TpRu Hydride and Dihydrogen Complexes Bearing Bidentate Phosphinoamine Ligands. NMR Study of Proton Transfer to [TpRuH(L)] (L = <i>R,R</i>-dippach, dippae; Tp = Hydrotris(pyrazolyl... by Manuel Jiménez-Tenorio (2507461)

“…The causes for this fast relaxation phenomenon are so far unknown.…”

Mononuclear Titanium(IV)−Citrate Complexes from Aqueous Solutions:  pH-Specific Synthesis and Structural and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)−Citrate Spec... by E. T. Kefalas (2679103)

“…In an effort to comprehend the involvement of titanium in requisite biological interactions with physiological ligands, synthetic efforts were launched targeting aqueous soluble species of Ti(IV). …”

NHC Bis-Phenolate Aluminum Chelates: Synthesis, Structure, and Use in Lactide and Trimethylene Carbonate Polymerization by Charles Romain (1366158)

“…Alternatively, compound <b>3</b> may be accessed via a salt metathesis route involving the reaction of the NHC bis-phenolate Li salt <b>1</b>·Li₂, generated in situ via reaction of <b>1</b>·H₃Cl with 3 equiv of ^<i>n</i>BuLi (−40 °C, THF), with 1 equiv of MeAlCl₂. …”

Preparation and Protonation of Fe₂(pdt)(CNR)₆, Electron-Rich Analogues of Fe₂(pdt)(CO)₆ by Xiaoyuan Zhou (1604638)

“…Like the hexacarbonyls, the stereodynamics of <b>1</b>–<b>3</b> involve both turnstile rotation of the Fe­(CNR)₃ as well as the inversion of the chair conformation of the pdt ligand. …”

Crossovers mediated by <i>K</i>. <i>lactis</i> Zip1 are dependent on Zip3, Zip4, Spo16 and Mlh3 but independent of Msh4, Msh5 and non-MutSγ-MutLγ crossover pathway components. by Karen Voelkel-Meiman (129315)

“…Each set of three adjacent bars represents samples harvested at 0, 40 and 70 hours (left to right) after placement in sporulation medium. Solid bars at far left of graphs in (B) are the % recombination values for <i>S</i>. …”

Empowering Community Health Workers to Transform Maternal Care in Uganda’s Lake Victoria Fishing Communities. by Ali Ssetaala (22558373)

“…There are only 14.2 SBAs (Doctor, Nurse, and Midwife), per 10,000 people, far below the WHO’s sustainable development recommendation of 44.5 per 10,000 people.…”

DataSheet_2_Effectiveness, safety and pharmacokinetics of Polo-like kinase 1 inhibitors in tumor therapy: A systematic review and meta-analysis.pdf by Xiao Wei (44054)

“…</p>Methods<p>The Medline, PubMed, Embase, etc. were searched and updated on 30 June 2022. 22 eligible clinical trials involving a total of 1256 patients were included for analyses. …”

Dataset of Semi-Autonomous Continuous Robotic Arm Control Using an Augmented Reality Brain-Computer Interface by Kirill Kokorin (9643181)

“…</p><h3>Overview</h3><p dir="ltr">The experiment involved 18 healthy participants using an augmented reality (AR) brain-computer interface (BCI) to continuously control a robotic arm. …”

DataSheet_1_High Prevalence and Diversity Characteristics of blaNDM, mcr, and blaESBLs Harboring Multidrug-Resistant Escherichia coli From Chicken, Pig, and Cattle in China.zip by Zhihai Liu (1425982)

“…More interestingly, two deletion events with a 500-bp deletion in ΔISAba125 and a 180-bp deletion in dsbC were observed in three bla_NDM-5 IncX3 plasmids, which, as far as we know, is the first discovery. This showed the instability and horizontal transfer of bla_NDM genetic context, suggesting that bla_NDM is evolving to “pack light” to facilitate rapid and stable horizontal transfer. …”

Table1_The Northernmost Volcanoes in South America (Colombia, 5–6°N): The Potentially Active Samaná Monogenetic Volcanic Field.XLSX by Laura Sánchez-Torres (12960728)

“…Few volcanoes have been studied so far, but they are recognized as a cluster of volcanoes of intermediate-to-acid composition, formed by both explosive and effusive eruptions. …”

Table2_The Northernmost Volcanoes in South America (Colombia, 5–6°N): The Potentially Active Samaná Monogenetic Volcanic Field.XLSX by Laura Sánchez-Torres (12960728)

“…Few volcanoes have been studied so far, but they are recognized as a cluster of volcanoes of intermediate-to-acid composition, formed by both explosive and effusive eruptions. …”

EllipSys3D large eddy simulation data of single wind turbine wakes in neutral atmospheric conditions by Paul van der Laan (6222017)

“…The force distribution is based on a rotor resolved detached eddy simulation. The rotor diameter D is 126 m.…”

Sister kinetochore biorientation during meiosis II is not affected by THR depletion. by Ariane C. Blattner (2633800)

“…In control (+, top panel), sister centromeres are segregated far apart to opposite poles during exit from meiosis II; only one of the two postmeiotic nuclei with four centromeres is shown. …”

DataSheet_1_Adjuvant capecitabine in triple negative breast cancer patients with residual disease after neoadjuvant treatment: real-world evidence from CaRe, a multicentric, observ... by Francesca Sofia Di Lisa (11782199)

“…</p>Methods<p>We carried out a multicenter, observational study, involving 44 oncologic centres. Triple negative breast cancer patients with residual disease, treated with adjuvant capecitabine from January 2017 through June 2021, were recruited. …”

Mexican Business and the State: The Political Economy of a 'Muddled' Transition by Blanca Heredia (18888610)

“…In contrast to most other authoritarian regimes in the region, however, conflict in state-business relations stopped short of rupture and business elites' political activation failed to facilitate a full-fledged transition to democracy. While democracy may evolve in the future, business elites have thus far only succeeded in ushering in a process of partial and segmented political liberalization which has tended to reinforce, rather than erode, the basic pillars of authoritarian rule. …”

Infrared Multiple Photon Dissociation Spectroscopy of the H–H Stretching Mode and Low-Lying Electronic Transitions in Fe⁺(H₂)_1,2 and Fe⁺... by Shan Jin (698618)

“…Although iron is the most abundant transition metal in the interstellar medium, its interaction with hydrogenby far the most abundant elementin small gas-phase molecules or complexes is poorly understood. …”

Uniportal Robotic-Assisted Thoracoscopic Surgery: Left S6 Segmentectomy by Felice Lo Faso (13904418)

“…</p> <p>The postoperative course was characterized by an air leak complication resolved by postoperative day three (POD 3), allowing chest drain removal on POD 4. …”

Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes by Teresa Calvet (1492921)

“…The thermal and pressure activation parameters measured indicate that the mechanism operating in this case lies out of the continuum existing for the series of C−H bond activations studied so far. The more than probable associative shift of the reactivity of the Pt^II complex containing the electron-withdrawing C₆F₅ ligands is held responsible for this fact.…”

Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes by Teresa Calvet (1492921)

“…The thermal and pressure activation parameters measured indicate that the mechanism operating in this case lies out of the continuum existing for the series of C−H bond activations studied so far. The more than probable associative shift of the reactivity of the Pt^II complex containing the electron-withdrawing C₆F₅ ligands is held responsible for this fact.…”

Characterization and Electrochemical Properties of Molecular Icosanuclear and Bidimensional Hexanuclear Cu(II) Azido Polyoxometalates by Céline Pichon (2476084)

“…<b>1</b> represents the first multidimensional compound based on azido polyoxometalate (POM) units, and <b>2</b> represents by far the largest azido POM complex isolated to date. …”