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Two-Step Chemical Recycling of Tire Rubber to Isoprene
Published 2025“…Here, we report a two-step chemical recycling method for tire rubber. This method involves cyclodepolymerization (CDP) through the successive ring-closing metathesis of isoprene rubber (reinforced by sulfur cross-linking and a carbon black (CB) filler) and pyrolytic process of the oligomer/polymer into monomeric isoprene. …”
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322
Supplementary information files for "Lego-microfluidics generated magnetically responsive bifunctional microcapsules with encapsulated phase change material"
Published 2025“…Iron (II, III) oxide (Fe<sub>3</sub>O<sub>4</sub>) nanoparticle-embedded microcapsules encapsulating hexadecane (HD) are synthesized without external heating or cooling in just ~80 s. The process involves forming oil-in-oil-in-water (O/O/W) double emulsion droplets with Norland Optical Adhesive (NOA) photopolymeric shell and consolidating them through on-the-fly shell polymerization using thiol-ene “click” chemistry. …”
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323
Revealing the Ultrafast Energy Transfer Pathways in Energetic Materials: Time-Dependent and Quantum State-Resolved
Published 2024“…Intramolecular vibrational energy transfer is gaining tremendous attention as a regulator of condensed-phase behavior and reactions. In polyatomic molecules, this transfer is an ultrafast process involving multiple modes with numerous quantum states. …”
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324
Nanoscale Flexing Mechanism of a Metal–Organic Framework Determined by Atomic Force Microscopy
Published 2025“…<b>1</b>·0.96DMF undergoes a flexing expansion transformation on guest exchange to form <b>1</b>·<i>x</i>EtOH through the passage of wavefronts of cooperatively transforming, consecutive rows of unit cells parallel to the (011) plane, resulting in whole (011) layers of unit cells transforming by a layer-by-layer shear mechanism. The reverse process involves <b>1</b>·<i>x</i>EtOH undergoing a flexing contraction transformation on guest exchange to form <b>1</b>·0.96DMF through a layer-by-layer shear mechanism involving layers of unit cells parallel to the (011̅) plane transforming in a cooperative manner. …”
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325
Nanoscale Flexing Mechanism of a Metal–Organic Framework Determined by Atomic Force Microscopy
Published 2025“…<b>1</b>·0.96DMF undergoes a flexing expansion transformation on guest exchange to form <b>1</b>·<i>x</i>EtOH through the passage of wavefronts of cooperatively transforming, consecutive rows of unit cells parallel to the (011) plane, resulting in whole (011) layers of unit cells transforming by a layer-by-layer shear mechanism. The reverse process involves <b>1</b>·<i>x</i>EtOH undergoing a flexing contraction transformation on guest exchange to form <b>1</b>·0.96DMF through a layer-by-layer shear mechanism involving layers of unit cells parallel to the (011̅) plane transforming in a cooperative manner. …”
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326
Poster: Evaluating an LGBTQ+ awarding gap and supporting our queer student community: An intersectional perspective (Phase 1)
Published 2025“…</p><p dir="ltr">This project is split into two phases. Phase 1 will involve a literature review and quantitative model that aims to explore the relationships between queer identities and academic awarding. …”
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Table 1_The future of Italian phase I trials regulation: lessons from a nationwide survey.docx
Published 2025“…</p>Methods<p>A nationwide cross-sectional survey (March–April 2024) was conducted among professionals involved in phase I trials. A 19-item questionnaire explored institutional characteristics, certification processes, quality structures and perceptions of the Determination. …”
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Temperature-driven metabolic shifts in duck egg components during early embryogenesis: from diapause to active developmental phase
Published 2025“…We propose that temperature-driven reactivation of diapause involves metabolic responses linked to dynamic small molecule profiles in yolk and albumen, potentially regulating embryonic resumption. …”
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337
The Electron-Yielding Capacity of the Matrix Can Explain Apparent Zero-Order Reduction of Electron-Acceptors in Aquifers at Steady State
Published 2025“…To better understand and quantify the reduction rates of electron acceptors at field sites, we propose investigating the processes and rates controlling the microbial access to solid-phase electron donors.…”
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338
Biphasic Coacervation Controlled by Kinetics as Studied by De Novo-Designed Peptides
Published 2025“…When pH-dependent electrostatic interaction and hydrophobic interaction are involved or the peptides form secondary structures, the Coacervation process is then path-dependent, indicating that the kinetics controls the phase separation process. …”
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339
Biphasic Coacervation Controlled by Kinetics as Studied by De Novo-Designed Peptides
Published 2025“…When pH-dependent electrostatic interaction and hydrophobic interaction are involved or the peptides form secondary structures, the Coacervation process is then path-dependent, indicating that the kinetics controls the phase separation process. …”
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340
Biphasic Coacervation Controlled by Kinetics as Studied by De Novo-Designed Peptides
Published 2025“…When pH-dependent electrostatic interaction and hydrophobic interaction are involved or the peptides form secondary structures, the Coacervation process is then path-dependent, indicating that the kinetics controls the phase separation process. …”