Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks Autor Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”

Stereospecific Reaction of Molecular Halogens with Palladacyclopentadienes Containing Bidentate Nitrogen Ligands To Give 1,4-Dihalo-1,3-dienes via Palladium(IV) Intermediates Autor Ruud van Belzen (3081261)

“…The calculations also point to the possible involvement of a Pd(Br₂) complex in the early stages of the reaction. …”

Oxotungsten(VI) Chemistry of Hydrotris(3,5-dimethylpyrazol-1-yl)borate:  Hydroxodioxotungsten(VI), Trioxotungsten(VI), and (μ-Oxo)bis[dioxotungsten(VI)] Complexes Autor Aston A. Eagle (2199943)

“…Colorless, diamagnetic, air-stable LW^VIO₂(OH) [L = hydrotris(3,5-dimethylpyrazol-1-yl)borate] forms when suspensions of LW^III(CO)₃ in dimethyl sulfoxide are heated at 100 °C. …”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks Autor Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units Autor Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

CiLV-C p29 acts as an RNA-binding protein and interacts with eukaryotic initiation factor 4A (eIF4A). Autor Mikhail Oliveira Leastro (5736329)

“…Magnification in the left image highlights the alpha helix formed by the residues 155-175 and its potential involvement in RNA interaction. lDDT corresponds to a per-atom confidence estimate on a 0-100 scale where higher values indicate greater confidence. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units Autor Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

Polyphosphate Ions Encapsulated in Oxothiomolybdate Rings:  Synthesis, Structure, and Behavior in Solution Autor Emmanuel Cadot (1606021)

“…Nevertheless, <b>1</b> remains labile, and successive equilibria were evidenced and interpreted as an ion-pair association involving a halide ion (Cl, Br, or I), responsible for the conformational change of the {P₂O₇} group within the cavity. …”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks Autor Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”

The emotional impact of nature seen through the lenses of Virtual Reality (VR) and revealed through the power of expressive art PART 1 Autor Gabriella Rodolico (11358915)

“…<br><br>We decided to follow a progressive planning starting from an Explorathon (https://www.explorathon.co.uk/) event with a focus on classroom teachers and progressing with a contribution to the Festival of Social Sciences(https://esrc.ukri.org/public-engagement/festival-of-social-science/) (FoSS) by involving the same teachers' classes and a total of 200 pupils from a mainstream and an ASN school. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units Autor Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

Dimerization of Stu2 is required for kinetochore association. Autor Matthew P. Miller (2328283)

“…For clarity, cross-links within Ndc80 complex proteins and those involving Stu2 fusion regions (extreme N-terminus and eGFP) are shown in grey. …”

Structural, Electrochemical, and Spectroscopic Investigation of Acetate Bridged Dinuclear Tetrakis-Schiff Base Macrocycles of Mn and Zn Autor Subhadeep Kal (1720603)

“…The electrochemical and spectroscopic analysis of these complexes will aid in future studies involving electrocatalytic processes with related dinuclear macrocycles.…”

The Dinuclear Zn(II) Complex Catalyzed Cyclization of a Series of 2-Hydroxypropyl Aryl Phosphate RNA Models:  Progressive Change in Mechanism from Rate-Limiting P−O Bond Cleavage t... Autor Shannon E. Bunn (2438131)

“…The data are analyzed in terms of a multistep process whereby a first formed complex rearranges to a reactive complex with a doubly activated phosphate coordinated to both metal ions. …”

Reversible Switching of the Coordination Modes of a Pyridine-Functionalized Quinonoid Zwitterion; Its Di- and Tetranuclear Palladium Complexes Autor Alessio Ghisolfi (1588846)

“…This switch modifies the extent of π-delocalization involving the potentially antiaromatic quinonoid moiety and is accompanied by a significant color change, from red in <b>3</b> to green in <b>4</b>. …”

Organometallic Complexes of Scandium and Yttrium Supported by a Bulky Salicylaldimine Ligand Autor David J. H. Emslie (1425715)

“…These compounds are highly thermally stable, decomposing at temperatures above 140 °C via a pathway involving metalation of one of the N-aryl isopropyl methyl groups. …”

Hormone-independent, EcR-mediated endoreplication of SC DNA is stimulated by mating. Autor Aaron Leiblich (3211392)

“…(F) Proposed model explaining the different forms of hormone-dependent and hormone-independent, EcR-mediated SC growth in virgin and mated males. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units Autor Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

[(Cp−CMe₂−Flu)₂Ln]^-[Li(ether)<i>_n</i>]⁺ (Ln = Y, La):  Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and... Autor Evgueni Kirillov (1425814)

“…The fluorenyl ligands in <b>2</b> show an unprecedented η¹ bonding mode and a rare η³ bonding mode involving, respectively, a carbon atom of a phenyl ring and the bridgehead carbon atom of the central ring and the two adjacent carbon atoms of one six-membered ring. …”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks Autor Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”