Chain Transfer to Solvent in Propene Polymerization with Ti Cp-phosphinimide Catalysts: Evidence for Chain Termination via Ti–C Bond Homolysis за авторством Christian Ehm (1593097)

“...End-group analysis suggests that these are formed after a 2,1-insertion event; density functional theory (DFT) studies support a mechanism involving homolysis of a Ti-<i>sec</i>-alkyl bond. ...”

Lactone Radical Cyclizations and Cyclization Cascades Mediated by SmI₂–H₂O за авторством Dixit Parmar (2059843)

“...The cyclizations proceed by the trapping of radical anions formed by electron transfer reduction of the lactone carbonyl....”

Congenital Zika syndrome and neuroimaging findings: what do we know so far? за авторством Bruno Niemeyer de Freitas Ribeiro (4647952)

“...<div><p>Abstract Although infection with the Zika virus was first recognized in 1942, it received little attention until 2007, when a true pandemic spread throughout Africa, Asia, and the Americas. Since then, numerous forms of central nervous system involvement have been described, mainly malformations related to congenital infection. ...”

Lactone Radical Cyclizations and Cyclization Cascades Mediated by SmI₂–H₂O за авторством Dixit Parmar (2059843)

“...The cyclizations proceed by the trapping of radical anions formed by electron transfer reduction of the lactone carbonyl....”

Electrophilic Interaction of 2,3-Allenoates with PhSeCl. An Unexpected Highly Stereoselective Synthesis of 3-Phenylseleno-4-oxo-2(<i>E</i>)-alkenoates за авторством Guofei Chen (2365789)

“...A possible mechanism involving a decomposition of selenate esters was proposed....”

Supplementary Figure S2. Characterization of the B-cell lymphoma PDX models from B-Cell Lymphoma Patient-Derived Xenograft Models Enable Drug Discovery and Are a Platform for Perso... за авторством Leo Zhang (13811878)

“...B-C, PDX tumors invaded the mouse spleen and formed splenomegaly. D, Patient abdomen PET/CT images of PT1 and PT5 showed splenomegaly (left panel). ...”

A Tunable Route for the Synthesis of Azomethine Imines and β‑Aminocarbonyl Compounds from Alkenes за авторством Christian Clavette (1968556)

“...A thermal, concerted alkene aminocarbonylation pathway involving an imino-isocyanate intermediate is proposed and supported by DFT calculations. ...”

Chain Transfer to Solvent in Propene Polymerization with Ti Cp-phosphinimide Catalysts: Evidence for Chain Termination via Ti–C Bond Homolysis за авторством Christian Ehm (1593097)

“...End-group analysis suggests that these are formed after a 2,1-insertion event; density functional theory (DFT) studies support a mechanism involving homolysis of a Ti-<i>sec</i>-alkyl bond. ...”

Dissociative Electron Attachment to Anthralin to Model Its Biochemical Reactions за авторством Stanislav A. Pshenichnyuk (1373139)

“...A likely mechanism for the biochemical transformations of anthralin under reductive conditions in vivo is hypothesized on the basis of its DEA properties. The involvement of excited electronic states generated by ultraviolet irradiation of skin is discussed....”

Lactone Radical Cyclizations and Cyclization Cascades Mediated by SmI₂–H₂O за авторством Dixit Parmar (2059843)

“...The cyclizations proceed by the trapping of radical anions formed by electron transfer reduction of the lactone carbonyl....”

1,4-Hydroboration Reactions of Electron-Poor Aromatic Rings by N‑Heterocyclic Carbene Boranes за авторством Wen Dai (1607932)

“...When regioisomers are possible, the more crowded (doubly ortho-substituted) product is formed preferably or exclusively. The mechanism may involve oxidation of the NHC-borane to an NHC-boryl radical, reduction of the electron-poor aromatic ring to a radical anion, coupling of the radical and the radical anion to give a cyclohexadienyl anion, and finally regioselective protonation....”

1,4-Hydroboration Reactions of Electron-Poor Aromatic Rings by N‑Heterocyclic Carbene Boranes за авторством Wen Dai (1607932)

“...When regioisomers are possible, the more crowded (doubly ortho-substituted) product is formed preferably or exclusively. The mechanism may involve oxidation of the NHC-borane to an NHC-boryl radical, reduction of the electron-poor aromatic ring to a radical anion, coupling of the radical and the radical anion to give a cyclohexadienyl anion, and finally regioselective protonation....”

A Tunable Route for the Synthesis of Azomethine Imines and β‑Aminocarbonyl Compounds from Alkenes за авторством Christian Clavette (1968556)

“...A thermal, concerted alkene aminocarbonylation pathway involving an imino-isocyanate intermediate is proposed and supported by DFT calculations. ...”

The Isolation of [Pd{OC(O)H}(H)(NHC)(PR₃)] (NHC = N‑Heterocyclic Carbene) and Its Role in Alkene and Alkyne Reductions Using Formic Acid за авторством Julie Broggi (1977043)

“...The [Pd­(SIPr)­(PCy₃)] complex efficiently promotes a tandem process involving dehydrogenation of formic acid and hydrogenation of C–C multiple bonds using H₂ formed in situ. ...”

Chain Transfer to Solvent in Propene Polymerization with Ti Cp-phosphinimide Catalysts: Evidence for Chain Termination via Ti–C Bond Homolysis за авторством Christian Ehm (1593097)

“...End-group analysis suggests that these are formed after a 2,1-insertion event; density functional theory (DFT) studies support a mechanism involving homolysis of a Ti-<i>sec</i>-alkyl bond. ...”

Technology for activity participation in older people with mild cognitive impairment or dementia: expert perspectives and a scoping review за авторством Stacey L. Schepens Niemiec (13729958)

“...</p><p>Innovative research-based technologies to be used directly by PwMCI/ADRD are under development, particularly to facilitate management of ADL, social participation and IADL in persons with mild-to-moderate forms of cognitive impairment.</p><p>Soft technology strategies to support technology implementation with MCI/ADRD target users include close attention to design of the technology (e.g., customisability, sensory stimulators and prompting features), instructional strategies that promote learning and motivation and involvement of technology partners to facilitate engagement with the technology....”

Some morphometric measurements of juvenile rainbow trout (Oncorhynchus mykiss) and inanga (Galaxias maculatus) relevant to fish passage remediation за авторством Jonathan D Tonkin (277559)

“...However, both the regressions involving FL were considerably weaker (R2 < 0.78), with most variation at the smaller size ranges where they transition from migratory juvenile ‘whitebait’ to post-migratory adults. ...”

Real Time Observation of the Formation of Hollow Nanostructures through Solid State Reactions за авторством Huang-Yen Lai (1812811)

“...Annealed above 450 °C, the nonequilibrium interdiffusion of core and shell species occurred at the interface; thus, Ni germanide hollow nanostructures were formed by solid state reactions involving the Kirkendall effect. ...”

Real Time Observation of the Formation of Hollow Nanostructures through Solid State Reactions за авторством Huang-Yen Lai (1812811)

“...Annealed above 450 °C, the nonequilibrium interdiffusion of core and shell species occurred at the interface; thus, Ni germanide hollow nanostructures were formed by solid state reactions involving the Kirkendall effect. ...”

Aqueous Silica and Silica Polimerization за авторством Lyudmila Lunevich (18028390)

“...Dissolved silica (SiO2) is supplied to the environment by chemical and bio- chemical weathering processes despite the fact that dissolved silica has many stable and unstable dissolved forms (silica species). The processes involve ion substitution and chelate forming reactions which remove mineral lattice cations. ...”