Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... af Shih-Huang Huang (2148001)

“...On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. ...”

Proton-Coupled Electron Transfer to a Molybdenum Ethylene Complex Yields a β‑Agostic Ethyl: Structure, Dynamics and Mechanism af Máté J. Bezdek (1980178)

“...Comparison of p<i>K</i>_a and electrochemical data for the complexes <b>[1-C₂H₄]⁺</b> and <b>[1-NH₃]⁺</b> in combination with a deuterium kinetic isotope effect (<i>k</i>_H/<i>k</i>_D) of 3.5(2) at 23 °C support a PCET process involving initial electron transfer followed by protonation leading to the formation of <b>[1-CH₂CH₃]⁺</b> and <b>[1-NH₂]⁺</b> or a concerted pathway. ...”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... af Shih-Huang Huang (2148001)

“...On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. ...”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... af Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”

Impact of Photosensitizing Multilayered Structure on Ruthenium(II)-Dye-Sensitized TiO₂‑Nanoparticle Photocatalysts af Sogo Furugori (4275475)

“...Thus, crucial aspects of the energy- and electron-transfer mechanism for the photocatalytic H₂ and O₂ evolution reactions involve not only the Ru­(II)-complex-TiO₂ interface but also the multilayered structure of the Ru­(II)-photosensitizers on the Pt–TiO₂ surface....”

Multiple sequence alignment of the NpDps4 with a selection of its homolog sequences from six cyanobacterial phylogenetic groups. af Christoph Howe (7114679)

“...Amino acids of the ferroxidase center (FOC) are indicated by an asterisk *A, *B or *A/B indicating the involvement of metal coordination at site A and/or B in regards to the His-type FOC of NpDps4 and TeDpsA. ...”

Tuning the Inclusion Properties and Solid-State Reactivity of Second Sphere Adducts Using Conformationally Flexible Bidentate Ligands af Fang Guo (105824)

“...We demonstrate that some of the second sphere adducts are dynamic, showing reversible guest release/uptake involving crystalline-to-amorphous-to-crystalline phase transformations. ...”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... af Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”

New Insights into the Visible-Light-Induced DNA Cleavage Activity of Dipyridoquinoxaline Complexes of Bivalent 3d-Metal Ions af Mithun Roy (2090650)

“...The DNA cleavage reactions at visible light under aerobic conditions involve the formation of hydroxyl radical. The Co^II complex shows photocleavage of DNA under an argon atmosphere. ...”

Flexible Coordination Polymers Composed of Luminescent Ruthenium(II) Metalloligands: Importance of the Position of the Coordination Site in Metalloligands af Atsushi Kobayashi (582164)

“...These results suggested that the position of the coordination site in the metalloligand played an important role not only on the structure of the porous framework but also on the structural flexibility involving the guest adsorption/desorption properties....”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... af Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... af Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... af Shih-Huang Huang (2148001)

“...On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. ...”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... af Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... af Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”

P−C and C−C Bond Formation by Michael Addition in Platinum-Catalyzed Hydrophosphination and in the Stoichiometric Reactions of Platinum Phosphido Complexes with Activated Alkenes... af Corina Scriban (1989502)

“...Subsequent C−H bond formation involving the Pt−H and the carbanion would yield the product R₂PCH₂CH₂X (<b>3</b>) and regenerate the catalyst, while attack of the carbanion on another alkene would yield byproducts derived from more than one alkene, such as R₂P(CH₂CH(X))<i>_n</i>CH₂CH₂X (<b>7</b>). ...”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... af Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”

New Insights into the Visible-Light-Induced DNA Cleavage Activity of Dipyridoquinoxaline Complexes of Bivalent 3d-Metal Ions af Mithun Roy (2090650)

“...The DNA cleavage reactions at visible light under aerobic conditions involve the formation of hydroxyl radical. The Co^II complex shows photocleavage of DNA under an argon atmosphere. ...”

Nyamsuren, I., Mitchell, E., and Tsay, J. (April 27 - May 2, 2025), <i>Learning Sign Language with Real-Time Kinematic Feedback</i> [Poster Presentation]. The Annual Meeting of the... af Indranil Nyamsuren (21498833)

“...At the baseline stage, participants attempted to guess the signs for 24 letters of the ASL alphabet without any cues (we excluded the letters J and Z because signs that involve movement are more difficult to recognize). ...”

Valve Sparing in Type A Aortic Dissection af Vishal Shah (5651)

“...<br><br>Given the extensive involvement of the aortic root and the age of the patient, a decision was made to perform a valve sparing surgery. ...”