Lactone Radical Cyclizations and Cyclization Cascades Mediated by SmI₂–H₂O по Dixit Parmar (2059843)

“...The cyclizations proceed by the trapping of radical anions formed by electron transfer reduction of the lactone carbonyl....”

1,4-Hydroboration Reactions of Electron-Poor Aromatic Rings by N‑Heterocyclic Carbene Boranes по Wen Dai (1607932)

“...When regioisomers are possible, the more crowded (doubly ortho-substituted) product is formed preferably or exclusively. The mechanism may involve oxidation of the NHC-borane to an NHC-boryl radical, reduction of the electron-poor aromatic ring to a radical anion, coupling of the radical and the radical anion to give a cyclohexadienyl anion, and finally regioselective protonation....”

1,4-Hydroboration Reactions of Electron-Poor Aromatic Rings by N‑Heterocyclic Carbene Boranes по Wen Dai (1607932)

“...When regioisomers are possible, the more crowded (doubly ortho-substituted) product is formed preferably or exclusively. The mechanism may involve oxidation of the NHC-borane to an NHC-boryl radical, reduction of the electron-poor aromatic ring to a radical anion, coupling of the radical and the radical anion to give a cyclohexadienyl anion, and finally regioselective protonation....”

A Tunable Route for the Synthesis of Azomethine Imines and β‑Aminocarbonyl Compounds from Alkenes по Christian Clavette (1968556)

“...A thermal, concerted alkene aminocarbonylation pathway involving an imino-isocyanate intermediate is proposed and supported by DFT calculations. ...”

The Isolation of [Pd{OC(O)H}(H)(NHC)(PR₃)] (NHC = N‑Heterocyclic Carbene) and Its Role in Alkene and Alkyne Reductions Using Formic Acid по Julie Broggi (1977043)

“...The [Pd­(SIPr)­(PCy₃)] complex efficiently promotes a tandem process involving dehydrogenation of formic acid and hydrogenation of C–C multiple bonds using H₂ formed in situ. ...”

Chain Transfer to Solvent in Propene Polymerization with Ti Cp-phosphinimide Catalysts: Evidence for Chain Termination via Ti–C Bond Homolysis по Christian Ehm (1593097)

“...End-group analysis suggests that these are formed after a 2,1-insertion event; density functional theory (DFT) studies support a mechanism involving homolysis of a Ti-<i>sec</i>-alkyl bond. ...”

Evidence for late apoptotic events induced by manuka honey in cancer cells. по Maria J. Fernandez-Cabezudo (284773)

“...Whole cell extracts (100 µg/lane) were resolved on 10% SDS-PAGE followed by Western blotting with an antibody specific to Bcl-2. ...”

CGGBP1 from higher amniotes restricts cytosine methylation and drives a GC-bias in transcription factor-binding sites at repressed promoters по Praveen Kumar (8242)

“...Our experiments using four representative and three consensus forms of CGGBPs and orthology analyses of target gene promoters indicate that this property of CGGBPs has most likely evolved in higher amniotes (aves and mammals) with lineage-specific heterogeneities in lower amniotes (reptiles). ...”

Supplementary Material for: Cleft Lip Palate in a Patient with 5q14.3 Deletion Syndrome: A Possible Unreported Feature? по FernándezHernández L. (11937293)

“...To date, nearly 40 cases have been reported; the deletion size and clinical spectrum are variable, and at least 6 cases without <i>MEF2C</i> involvement have been documented. We herein report the clinical and cytogenomic findings of an 11-year-old girl who has a 5q14.3q21.1 de novo deletion that does not involve <i>MEF2C</i> but shares the clinical features described in other reported patients. ...”

Supplementary Material for: A first case of acute flaccid myelitis related to enterovirus D-68 in Belgium по Rodesch M. (17844509)

“...The magnetic resonance imaging (MRI) revealed an increased T2 signal intensity of the entire central gray matter of the cervical cord with involvement of the posterior brainstem. A polymerase-chain-reaction (PCR) conducted on a naso-pharyngeal swab was found positive for EV-D68. ...”

Halogen Bonding inside a Molecular Container по Hamdy S. El-Sheshtawy (1290636)

“...The synthetic macrocycle cucurbit[6]­uril forms host–guest inclusion complexes with molecular dibromine and diiodine. ...”

Dissecting a Role for Melanopsin in Behavioural Light Aversion Reveals a Response Independent of Conventional Photoreception по Ma'ayan Semo (235782)

“...<div><p>Melanopsin photoreception plays a vital role in irradiance detection for non-image forming responses to light. However, little is known about the involvement of melanopsin in emotional processing of luminance. ...”

Direct Catalytic Asymmetric Synthesis of <i>anti</i>-1,2-Amino Alcohols and <i>syn</i>-1,2-Diols through Organocatalytic <i>anti</i>-Mannich and <i>syn</i>-Aldol Reactions по S. S. V. Ramasastry (1358289)

“...To date, however, approaches involving organocatalysis have been limited to the syntheses of the <i>syn</i>-1,2-amino alcohols and <i>anti</i>-1,2-diols. ...”

Data_Sheet_1_Homoacetogenic Conversion of Mannitol by the Thermophilic Acetogenic Bacterium Thermoanaerobacter kivui Requires External CO2.pdf по Jimyung Moon (9377255)

“...We found an acetate:mannitol ratio higher than 3, indicating the requirement of external CO₂, and the involvement of the WLP as terminal electron accepting pathway. ...”

Halogen Bonding inside a Molecular Container по Hamdy S. El-Sheshtawy (1290636)

“...The synthetic macrocycle cucurbit[6]­uril forms host–guest inclusion complexes with molecular dibromine and diiodine. ...”

Supplementary Material for: Development of a Multinational Clinical Practice Guideline: A Practical Structured Procedure по Sonyi M. (9562001)

“...For persons contributing to the guideline process, different levels of involvement were defined. The tasks were assigned to different groups of persons, which formed scientific institutions. ...”

Data Sheet 1_Correlation of heat shock protein 1 expression with progression and prognosis of non-small cell lung cancer.pdf по Rui Wang (52434)

“...</p>Results<p>The high expression of HSPH1 in NSCLC was significantly correlated with the clinical characteristics and poor prognosis of patients, and it may affect the progression of NSCLC by forming a regulatory network with molecules such as HSPA8, BAG2, etc., and its mechanism may involve the regulation of the P53 signalling pathway, G2M_CHECKPOINT and mTORC1_SGNALING. ...”

Lesions of the Fasciculus Retroflexus Alter Footshock-Induced cFos Expression in the Mesopontine Rostromedial Tegmental Area of Rats по Paul Leon Brown (402126)

“...It has been hypothesized that habenular input to midbrain dopamine neurons is conveyed via a feedforward inhibitory pathway involving the GABAergic mesopontine rostromedial tegmental area. ...”

Data Sheet 1_Roles of health promotion researchers in the planning stages of a global urban health promotion initiative: understandings identified from an interview-based case stud... по Sophie Meyer (374556)

“...</p>Results<p>We identified three diverging types of local researchers’ roles understandings: (1) active deep involvement in collaborative arrangements, (2) balancing between active involvement and passively supporting, and (3) passively supporting the initiative. ...”

Synthesis of Hexahydro‑1<i>H</i>‑isoindole Derivatives from Arylacyl Bromides via Homoallenic Bromohydrins по Mei-Huey Lin (1651900)

“...The approach employs a sequence involving an initial indium-mediated allenylation reaction of an arylacyl bromide with propargyl bromide. ...”