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largest decrease » largest decreases (Expand Search), marked decrease (Expand Search)
larger decrease » marked decrease (Expand Search)
step decrease » sizes decrease (Expand Search), teer decrease (Expand Search), we decrease (Expand Search)
a decrease » _ decrease (Expand Search), _ decreased (Expand Search), _ decreases (Expand Search)
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15741
Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets
Published 2006“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm<sup>-1</sup>). …”
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15742
Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets
Published 2006“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm<sup>-1</sup>). …”
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15743
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15744
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15745
DataSheet_1_Evidence on Efficacy and Safety of Chinese Medicines Combined Western Medicines Treatment for Breast Cancer With Endocrine Therapy.docx
Published 2021“…Background<p>Breast cancer, a malignant disorder, occurs in epithelial tissue of the breast glands and ducts. …”
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15746
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15747
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15748
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15749
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15750
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15751
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15752
Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets
Published 2006“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm<sup>-1</sup>). …”
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15753
Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets
Published 2006“…All six complexes were characterized by dc magnetic susceptibility data to be ferromagnetically coupled to give an <i>S</i> = 4 ground state with significant magnetoanisotropy (<i>D</i> ≈ −0.6 cm<sup>-1</sup>). …”
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15754
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15755
Synthesis of Selected Cationic Pnictanes [L<sub><i>n</i></sub>PnX<sub>3–<i>n</i></sub>]<sup><i>n</i>+</sup> (L = Imidazolium-2-yl; Pn = P, As; <i>n</i> = 1–3) and Replacement React...
Published 2015“…In the case of the 1:1 reaction of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] with PCl<sub>3</sub> the corresponding cationic imidazoliumyl-substituted dichlorophosphanes [L<sup>(R/R′)</sup>PCl<sub>2</sub>]<sup>+</sup> (<b>1</b><sub>P</sub><sup>(R/R′)</sup>)<sup><b>+</b></sup> are obtained as triflate salts on a multigram scale. We found that the reactions using various stoichiometries of [L<sup>(R/R′)</sup>SiMe<sub>3</sub>][OTf] and PnCl<sub>3</sub> are less selective in the case of the heavier congeners or by decreasing steric demand of the R-group attached to the N atoms of the heterocycle. …”
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15756
Anterior Ischemic VSD Repair After Failed Percutaneous Device Closure
Published 2022“…</p> <p>The patient’s postoperative course was uncomplicated, and she was discharged home on day six from her operation. A transthoracic echocardiogram showed a trace residual shunt near the apical portion of the repair. …”
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15757
Transition Metal Substitution Effects on Metal-to-Polyoxometalate Charge Transfer
Published 2016“…A series of hetero-bimetallic transition metal-substituted polyoxometalates (TMSPs) were synthesized based on the Co<sup>II</sup>-centered ligand [Co<sup>II</sup>W<sub>11</sub>O<sub>39</sub>]<sup>10–</sup>. …”
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15758
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15759
Image_1_GADD45B regulates the carcinogenesis process of chronic atrophic gastritis and the metabolic pathways of gastric cancer.tif
Published 2023“…</p>Conclusion<p>GADD45B, an oncogene implicated in chronic atrophic gastritis, played a critical role in GC development. Decreased expression of GADD45B was associated with the onset of GC. …”
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15760
Table_1_GADD45B regulates the carcinogenesis process of chronic atrophic gastritis and the metabolic pathways of gastric cancer.docx
Published 2023“…</p>Conclusion<p>GADD45B, an oncogene implicated in chronic atrophic gastritis, played a critical role in GC development. Decreased expression of GADD45B was associated with the onset of GC. …”