Ligand-Induced and Reductively Induced Alkyne−Isocyanide Coupling Reactions of [Mo(CNBu^t)₃(PhC⋮CPh)(η⁵-C₅Me₅)][BF₄... per Christopher J. Adams (1847317)

“…A similar reaction of <b>4</b> with P(OMe)₃ generates [Mo{C(NHBu^t)C(Ph)C(Ph)CN}(CNBu^t){P(OMe)₃}(η⁵-C₅Me₅)][BF₄], <b>5</b>, involving the same coupling and elimination pattern. …”

Arsenic(III) Halide Complexes with Acyclic and Macrocyclic Thio- and Selenoether Coligands:  Synthesis and Structural Properties per Nicholas J. Hill (1333515)

“…[AsCl₃([14]aneS₄)] forms an infinite sheet involving two μ²-chloro ligands on each As but bridging to two distinct As centers. …”

Structural Diversity in Supramolecular Complexes of MCl₃ (M = As, Sb, Bi) with Constrained Thio- and Seleno-Ether Ligands per William Levason (1275612)

“…[BiCl₃{<i>o</i>-C₆H₄(SeMe)₂}] comprises distorted square pyramidal units involving pyramidal BiCl₃ primary coordination and a weakly chelating diselenoether ligand, and assembled into infinite chains through long bridging Bi···Cl interactions via all three Clʼs. …”

Preparation, Structure, and Properties of the Corner-Shared Double Cubes [Mo₆HgQ₈(H₂O)₁₈]⁸⁺ (Q = S, Se) and Tungsten Analogue... per Vladimir P. Fedin (1491637)

“…Furthermore, on dilution of column-purified [Mo₆HgS₈(H₂O)₁₈]⁸⁺, Beer's law is not obeyed and equilibria involving 2[Mo₃S₄(H₂O)₉]⁴⁺ are apparent. …”

Rooted phylogenetic tree of 550 base pair E1 fragment produced from Bayesian analysis using BEAST. per Isabel Fourie (11896234)

“…Phylogenetic analysis with strong posterior probability support was obtained as follows: the concatenated (ORF1 and ORF 2) and nsP region placed MIDV in its own complex as seen for analysis using nsP4, while analysis using the sP region placed MIDV within the SF complex as seen with analyses involving the E1 fragment (which forms part of the structural proteins) (Figs <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g003" target="_blank">3</a>, <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g004" target="_blank">4</a> and <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g005" target="_blank">5</a>). …”

Tuning the Inclusion Properties and Solid-State Reactivity of Second Sphere Adducts Using Conformationally Flexible Bidentate Ligands per Fang Guo (105824)

“…We demonstrate that some of the second sphere adducts are dynamic, showing reversible guest release/uptake involving crystalline-to-amorphous-to-crystalline phase transformations. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... per Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Near-isotropic, reconstructed volume electron microscopy (FIB-SEM) of mouse dorsal striatum (jrc_mus-dorsal-striatum) per CellMap Project Team (14322654)

“…Here, we have used focused ion beam-scanning electron microscopy to generate 3D reconstructions of intracellular organelles and their membrane appositions involving the ER (distance ≤30 nm) in different neuronal compartments. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... per Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... per Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... per Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”

Proton-Coupled Electron Transfer to a Molybdenum Ethylene Complex Yields a β‑Agostic Ethyl: Structure, Dynamics and Mechanism per Máté J. Bezdek (1980178)

“…Comparison of p<i>K</i>_a and electrochemical data for the complexes <b>[1-C₂H₄]⁺</b> and <b>[1-NH₃]⁺</b> in combination with a deuterium kinetic isotope effect (<i>k</i>_H/<i>k</i>_D) of 3.5(2) at 23 °C support a PCET process involving initial electron transfer followed by protonation leading to the formation of <b>[1-CH₂CH₃]⁺</b> and <b>[1-NH₂]⁺</b> or a concerted pathway. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... per Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... per Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Impact of Photosensitizing Multilayered Structure on Ruthenium(II)-Dye-Sensitized TiO₂‑Nanoparticle Photocatalysts per Sogo Furugori (4275475)

“…Thus, crucial aspects of the energy- and electron-transfer mechanism for the photocatalytic H₂ and O₂ evolution reactions involve not only the Ru­(II)-complex-TiO₂ interface but also the multilayered structure of the Ru­(II)-photosensitizers on the Pt–TiO₂ surface.…”

Multiple sequence alignment of the NpDps4 with a selection of its homolog sequences from six cyanobacterial phylogenetic groups. per Christoph Howe (7114679)

“…Amino acids of the ferroxidase center (FOC) are indicated by an asterisk *A, *B or *A/B indicating the involvement of metal coordination at site A and/or B in regards to the His-type FOC of NpDps4 and TeDpsA. …”

Tuning the Inclusion Properties and Solid-State Reactivity of Second Sphere Adducts Using Conformationally Flexible Bidentate Ligands per Fang Guo (105824)

“…We demonstrate that some of the second sphere adducts are dynamic, showing reversible guest release/uptake involving crystalline-to-amorphous-to-crystalline phase transformations. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... per Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

New Insights into the Visible-Light-Induced DNA Cleavage Activity of Dipyridoquinoxaline Complexes of Bivalent 3d-Metal Ions per Mithun Roy (2090650)

“…The DNA cleavage reactions at visible light under aerobic conditions involve the formation of hydroxyl radical. The Co^II complex shows photocleavage of DNA under an argon atmosphere. …”

Flexible Coordination Polymers Composed of Luminescent Ruthenium(II) Metalloligands: Importance of the Position of the Coordination Site in Metalloligands per Atsushi Kobayashi (582164)

“…These results suggested that the position of the coordination site in the metalloligand played an important role not only on the structure of the porous framework but also on the structural flexibility involving the guest adsorption/desorption properties.…”