Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks -н Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units -н Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units -н Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

Polyphosphate Ions Encapsulated in Oxothiomolybdate Rings:  Synthesis, Structure, and Behavior in Solution -н Emmanuel Cadot (1606021)

“…Nevertheless, <b>1</b> remains labile, and successive equilibria were evidenced and interpreted as an ion-pair association involving a halide ion (Cl, Br, or I), responsible for the conformational change of the {P₂O₇} group within the cavity. …”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks -н Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”

The emotional impact of nature seen through the lenses of Virtual Reality (VR) and revealed through the power of expressive art PART 1 -н Gabriella Rodolico (11358915)

“…<br><br>We decided to follow a progressive planning starting from an Explorathon (https://www.explorathon.co.uk/) event with a focus on classroom teachers and progressing with a contribution to the Festival of Social Sciences(https://esrc.ukri.org/public-engagement/festival-of-social-science/) (FoSS) by involving the same teachers' classes and a total of 200 pupils from a mainstream and an ASN school. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units -н Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

Dimerization of Stu2 is required for kinetochore association. -н Matthew P. Miller (2328283)

“…For clarity, cross-links within Ndc80 complex proteins and those involving Stu2 fusion regions (extreme N-terminus and eGFP) are shown in grey. …”

Structural, Electrochemical, and Spectroscopic Investigation of Acetate Bridged Dinuclear Tetrakis-Schiff Base Macrocycles of Mn and Zn -н Subhadeep Kal (1720603)

“…The electrochemical and spectroscopic analysis of these complexes will aid in future studies involving electrocatalytic processes with related dinuclear macrocycles.…”

The Dinuclear Zn(II) Complex Catalyzed Cyclization of a Series of 2-Hydroxypropyl Aryl Phosphate RNA Models:  Progressive Change in Mechanism from Rate-Limiting P−O Bond Cleavage t... -н Shannon E. Bunn (2438131)

“…The data are analyzed in terms of a multistep process whereby a first formed complex rearranges to a reactive complex with a doubly activated phosphate coordinated to both metal ions. …”

Reversible Switching of the Coordination Modes of a Pyridine-Functionalized Quinonoid Zwitterion; Its Di- and Tetranuclear Palladium Complexes -н Alessio Ghisolfi (1588846)

“…This switch modifies the extent of π-delocalization involving the potentially antiaromatic quinonoid moiety and is accompanied by a significant color change, from red in <b>3</b> to green in <b>4</b>. …”

Organometallic Complexes of Scandium and Yttrium Supported by a Bulky Salicylaldimine Ligand -н David J. H. Emslie (1425715)

“…These compounds are highly thermally stable, decomposing at temperatures above 140 °C via a pathway involving metalation of one of the N-aryl isopropyl methyl groups. …”

Hormone-independent, EcR-mediated endoreplication of SC DNA is stimulated by mating. -н Aaron Leiblich (3211392)

“…(F) Proposed model explaining the different forms of hormone-dependent and hormone-independent, EcR-mediated SC growth in virgin and mated males. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units -н Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

[(Cp−CMe₂−Flu)₂Ln]^-[Li(ether)<i>_n</i>]⁺ (Ln = Y, La):  Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and... -н Evgueni Kirillov (1425814)

“…The fluorenyl ligands in <b>2</b> show an unprecedented η¹ bonding mode and a rare η³ bonding mode involving, respectively, a carbon atom of a phenyl ring and the bridgehead carbon atom of the central ring and the two adjacent carbon atoms of one six-membered ring. …”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks -н Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units -н Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

Synthesis and Characterization of Dimetallic Oxorhenium(V) and Dioxorhenium(VII) Compounds, and a Study of Stoichiometric and Catalytic Reactions -н James H. Espenson (2536300)

“…They, too, have similar Re₂S₂ cores that involve donor atoms from two of the dithiolate ligands; the third dithiolate chelates one of the rhenium atoms. …”

Contrasting Thermal and Photochemical Intramolecular Coupling in Alkynylphosphine Platinum(II) Complexes -н Ana García (2440420)

“…Thus, while under photochemical conditions complex <b>6</b> yields selectively [Pt]{Ph₂PC(Ph)C(Ph)PPhH}, <b>7</b>, by a ligand rearrangement coupling process involving activation of a P−C(Ph) bond, the regioisomer [Pt]{Ph₂PC(H)C(Ph)PPh₂}, <b>8</b>, is generated by a thermal activation of the P−H bond.…”

Ligand-Induced and Reductively Induced Alkyne−Isocyanide Coupling Reactions of [Mo(CNBu^t)₃(PhC⋮CPh)(η⁵-C₅Me₅)][BF₄... -н Christopher J. Adams (1847317)

“…A similar reaction of <b>4</b> with P(OMe)₃ generates [Mo{C(NHBu^t)C(Ph)C(Ph)CN}(CNBu^t){P(OMe)₃}(η⁵-C₅Me₅)][BF₄], <b>5</b>, involving the same coupling and elimination pattern. …”