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31541
Synthesis, Characterization, and Chiral Behavior of S-Bridged Co<sup>III</sup>Pt<sup>II</sup>Co<sup>III</sup> Trinuclear Complexes Composed of Bis(thiolato)-Type Octahedral Units <...
出版事項 2002“…Complex [<b>1</b>]<sup>4+</sup> formed both racemic (ΔΔ/ΛΛ) and meso (ΔΛ) forms, which were separated and optically resolved by cation-exchange column chromatography. …”
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31542
Syntheses of the Uranium Complexes [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>2</sub>{N(SiMe<sub>3</sub>)(SiMe<sub>2</sub>CH<sub>2</sub>B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)}] an...
出版事項 1998“…The complex [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>2</sub>{N(SiMe<sub>3</sub>)(SiMe<sub>2</sub>CH<sub>2</sub>B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)}] (<b>1</b>) is formed in the reaction between the hydride complex [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>3</sub>(H)] and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>, and H<sub>2</sub> is evolved. …”
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31543
Influence of the Bite Angle of Dianionic C,N,C-Pincer Ligands on the Chemical and Photophysical Properties of Iridium(III) and Osmium(IV) Hydride Complexes
出版事項 2019“…Initially, the phenyl activation gives IrH<sub>2</sub>{κ<sup>2</sup>-<i>C</i>,<i>N</i>-(C<sub>6</sub>H<sub>4</sub>-py-OPh)}(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> (<b>3</b>), which subsequently evolves to IrH{κ<sup>3</sup>-<i>C</i>,<i>N</i>,<i>C</i>-(C<sub>6</sub>H<sub>4</sub>-py-OC<sub>6</sub>H<sub>4</sub>)}(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> (<b>4</b>). …”
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31544
Supporting Information tables, figures, and text.
出版事項 2015“…Three binding metrics were computed for each docking pose: 1) RMSD (Å) to the natural CDP ligand; 2) number of hydrogen bonds formed with the crystallographically resolved water molecule anticipated to catalyze the formation of the new phosphodiester bond to the incoming nucleotide; and 3) number of hydrogen bonds formed with the RNA template (B) Docked binding modes for 2'F-2'Me-, 2'F-4'ClCH<sub>2</sub>-, and 2'F-4'N<sub>3</sub>-CDP were overlaid with the CDP (yellow) X-ray binding mode for reference. …”
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31545
Alkynyldiphenylphosphine d<sup>8</sup> (Pt, Rh, Ir) Complexes: Contrasting Behavior toward <i>cis</i>-[Pt(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>(THF)<sub>2</sub>]
出版事項 2004“…Thus, treatment of <b>1</b> with 1 equiv of <i>cis</i>-[Pt(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>(THF)<sub>2</sub>] gives the double inserted cationic product [Pt(C<sub>6</sub>F<sub>5</sub>)(S)μ-{C(Ph)C(PPh<sub>2</sub>)C(PPh<sub>2</sub>)C(Ph)(C<sub>6</sub>F<sub>5</sub>)}Pt(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>C⋮CPh)](CF<sub>3</sub>SO<sub>3</sub>) (S = THF, H<sub>2</sub>O), <b>8</b> (S = H<sub>2</sub>O, X-ray), which evolves in solution to the mononuclear complex [(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>C⋮CPh)Pt{C<sub>10</sub>H<sub>4</sub>-1-C<sub>6</sub>F<sub>5</sub>-4-Ph-2,3-κ<i>PP</i>‘(PPh<sub>2</sub>)<sub>2</sub>}](CF<sub>3</sub> SO<sub>3</sub>), <b>9</b> (X-ray), containing a 1-pentafluorophenyl-2,3-bis(diphenylphosphine)-4-phenylnaphthalene ligand, formed by annulation of a phenyl group and loss of the Pt(C<sub>6</sub>F<sub>5</sub>) unit. …”
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31546
Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo<sub>2</sub>(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>(μ-R)(μ-PCy...
出版事項 2009“…Finally, the phenyl-bridged complex gives again the analogous phenyl derivative [Mo<sub>2</sub>Cp<sub>2</sub>(Ph)(μ-PCy<sub>2</sub>)(CO)(NO)<sub>2</sub>], but small amounts of dinitrosyl derivatives having terminal benzoyl, [Mo<sub>2</sub>Cp<sub>2</sub>{C(O)Ph}(μ-PCy<sub>2</sub>)(CO)(NO)<sub>2</sub>], bridging benzoyl, [Mo<sub>2</sub>Cp<sub>2</sub>{μ-κ<sup>1</sup>:η<sup>2</sup>-C(O)Ph}(μ-PCy<sub>2</sub>)(NO)<sub>2</sub>], and bridging phenyl ([Mo<sub>2</sub>Cp<sub>2</sub>{μ-κ<sup>1</sup>:η<sup>2</sup>-Ph}(μ-PCy<sub>2</sub>)(NO)<sub>2</sub>], Mo−Mo = 2.9753(5) Å)) ligands are now formed. The latter complex can be selectively generated through the photochemical decarbonylation of the major phenyl complex. …”
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31547
Single-Molecule Magnets: Two-Electron Reduced Version of a Mn<sub>12</sub> Complex and Environmental Influences on the Magnetization Relaxation of (PPh<sub>4</sub>)<sub>2</sub>[Mn...
出版事項 2003“…Complexes <b>4a</b> and <b>4b</b> give resolvable frequency-dependent out-of-phase (χ<sub>M</sub>‘ ‘) signals in AC susceptibility studies resulting from the magnetization relaxation of SMMs. …”
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31548
System enablers and barriers to continuity of care for First Nations people living with chronic conditions: A rapid qualitative review protocol
出版事項 2022“…Any disagreements will be resolved through discussion or with one or more additional reviewers. …”
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31549
Shape Model of Hydra
出版事項 2021“…Shape created from the resolved images of Hydra obtained by New Horizons. …”
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31550
E00144: Coptic Stories of the Monks of the Desert, attributed in the text to Paphnouthios, possibly Paphnouthios of Scetis, 4th c., which describe the lives and miracles of two bis...
出版事項 2014“…<br> <br>The second part (fol. 11b–37a) forms a history of the Bishops of Philae, from the see’s foundation to the death of bishop *Pseleusias (who is different from the monk Pseleusius). …”
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31551
Reactivity of the Phosphinidene-Bridged Complexes [Mo<sub>2</sub>Cp(μ-κ<sup>1</sup>:κ<sup>1</sup>,η<sup>5</sup>-PC<sub>5</sub>H<sub>4</sub>)(η<sup>6</sup>-1,3,5-C<sub>6</sub>H<sub>...
出版事項 2012“…A side product was also formed during the photochemical treatment of the dicarbonyl substrate, it being finally isolated after chromatographic workup as the alkenylphosphide-chloride complex [Mo<sub>2</sub>CpCl{μ-κ<sup>1</sup>,η<sup>5</sup>:κ<sup>1</sup>,η<sup>2</sup>-(C<sub>5</sub>H<sub>4</sub>)PC(CO<sub>2</sub>Me)CH(CO<sub>2</sub>Me)}(η<sup>6</sup>-HMes*)(CO)] (Mo–P = 2.553(2) and 2.436(2) Ǻ).…”
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31552
Structurally Flexible and Solution Stable [Ln<sub>4</sub>TM<sub>8</sub>(OH)<sub>8</sub>(L)<sub>8</sub>(O<sub>2</sub>CR)<sub>8</sub>(MeOH)<sub><i>y</i></sub>](ClO<sub>4</sub>)<sub>4...
出版事項 2016“…This family of compounds offers an excellent playground for probing how the magnetocaloric effect evolves by introducing either antiferromagnetic or ferromagnetic interactions, or magnetic anisotropy, by substituting the nonmagnetic Zn<sup>II</sup> (<b>1a</b>) with Cu<sup>II</sup> (<b>2a</b>), Ni<sup>II</sup> (<b>6a</b>) or Co<sup>II</sup> (<b>7a</b>), respectively. …”
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31553
E06111: The ‘epic’ Greek Martyrdom of *Christophoros (martyr of Pamphylia, S00616) tells of Reprebos, an outwardly repulsive barbarian from a tribe of cannibals, who is baptised a...
出版事項 2018“…Christophoros is nailed to a bronze bench, while around him wood is piled forming a circular covered structure, which is then doused with oil and set on fire.…”
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31554
Reactivity of Silyl-Substituted Iron–Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum–Hydride Bond. Synthesis...
出版事項 2016“…In contrast, treatment of <b>1a</b> with <i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH produces first [(OC)<sub>3</sub>Fe{μ-Si(OMe)<sub>2</sub>(OMe)}(μ-dppm)Pt(<i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH<sub>2</sub>)] (<b>2b</b>), which evolves to the dimetallacyclopentenone complex [(OC)<sub>2</sub>Fe(μ-dppm){μ-C(O)C(H)C(C<sub>6</sub>H<sub>4</sub>F-<i>o</i>)}Pt(PPh<sub>3</sub>)] (<b>4b′</b>). …”
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31555
Degradation of triazine-2-14C metsulfuron–methyl in soil from an oil palm plantation
出版事項 2015“…Results of microbial colonies counted were expressed in colony forming units (CFU).</p> <p>Table 1. Soil characterization.…”