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31541
Expression and localization of the DEN1 homolog DenA (AN10456) during development of the fungus <i>Aspergillus nidulans</i>.
Published 2013“…In the presence of light <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-vonZeskaKress1" target="_blank">[4]</a> an aerial filament with an apical vesicle forms the asexual developmental structure (conidiophore) <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-Morimoto1" target="_blank">[5]</a> and releases the uninucleate conidiospores (green) into the air. …”
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31542
Eh!woza Learner Doccies
Published 2023“…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”
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31543
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Published 2020“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product.…”
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31544
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Published 2025“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”
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31545
Preparation of Half-Sandwich Osmium Complexes by Deprotonation of Aromatic and Pro-aromatic Acids with a Hexahydride Brønsted Base
Published 2011“…The equilibrium mixture of <b>2</b> and <b>3</b> evolves into OsH(η<sup>5</sup>-PhO)(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> (<b>4</b>) with loss of molecular hydrogen. …”
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31546
The recycle hypothesis of junk DNA
Published 2016“…Blue arrows suggest the exchange of newly formed SSRs from A, with degraded SSRs from B.<div><br></div><div><h3>Heterochromatin and euchromatin: the two main evolutionary forces</h3><div>Heterochromatin is also acting as a shield for the inner core against point mutations originating from outside the nucleus. …”
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31547
C<sub>β</sub>(sp<sup>2</sup>)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carb...
Published 2008“…In dichloromethane the H···F hydrogen bond is broken and DFT calculations suggest that the OH-hydrogen atom forms an H···Cl hydrogen bond with the chlorine ligand. …”
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31548
<b>2025 GSENet Annual Report </b>Smart Education in the Age of AI
Published 2025“…</p><p dir="ltr">Finally, the report concludes by synthesizing these findings to reimagine the futures of smart education, highlighting the evolving role of AI agents in creating human-AI collaborative learning ecosystems. …”
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31549
Influence of the Bite Angle of Dianionic C,N,C-Pincer Ligands on the Chemical and Photophysical Properties of Iridium(III) and Osmium(IV) Hydride Complexes
Published 2019“…Initially, the phenyl activation gives IrH<sub>2</sub>{κ<sup>2</sup>-<i>C</i>,<i>N</i>-(C<sub>6</sub>H<sub>4</sub>-py-OPh)}(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> (<b>3</b>), which subsequently evolves to IrH{κ<sup>3</sup>-<i>C</i>,<i>N</i>,<i>C</i>-(C<sub>6</sub>H<sub>4</sub>-py-OC<sub>6</sub>H<sub>4</sub>)}(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> (<b>4</b>). …”
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31550
Alkynyldiphenylphosphine d<sup>8</sup> (Pt, Rh, Ir) Complexes: Contrasting Behavior toward <i>cis</i>-[Pt(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>(THF)<sub>2</sub>]
Published 2004“…Thus, treatment of <b>1</b> with 1 equiv of <i>cis</i>-[Pt(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>(THF)<sub>2</sub>] gives the double inserted cationic product [Pt(C<sub>6</sub>F<sub>5</sub>)(S)μ-{C(Ph)C(PPh<sub>2</sub>)C(PPh<sub>2</sub>)C(Ph)(C<sub>6</sub>F<sub>5</sub>)}Pt(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>C⋮CPh)](CF<sub>3</sub>SO<sub>3</sub>) (S = THF, H<sub>2</sub>O), <b>8</b> (S = H<sub>2</sub>O, X-ray), which evolves in solution to the mononuclear complex [(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>C⋮CPh)Pt{C<sub>10</sub>H<sub>4</sub>-1-C<sub>6</sub>F<sub>5</sub>-4-Ph-2,3-κ<i>PP</i>‘(PPh<sub>2</sub>)<sub>2</sub>}](CF<sub>3</sub> SO<sub>3</sub>), <b>9</b> (X-ray), containing a 1-pentafluorophenyl-2,3-bis(diphenylphosphine)-4-phenylnaphthalene ligand, formed by annulation of a phenyl group and loss of the Pt(C<sub>6</sub>F<sub>5</sub>) unit. …”
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31551
Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo<sub>2</sub>(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>(μ-R)(μ-PCy...
Published 2009“…Finally, the phenyl-bridged complex gives again the analogous phenyl derivative [Mo<sub>2</sub>Cp<sub>2</sub>(Ph)(μ-PCy<sub>2</sub>)(CO)(NO)<sub>2</sub>], but small amounts of dinitrosyl derivatives having terminal benzoyl, [Mo<sub>2</sub>Cp<sub>2</sub>{C(O)Ph}(μ-PCy<sub>2</sub>)(CO)(NO)<sub>2</sub>], bridging benzoyl, [Mo<sub>2</sub>Cp<sub>2</sub>{μ-κ<sup>1</sup>:η<sup>2</sup>-C(O)Ph}(μ-PCy<sub>2</sub>)(NO)<sub>2</sub>], and bridging phenyl ([Mo<sub>2</sub>Cp<sub>2</sub>{μ-κ<sup>1</sup>:η<sup>2</sup>-Ph}(μ-PCy<sub>2</sub>)(NO)<sub>2</sub>], Mo−Mo = 2.9753(5) Å)) ligands are now formed. The latter complex can be selectively generated through the photochemical decarbonylation of the major phenyl complex. …”
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31552
Reactivity of the Phosphinidene-Bridged Complexes [Mo<sub>2</sub>Cp(μ-κ<sup>1</sup>:κ<sup>1</sup>,η<sup>5</sup>-PC<sub>5</sub>H<sub>4</sub>)(η<sup>6</sup>-1,3,5-C<sub>6</sub>H<sub>...
Published 2012“…A side product was also formed during the photochemical treatment of the dicarbonyl substrate, it being finally isolated after chromatographic workup as the alkenylphosphide-chloride complex [Mo<sub>2</sub>CpCl{μ-κ<sup>1</sup>,η<sup>5</sup>:κ<sup>1</sup>,η<sup>2</sup>-(C<sub>5</sub>H<sub>4</sub>)PC(CO<sub>2</sub>Me)CH(CO<sub>2</sub>Me)}(η<sup>6</sup>-HMes*)(CO)] (Mo–P = 2.553(2) and 2.436(2) Ǻ).…”
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31553
Structurally Flexible and Solution Stable [Ln<sub>4</sub>TM<sub>8</sub>(OH)<sub>8</sub>(L)<sub>8</sub>(O<sub>2</sub>CR)<sub>8</sub>(MeOH)<sub><i>y</i></sub>](ClO<sub>4</sub>)<sub>4...
Published 2016“…This family of compounds offers an excellent playground for probing how the magnetocaloric effect evolves by introducing either antiferromagnetic or ferromagnetic interactions, or magnetic anisotropy, by substituting the nonmagnetic Zn<sup>II</sup> (<b>1a</b>) with Cu<sup>II</sup> (<b>2a</b>), Ni<sup>II</sup> (<b>6a</b>) or Co<sup>II</sup> (<b>7a</b>), respectively. …”
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31554
Structural and Kinetic Study of Reversible CO<sub>2</sub> Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes
Published 2007“…Under a N<sub>2</sub> atmosphere the complexes evolve CO<sub>2</sub> and revert to the starting hydroxo complexes <b>1</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub> and <b>2</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>, a reaction the rate of which linearly depends on [H<sub>2</sub>O]. …”
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31555
Reactivity of Silyl-Substituted Iron–Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum–Hydride Bond. Synthesis...
Published 2016“…In contrast, treatment of <b>1a</b> with <i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH produces first [(OC)<sub>3</sub>Fe{μ-Si(OMe)<sub>2</sub>(OMe)}(μ-dppm)Pt(<i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH<sub>2</sub>)] (<b>2b</b>), which evolves to the dimetallacyclopentenone complex [(OC)<sub>2</sub>Fe(μ-dppm){μ-C(O)C(H)C(C<sub>6</sub>H<sub>4</sub>F-<i>o</i>)}Pt(PPh<sub>3</sub>)] (<b>4b′</b>). …”