Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets by En-Che Yang (2092804)

“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm^-1). …”

Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets by En-Che Yang (2092804)

“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm^-1). …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Synthesis of Selected Cationic Pnictanes [L_<i>n</i>PnX_3–<i>n</i>]^<i>n</i>+ (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React... by F. D. Henne (1565356)

“…In the case of the 1:1 reaction of [L^(R/R′)SiMe₃]­[OTf] with PCl₃ the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L^(R/R′)PCl₂]⁺ (<b>1</b>_P^(R/R′))^<b>+</b> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L^(R/R′)SiMe₃]­[OTf] and PnCl₃ are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”

Anterior Ischemic VSD Repair After Failed Percutaneous Device Closure by Rishav Aggarwal (14191566)

“…</p> <p>The patient’s postoperative course was uncomplicated, and she was discharged home on day six from her operation. A transthoracic echocardiogram showed a trace residual shunt near the apical portion of the repair. …”

A Randomised Placebo-Controlled Trial of a Traditional Chinese Herbal Formula in the Treatment of Primary Dysmenorrhoea by Lan Lan Liang Yeh (33527)

“…Participants were followed with two to four cycles for an initial washout interval, one to two baseline cycles, three to four treatment cycles, and three follow-up cycles. …”

Transition Metal Substitution Effects on Metal-to-Polyoxometalate Charge Transfer by Elliot N. Glass (1648816)

“…A series of hetero-bimetallic transition metal-substituted polyoxometalates (TMSPs) were synthesized based on the Co^II-centered ligand [Co^IIW₁₁O₃₉]^10–. …”

Image_1_GADD45B regulates the carcinogenesis process of chronic atrophic gastritis and the metabolic pathways of gastric cancer.tif by Wei Xu (28953)

“…</p>Conclusion<p>GADD45B, an oncogene implicated in chronic atrophic gastritis, played a critical role in GC development. Decreased expression of GADD45B was associated with the onset of GC. …”

Table_1_GADD45B regulates the carcinogenesis process of chronic atrophic gastritis and the metabolic pathways of gastric cancer.docx by Wei Xu (28953)

“…</p>Conclusion<p>GADD45B, an oncogene implicated in chronic atrophic gastritis, played a critical role in GC development. Decreased expression of GADD45B was associated with the onset of GC. …”

Table_2_GADD45B regulates the carcinogenesis process of chronic atrophic gastritis and the metabolic pathways of gastric cancer.docx by Wei Xu (28953)

“…</p>Conclusion<p>GADD45B, an oncogene implicated in chronic atrophic gastritis, played a critical role in GC development. Decreased expression of GADD45B was associated with the onset of GC. …”

Image_2_GADD45B regulates the carcinogenesis process of chronic atrophic gastritis and the metabolic pathways of gastric cancer.pdf by Wei Xu (28953)

“…</p>Conclusion<p>GADD45B, an oncogene implicated in chronic atrophic gastritis, played a critical role in GC development. Decreased expression of GADD45B was associated with the onset of GC. …”

SGS-LTER Disturbance intensity and above- and belowground herbivory effects on long-term recovery of shortgrass steppe on the Central Plains Experimental Range, Nunn, Colorado, USA... by William Lauenroth (17483292)

DataSheet_1_Sex-specific differences in immunogenomic features of response to immune checkpoint blockade.pdf by Susan C. Scott (13191618)

Data_Sheet_1_Modulation of Dorsolateral Prefrontal Cortex Glutamate/Glutamine Levels Following Repetitive Transcranial Magnetic Stimulation in Young Adults With Autism.pdf by Iska Moxon-Emre (11527411)

“…MRS scans were acquired before and after participants with ASD were randomized to receive a 20-session course of active or sham rTMS to the DLPFC. …”

Table_1_Sex-specific differences in immunogenomic features of response to immune checkpoint blockade.xlsx by Susan C. Scott (13191618)

Overexpression of Survivin does not significantly protect radiations-induced apoptosis, but does protect apoptosis under other stresses. by Masato Hori (280003)

“…<p><b>A.</b> Frequency of apoptosis in CHE cells (with p53+/+ and p53−/−) transfected with pEGFP-empty and pEGFP-Survivin after treatment with X-irradiation (10 Gy) and UV-C (10 J/m²). …”