II-centered ligand [Co^IIW₁₁O₃₉]^10–. …”

SGS-LTER Disturbance intensity and above- and belowground herbivory effects on long-term recovery of shortgrass steppe on the Central Plains Experimental Range, Nunn, Colorado, USA... by William Lauenroth (17483292)

Image_1_GADD45B regulates the carcinogenesis process of chronic atrophic gastritis and the metabolic pathways of gastric cancer.tif by Wei Xu (28953)

“…</p>Conclusion<p>GADD45B, an oncogene implicated in chronic atrophic gastritis, played a critical role in GC development. Decreased expression of GADD45B was associated with the onset of GC. …”

Table_1_GADD45B regulates the carcinogenesis process of chronic atrophic gastritis and the metabolic pathways of gastric cancer.docx by Wei Xu (28953)

“…</p>Conclusion<p>GADD45B, an oncogene implicated in chronic atrophic gastritis, played a critical role in GC development. Decreased expression of GADD45B was associated with the onset of GC. …”

Table_2_GADD45B regulates the carcinogenesis process of chronic atrophic gastritis and the metabolic pathways of gastric cancer.docx by Wei Xu (28953)

“…</p>Conclusion<p>GADD45B, an oncogene implicated in chronic atrophic gastritis, played a critical role in GC development. Decreased expression of GADD45B was associated with the onset of GC. …”