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a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
largest decrease » largest decreases (Expand Search), marked decrease (Expand Search)
larger decrease » marked decrease (Expand Search)
nn decrease » _ decrease (Expand Search), mean decrease (Expand Search), gy decreased (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
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15701
Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets
Published 2006“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm<sup>-1</sup>). …”
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15702
The Role of Neutral Coligands on the Stabilization of Mono-Tp<sup><sup><i>i</i></sup>Pr</sup><sub><sup>2</sup></sub> U(III) Complexes
Published 2004“…The other complexes (<b>1</b>, <b>4</b>, and <b>5</b>) are fluxional, but the dynamic processes involved can be slowed by decreasing the temperature.…”
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15703
Single-center retrospective study of the effectiveness and toxicity of the oral iron chelating drugs deferiprone and deferasirox
Published 2019“…During deferiprone exposure, new diabetes mellitus, a recognized consequence of inadequate iron control, was diagnosed in 17% patients, most of whom had sustained HICs exceeding 15 mg/g for years; one woman died after 13 months of a regimen of deferiprone and low-dose deferasirox. …”
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15704
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15705
Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets
Published 2006“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm<sup>-1</sup>). …”
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15706
Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets
Published 2006“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm<sup>-1</sup>). …”
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15707
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15708
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15709
DataSheet_1_Evidence on Efficacy and Safety of Chinese Medicines Combined Western Medicines Treatment for Breast Cancer With Endocrine Therapy.docx
Published 2021“…Background<p>Breast cancer, a malignant disorder, occurs in epithelial tissue of the breast glands and ducts. …”
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15710
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15711
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15712
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15713
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15714
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15715
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15716
Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets
Published 2006“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm<sup>-1</sup>). …”
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15717
Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets
Published 2006“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm<sup>-1</sup>). …”
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15718
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15719
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15720
Anterior Ischemic VSD Repair After Failed Percutaneous Device Closure
Published 2022“…</p> <p>The patient’s postoperative course was uncomplicated, and she was discharged home on day six from her operation. A transthoracic echocardiogram showed a trace residual shunt near the apical portion of the repair. …”