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28521
Stereoselectivity in the Formation of Metallomacrocycles from [Mo(NO){HB(3,5-Me<sub>2</sub>C<sub>3</sub>HN<sub>2</sub>)<sub>3</sub>}I<sub>2</sub>] and Ditopic Proligands: The X-ra...
Published 1999“…These binuclear complexes are formed under kinetic control so that <i>syn</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2s</b>, forms more rapidly than <i>anti</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2a</b>, but in lower yield. …”
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28522
Mixed-Metal Cluster Chemistry. 30. Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes
Published 2007“…Some insight into the mechanism by which these clusters function as optical limiters has been gleaned from complementary pump−probe studies, with their behavior consistent with a fast nonlinear absorption process followed by reverse saturable absorption involving metastable excited states of greater than nanosecond lifetime.…”
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28523
Structural and Kinetic Study of Reversible CO<sub>2</sub> Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes
Published 2007“…Under a N<sub>2</sub> atmosphere the complexes evolve CO<sub>2</sub> and revert to the starting hydroxo complexes <b>1</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub> and <b>2</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>, a reaction the rate of which linearly depends on [H<sub>2</sub>O]. …”
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28524
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
Published 1997“…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”
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28525
Eh!woza Learner Doccies
Published 2023“…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”
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28526
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Published 2020“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product.…”
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28527
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Published 2025“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”