Unusual [Pt{κ²(<i>C</i>,<i>N</i>)}]⁺ → [Pt{κ²(<i>N</i>,<i>N</i>)}]⁺ Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... by Rishabh Ujjval (9454247)

“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ²(<i>C</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ²(<i>N</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>16</b>′), is a kinetically controlled product.…”

Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) by Thomas Gernon (11046150)

“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”

17- and 19-Electron Complexes [Fe^III(η⁵-C₅R₅)(S₂CNMe₂)L]^<i>n</i>+ (<i>n</i> = 1, 0):  Electronic Struct... by Marie-Hélène Delville-Desbois (2995521)

“…The cyclic voltammogram of <b>9⁺PF₆^-</b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9⁺PF₆^-</b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b>^+/<b>0</b>/-, <b>9‘</b>^+/<b>0</b>/-, and solvent (DMF) adducts in 18- and 19e states.…”

Loughborough University East Midlands campus meteorological data, 2008-2021 by Richard Hodgkins (1254879)

“…The paddock is otherwise mostly open on an arc from the northwest to the northeast, but on the other sides there are fruit trees (mainly varieties of <i>prunus domestica</i>) at distances of 13–16 m, forming part of the university's "Fruit Routes" biodiversity initiative.…”