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4181
Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes
Published 2009“…The thermal and pressure activation parameters measured indicate that the mechanism operating in this case lies out of the continuum existing for the series of C−H bond activations studied so far. The more than probable associative shift of the reactivity of the Pt<sup>II</sup> complex containing the electron-withdrawing C<sub>6</sub>F<sub>5</sub> ligands is held responsible for this fact.…”
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4182
Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes
Published 2009“…The thermal and pressure activation parameters measured indicate that the mechanism operating in this case lies out of the continuum existing for the series of C−H bond activations studied so far. The more than probable associative shift of the reactivity of the Pt<sup>II</sup> complex containing the electron-withdrawing C<sub>6</sub>F<sub>5</sub> ligands is held responsible for this fact.…”
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4183
Characterization and Electrochemical Properties of Molecular Icosanuclear and Bidimensional Hexanuclear Cu(II) Azido Polyoxometalates
Published 2007“…<b>1</b> represents the first multidimensional compound based on azido polyoxometalate (POM) units, and <b>2</b> represents by far the largest azido POM complex isolated to date. …”
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4184
Uniportal VATS Lung Sparing Resection with Radial Stapler for Unknown Post-COVID-19 Lesions
Published 2023“…Excessive production of reactive oxygen species and nonprotective mechanical ventilation could also be involved (10).</p> <p>Clinicians and surgeons should always be aware of these post-COVID-19 atypical benign lesions, mimicking lung tumors, to avoid unnecessary extensive pulmonary resections. …”
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4185
Counting the Dead, Making the Dead Count (including everyone) throughHealthy Sierra Leone — HEAL-SL
Published 2024“…Deaths from coronavirus 2019 (COVID-19) are far lower than expected. HEAL-SL is about counting the dead to help the living.…”
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4186
32271: An Introvert in Lockdown
Published 2023“…It's actually proven really productive so far. </p><p dir="ltr">Another thing that I'm enjoying is how much extroverts are struggling with the lockdown. …”
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4187
The Agave Platform: An Open Science-As-A-Service Cloud Platform for Reproducible Science
Published 2018“…This project includes three well-defined efforts which will synergistically evolve the current technology into a sustainable Science-as-a-Service platform for the national research community. …”
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4188
The Agave Platform: An Open Science-As-A-Service Cloud Platform for Reproducible Science
Published 2020“…This project includes three well-defined efforts which will synergistically evolve the current technology into a sustainable Science-as-a-Service platform for the national research community. …”
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4189
The Agave Platform: An Open Science-As-A-Service Cloud Platform for Reproducible Science
Published 2020“…This project includes three well-defined efforts which will synergistically evolve the current technology into a sustainable Science-as-a-Service platform for the national research community. …”
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4190
Data from: Viviparity does not affect the numbers and sizes of reptile offspring
Published 2022“…Viviparity (live-bearing) has independently evolved from oviparity (egg-laying) in more than 100 lineages of squamates (lizards and snakes). …”
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4191
Novel Iron(III) Complexes of Sterically Hindered 4N Ligands: Regioselectivity in Biomimetic Extradiol Cleavage of Catechols
Published 2008“…Upon adding 3,5-di-<i>tert</i>-butylcatechol (H<sub>2</sub>DBC) pretreated with 1 equiv of Et<sub>3</sub>N to <b>1</b>−<b>3</b>, only one catecholate-to-iron(III) LMCT band (648−800 nm) is observed revealing the formation of [Fe(L)(HDBC)]<sup>2+</sup> involving bidentate coordination of the monoanion HDBC<sup>−</sup>. …”
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4192
Bis(purine) Complexes of <i>trans</i>-a<sub>2</sub>Pt<sup>II</sup>: Preparation and X-ray Structures of Bis(9-methyladenine) and Mixed 9-Methyladenine, 9-Methylguanine Complexes a...
Published 1996“…The fact that Pt−(A-<i>N1</i>) and Pt−(A-<i>N7</i>) vectors are at right angles and the nucleobases essentially coplanar in many cases leads to intramolecular H bonding involving NH<sub>2</sub>(6) of 9-MeA and exocyclic groups of the other nucleobases. …”
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4193
W<sub>2</sub>Cl<sub>4</sub>(NHR)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 3. Bidentate Phosphine Complexes of Bis(<i>tert</i>-butylamido)tetrachloroditungsten. Preparati...
Published 1997“…While strong N-H···Cl hydrogen bonding is retained in these diphosphine complexes, each molecule deviates from an eclipsed geometry with torsion angles involving the hydrogen-bonded N and Cl atoms being in the range 12.8−22.0°. …”
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4194
Frank Watson's War
Published 2025“…Hundreds of men were crammed into spaces meant for far fewer, forced to share minimal water supplies for drinking, washing, and sanitation. …”
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4195
Long COVID: a drive to understand the pathophysiology and lived experience to improve patient outcomes
Published 2024“…The largest pandemic of the current millennia so far, caused by severe acute respiratory syndrome coronavirus 2 (SARs-CoV-2), has resulted in over 7 million deaths worldwide.…”
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4196
Understanding alcohol use in UK transgender and non-binary communities
Published 2025“…It demonstrates meaningful involvement of marginalized communities in minimally funded research. …”
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4197
Google form data_ Public awareness and acceptance of COVID-19 vaccine: An online cross-sectional survey, conducted in the first phase of vaccination drive in India
Published 2021“…<b></b></p><p> </p><p> </p><p><b>Ethical considerations</b></p><p>All procedures performed in this study, involving human participants, complied with the institutional ethical standards and were approved by the Ethical Committee of the Institute of Advanced Research, Gujarat, India. …”
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4198
What mechanisms or conditions could explain the observed and reported cases of anticancer efficacy of Amygdalin <sub><em>(</em></sub><i>Vitamin B17</i><sub>)</sub>?
Published 2025“…This is far more appropriate for them than changing their entire enzyme regulation to counteract it. …”
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4199
32169: Corpus Law Diary week 7 TT
Published 2023“…Coming up next Tuesday is a tort tutorial, which I anticipate will involve some heavy lifting in terms of work and thinking: we are moving on to causation, which is a conceptually difficult area of law. …”
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4200
AI is in Your Classroom Even if You Didn't Know It
Published 2023“…</p><p dir="ltr">“Reasoning” is used in the sense of drawing inferences, and AI capabilities are mostly limited to data-based or statistical inference. (True reasoning involving more than inference is still a challenge for AI.)…”