σ-Borane Complexes of Iridium: Synthesis and Structural Characterization Yazar: Travis J. Hebden (2319073)

“…Reaction of (<i>t</i>BuPOCOP)IrH₂ with pinacol borane gave initially complex <b>2</b>, which is assigned a structure analogous to that of <b>1</b> based on spectroscopic measurements. Complex <b>2</b> evolves H₂ at room temperature leading to the borane complex <b>3</b>, which is formed cleanly when <b>2</b> is subjected to dynamic vacuum. …”

σ-Borane Complexes of Iridium: Synthesis and Structural Characterization Yazar: Travis J. Hebden (2319073)

“…Reaction of (<i>t</i>BuPOCOP)IrH₂ with pinacol borane gave initially complex <b>2</b>, which is assigned a structure analogous to that of <b>1</b> based on spectroscopic measurements. Complex <b>2</b> evolves H₂ at room temperature leading to the borane complex <b>3</b>, which is formed cleanly when <b>2</b> is subjected to dynamic vacuum. …”

Reactivity of the Iridium(I) Alkene/Alkyne Complex Tp^Me2Ir(C₂H₄)(MeO₂CC⋮CCO₂Me) Yazar: Margarita Paneque (1478251)

“…Complex <b>3</b> slowly evolves to another alkenyl species, (<b>4</b>), which exists as a mixture of two stereoisomers. …”

Mixed-Metal Cluster Chemistry. 30. Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes Yazar: Michael D. Randles (2034709)

“…Some insight into the mechanism by which these clusters function as optical limiters has been gleaned from complementary pump−probe studies, with their behavior consistent with a fast nonlinear absorption process followed by reverse saturable absorption involving metastable excited states of greater than nanosecond lifetime.…”

Junctional Adhesion Molecules (JAMs) - New Players in Breast Cancer? Yazar: Gozie Offiah (7897577)

“…The simplest classifications of disease subdivide breast cancer into pre-invasive and invasive forms; with the pre-invasive forms being ductal carcinoma <em><em>in situ </em></em>(DCIS) and lobular carcinoma <em><em>in situ </em></em>(LCIS). …”

Facile Single or Double C−H Bond Activation on a Cp* Ligand Promoted by the Presence of Alkynylphosphine Ligands Yazar: María Bernechea (1595569)

“…Complex <b>1</b> rearranges thermally (toluene, reflux) to generate a solution from which a mixture formed by <b>1</b>, the monohydroalkylated derivative [Rh{κ<i>P:</i>η⁵-C₅Me₄(CH₂CPhCHPPh₂)}Cl(PPh₂CCPh)](CF₃SO₃) (<b>2</b>), and the symmetrical 1,2 -dihydroalkylated derivative [Rh{κ²<i>PP′:</i>η⁵-C₅Me₃-1,2-(CH₂CPhCHPPh₂)₂}Cl](CF₃SO₃) (<b>3′</b>) (∼30:60:10, respectively) can be isolated. …”

Elucidating Potential Energy Surfaces for Singlet O₂ Reactions with Protonated, Deprotonated, and Di-Deprotonated Cystine Using a Combination of Approximately Spin-Proje... Yazar: Wenchao Lu (3695281)

“…Collision of di-deprotonated cystine with singlet O₂, on the other hand, forms a short-lived electrostatically bonded precursor complex at low <i>E</i>_col. …”

Joining Natural and Synthetic DNA Using Biversal Nucleotides: Efficient Sequencing of Six-Nucleotide DNA Yazar: Bang Wang (525276)

“…By rearranging hydrogen bond donor and acceptor groups within a standard Watson–Crick geometry, DNA can add eight independently replicable nucleotides forming four additional not found in standard Terran DNA. …”

DataSheet_1_Protection against influenza-induced Acute Lung Injury (ALI) by enhanced induction of M2a macrophages: possible role of PPARγ/RXR ligands in IL-4-induced M2a macrophage... Yazar: Archana Gopalakrishnan (13252188)

“…<p>Many respiratory viruses cause lung damage that may evolve into acute lung injury (ALI), a cytokine storm, acute respiratory distress syndrome, and ultimately, death. …”

W₂Cl₄(NR₂)₂(PR‘₃)₂ Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and... Yazar: F. Albert Cotton (1781341)

“…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”

Examining prediction formation in empirical and model position representations. Yazar: William Turner (2220598)

“…In the main analysis we consider the ‘steady state’ of position representations formed after sustained exposure to motion along a predictable trajectory, and found evidence of progressive extrapolation. …”

Expression and localization of the DEN1 homolog DenA (AN10456) during development of the fungus <i>Aspergillus nidulans</i>. Yazar: Martin Christmann (280300)

“…In the presence of light <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-vonZeskaKress1" target="_blank">[4]</a> an aerial filament with an apical vesicle forms the asexual developmental structure (conidiophore) <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-Morimoto1" target="_blank">[5]</a> and releases the uninucleate conidiospores (green) into the air. …”

Eh!woza Learner Doccies Yazar: Anastasia Koch (9420299)

“…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”

Unusual [Pt{κ²(<i>C</i>,<i>N</i>)}]⁺ → [Pt{κ²(<i>N</i>,<i>N</i>)}]⁺ Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... Yazar: Rishabh Ujjval (9454247)

“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ²(<i>C</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ²(<i>N</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>16</b>′), is a kinetically controlled product.…”

Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) Yazar: Thomas Gernon (11046150)

“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”

Preparation of Half-Sandwich Osmium Complexes by Deprotonation of Aromatic and Pro-aromatic Acids with a Hexahydride Brønsted Base Yazar: Miguel A. Esteruelas (1359033)

“…The equilibrium mixture of <b>2</b> and <b>3</b> evolves into OsH(η⁵-PhO)(PⁱPr₃)₂ (<b>4</b>) with loss of molecular hydrogen. …”

The recycle hypothesis of junk DNA Yazar: Paul A. Gagniuc (1818325)

“…Blue arrows suggest the exchange of newly formed SSRs from A, with degraded SSRs from B.<div><br></div><div><h3>Heterochromatin and euchromatin: the two main evolutionary forces</h3><div>Heterochromatin is also acting as a shield for the inner core against point mutations originating from outside the nucleus. …”

C_β(sp²)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carb... Yazar: María L. Buil (1795546)

“…In dichloromethane the H···F hydrogen bond is broken and DFT calculations suggest that the OH-hydrogen atom forms an H···Cl hydrogen bond with the chlorine ligand. …”

<b>2025 GSENet Annual Report </b>Smart Education in the Age of AI Yazar: Ronghuai Huang (11965352)

“…</p><p dir="ltr">Finally, the report concludes by synthesizing these findings to reimagine the futures of smart education, highlighting the evolving role of AI agents in creating human-AI collaborative learning ecosystems. …”

Influence of the Bite Angle of Dianionic C,N,C-Pincer Ligands on the Chemical and Photophysical Properties of Iridium(III) and Osmium(IV) Hydride Complexes Yazar: Ruth Castro-Rodrigo (2105221)

“…Initially, the phenyl activation gives IrH₂{κ²-<i>C</i>,<i>N</i>-(C₆H₄-py-OPh)}­(PⁱPr₃)₂ (<b>3</b>), which subsequently evolves to IrH­{κ³-<i>C</i>,<i>N</i>,<i>C</i>-(C₆H₄-py-OC₆H₄)}­(PⁱPr₃)₂ (<b>4</b>). …”