Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes ανά Teresa Calvet (1492921)

“…The thermal and pressure activation parameters measured indicate that the mechanism operating in this case lies out of the continuum existing for the series of C−H bond activations studied so far. The more than probable associative shift of the reactivity of the Pt^II complex containing the electron-withdrawing C₆F₅ ligands is held responsible for this fact.…”

Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes ανά Teresa Calvet (1492921)

“…The thermal and pressure activation parameters measured indicate that the mechanism operating in this case lies out of the continuum existing for the series of C−H bond activations studied so far. The more than probable associative shift of the reactivity of the Pt^II complex containing the electron-withdrawing C₆F₅ ligands is held responsible for this fact.…”

Characterization and Electrochemical Properties of Molecular Icosanuclear and Bidimensional Hexanuclear Cu(II) Azido Polyoxometalates ανά Céline Pichon (2476084)

“…<b>1</b> represents the first multidimensional compound based on azido polyoxometalate (POM) units, and <b>2</b> represents by far the largest azido POM complex isolated to date. …”

Robotic Diaphragm Plication—Technical Pearls ανά Benjamin A. Palleiko (10536472)

“…Small bleeding from the diaphragm is to be expected and almost always resolves on its own. In this case, a slip knot was used to tie the sutures under tension. …”

Uniportal VATS Lung Sparing Resection with Radial Stapler for Unknown Post-COVID-19 Lesions ανά Elisa Sicolo (13559275)

“…Excessive production of reactive oxygen species and nonprotective mechanical ventilation could also be involved (10).</p> <p>Clinicians and surgeons should always be aware of these post-COVID-19 atypical benign lesions, mimicking lung tumors, to avoid unnecessary extensive pulmonary resections. …”

Counting the Dead, Making the Dead Count (including everyone) throughHealthy Sierra Leone — HEAL-SL ανά Hellen Gelband (4348504)

“…Deaths from coronavirus 2019 (COVID-19) are far lower than expected. HEAL-SL is about counting the dead to help the living.…”

32271: An Introvert in Lockdown ανά Lockdown2020 and Beyond Project (17603670)

“…It's actually proven really productive so far. </p><p dir="ltr">Another thing that I'm enjoying is how much extroverts are struggling with the lockdown. …”

Polarity of Chromosome XII and the Nucleolus. ανά Urvashi Rai (3860416)

“…The nucleolar signal then follows slowly, remaining in contact with the stretched chromatin mass. It subsequently is resolved into two equal parts that associate with the chromatin masses. …”

Novel Iron(III) Complexes of Sterically Hindered 4N Ligands: Regioselectivity in Biomimetic Extradiol Cleavage of Catechols ανά Ramasamy Mayilmurugan (2349358)

“…Upon adding 3,5-di-<i>tert</i>-butylcatechol (H₂DBC) pretreated with 1 equiv of Et₃N to <b>1</b>−<b>3</b>, only one catecholate-to-iron(III) LMCT band (648−800 nm) is observed revealing the formation of [Fe(L)(HDBC)]²⁺ involving bidentate coordination of the monoanion HDBC⁻. …”

Bis(purine) Complexes of <i>trans</i>-a₂Pt^II:  Preparation and X-ray Structures of Bis(9-methyladenine) and Mixed 9-Methyladenine, 9-Methylguanine Complexes a... ανά André Schreiber (2995506)

“…The fact that Pt−(A-<i>N1</i>) and Pt−(A-<i>N7</i>) vectors are at right angles and the nucleobases essentially coplanar in many cases leads to intramolecular H bonding involving NH₂(6) of 9-MeA and exocyclic groups of the other nucleobases. …”

W₂Cl₄(NHR)₂(PR‘₃)₂ Molecules. 3. Bidentate Phosphine Complexes of Bis(<i>tert</i>-butylamido)tetrachloroditungsten. Preparati... ανά F. Albert Cotton (1781341)

“…While strong N-H···Cl hydrogen bonding is retained in these diphosphine complexes, each molecule deviates from an eclipsed geometry with torsion angles involving the hydrogen-bonded N and Cl atoms being in the range 12.8−22.0°. …”

Frank Watson's War ανά Their Finest Hour Project Team (18604667)

“…Hundreds of men were crammed into spaces meant for far fewer, forced to share minimal water supplies for drinking, washing, and sanitation. …”

Understanding alcohol use in UK transgender and non-binary communities ανά Dean Connolly (20700822)

“…It demonstrates meaningful involvement of marginalized communities in minimally funded research. …”

Syntheses, Structures, and Spectroscopic Properties of K₉Nd[PS₄]₄, K₃Nd[PS₄]₂, Cs₃Nd[PS₄]<su... ανά Yuandong Wu (2382421)

“…Resonant Raman excitation via a B-term mechanism involving the ⁴I_15/2 and ⁴F_3/2 intermediate states may account for the significant intensity enhancement of the ER transitions with respect to the symmetric P−S stretching vibration ν₁. …”

Google form data_ Public awareness and acceptance of COVID-19 vaccine: An online cross-sectional survey, conducted in the first phase of vaccination drive in India ανά Arumuganainar Suresh (10582049)

“…<b></b></p><p> </p><p> </p><p><b>Ethical considerations</b></p><p>All procedures performed in this study, involving human participants, complied with the institutional ethical standards and were approved by the Ethical Committee of the Institute of Advanced Research, Gujarat, India. …”

Creative Futures Consortium X SWISP Lab: Young People in Anthropogenic TimesWatch video with captions on YouTube (recommended) https://youtu.be/OFDjhW6I6vU?si=Jx-x1OTzhnWiG0Fq ανά SWISP Lab (17289516)

“…So SWISP Lab hacks are comprised of collaborative creativities involving both human, technological and other collaborators.…”

32169: Corpus Law Diary week 7 TT ανά Lockdown2020 and Beyond Project (17603670)

“…Coming up next Tuesday is a tort tutorial, which I anticipate will involve some heavy lifting in terms of work and thinking: we are moving on to causation, which is a conceptually difficult area of law. …”

AI is in Your Classroom Even if You Didn't Know It ανά Lorena A. Barba (97553)

“…</p><p dir="ltr">“Reasoning” is used in the sense of drawing inferences, and AI capabilities are mostly limited to data-based or statistical inference. (True reasoning involving more than inference is still a challenge for AI.)…”

Generation X: Reaching the Minds of Residents and Fellows ανά Joseph Policarpio (13954451)

“…As this learning technique can involve tedious repetition, adding game-like elements to traditionally nongame activities, also described as gamification, achieves learning goals by increasing motivation with both solo and multiplayer configurations. …”

Reactions used in the Platelet-Plasma model. ανά Manash S. Chatterjee (240613)

“…</b>XII activation was coarse grained by assuming a first order dependence on XII concentration and estimating a rate of production (5×10⁻⁴s⁻¹) that would resolve the disparity between the Hockin-Mann model prediction and the experimentally observed control.…”