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    Evidence for the Involvement of 5f Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes od Thibault Cantat (1574710)

    Izdano 2008
    “...The insertion of a second diazoalkane molecule into the sole metal−carbon bond in the mono(hydrazonato) complexes involves a high energy barrier (∼20 kcal/mol) for the zirconium(IV) system, whereas the actinides can facilitate the approach of the diazoalkane by coordination (formation of an adduct) and its insertion into the An−C bond with a very low barrier on the potential energy surface....”
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