Copper, Nickel, and Zinc Cyclam–Amino Acid and Cyclam–Peptide Complexes May Be Synthesized with “Click” Chemistry and Are Noncytotoxic by Mingfeng Yu (591016)

“…We describe the synthesis of cyclam metal complexes derivatized with amino acids or a tripeptide using a copper(I)-catalyzed Huisgen “click” reaction. The linker triazole formed during the synthesis plays an active coordinating role in the complexes. …”

Electrochemically Mediated Oxidative Transformations of Substituted 4‑Methoxystilbenes: Effect of Ortho-Substituted Nucleophilic Groups by Kam-Weng Chong (1715197)

“…Where an additional 3-methoxy substituent is present, bridged oxocine/azocine products are formed in addition to the bisbenzopyrans/bisquinolines and bisbenzofurans/bisindoles. …”

Electrochemically Mediated Oxidative Transformations of Substituted 4‑Methoxystilbenes: Effect of Ortho-Substituted Nucleophilic Groups by Kam-Weng Chong (1715197)

“…Where an additional 3-methoxy substituent is present, bridged oxocine/azocine products are formed in addition to the bisbenzopyrans/bisquinolines and bisbenzofurans/bisindoles. …”

Copper, Nickel, and Zinc Cyclam–Amino Acid and Cyclam–Peptide Complexes May Be Synthesized with “Click” Chemistry and Are Noncytotoxic by Mingfeng Yu (591016)

“…We describe the synthesis of cyclam metal complexes derivatized with amino acids or a tripeptide using a copper(I)-catalyzed Huisgen “click” reaction. The linker triazole formed during the synthesis plays an active coordinating role in the complexes. …”

Copper, Nickel, and Zinc Cyclam–Amino Acid and Cyclam–Peptide Complexes May Be Synthesized with “Click” Chemistry and Are Noncytotoxic by Mingfeng Yu (591016)

“…We describe the synthesis of cyclam metal complexes derivatized with amino acids or a tripeptide using a copper(I)-catalyzed Huisgen “click” reaction. The linker triazole formed during the synthesis plays an active coordinating role in the complexes. …”

Electrochemically Mediated Oxidative Transformations of Substituted 4‑Methoxystilbenes: Effect of Ortho-Substituted Nucleophilic Groups by Kam-Weng Chong (1715197)

“…Where an additional 3-methoxy substituent is present, bridged oxocine/azocine products are formed in addition to the bisbenzopyrans/bisquinolines and bisbenzofurans/bisindoles. …”

Electrochemically Mediated Oxidative Transformations of Substituted 4‑Methoxystilbenes: Effect of Ortho-Substituted Nucleophilic Groups by Kam-Weng Chong (1715197)

“…Where an additional 3-methoxy substituent is present, bridged oxocine/azocine products are formed in addition to the bisbenzopyrans/bisquinolines and bisbenzofurans/bisindoles. …”

Electrochemically Mediated Oxidative Transformations of Substituted 4‑Methoxystilbenes: Effect of Ortho-Substituted Nucleophilic Groups by Kam-Weng Chong (1715197)

“…Where an additional 3-methoxy substituent is present, bridged oxocine/azocine products are formed in addition to the bisbenzopyrans/bisquinolines and bisbenzofurans/bisindoles. …”

<i>In vivo</i> voxel based morphometry identified areas of significant enlargement in trained animals relative to the controls. by Alexandra Badea (352052)

“…Uncorrected statistical maps (shown in yellow) suggested involvement of the ipsilateral hemisphere as well.</p>…”

Pan-KRAS inhibition selectively halts proliferation of KRAS G12S HOS-143B cells. by Okkeun Jung (21243431)

“…(B) Proliferation assay across three days of treatment with DMSO or 5 nM daraxonrasib in HOS and 143B cell lines. (C-D) Colony forming assay and quantification of colony numbers of (C) HOS-143B and (D) HOS. …”

Functional model of ternary interactions of BoNT/B, DC, and G with the neuronal membrane. by Daniel Stern (213946)

“…<p>BoNT (H_C, green oval; H_C loop, red) forms a highly stable BoNT-receptors complex, involving an SV protein (Syt-II, green helix), a carbohydrate portion (empty hexagons) of gangliosides, and membrane lipids, that is critical to confer the toxin’s exquisite toxicity. …”

Observation of Liquid–Liquid-Phase Separation and Vesicle Spreading during Supported Bilayer Formation via Liquid-Phase Transmission Electron Microscopy by Aoon Rizvi (3829255)

“…We observe two formation pathways that involve either liquid droplets or vesicles as intermediates toward supported bilayers. …”

Observation of Liquid–Liquid-Phase Separation and Vesicle Spreading during Supported Bilayer Formation via Liquid-Phase Transmission Electron Microscopy by Aoon Rizvi (3829255)

“…We observe two formation pathways that involve either liquid droplets or vesicles as intermediates toward supported bilayers. …”

Hydrogen-Bond Architectures of Protonated 4,4′-Biimidazolium Derivatives and Oligo(imidazolium)s in Charge-Transfer Salts with Tetracyanoquinodimethane by Tsuyoshi Murata (1939669)

“…Structural analyses revealed that the protonated 4,4′-biimidazolium derivatives formed multidirectional and multidimensional hydrogen bonds with TCNQ, and constructed two kinds of self-assembled architectures: one-dimensional chainlike motifs involving TCNQ molecules and two-dimensional sheet structures composed of the alternation of segregated columns of 4,4′-biimidazolium and TCNQ. …”

Crystal Chemistry of the Gold (I) Trimer, Au₃(NC₅H₄)₃:  Formation of Hourglass Figures and Self-Association through Aurophilic Attractio... by Akari Hayashi (2268202)

“…X-ray crystallography reveals that individual molecules of Au₃(NC₅H₄)₃ self-associate through aurophilic interactions into two distinct structural motifs that involve both extended chains of molecules connected by pairwise Au···Au contacts and individual Au···Au contacts and discrete dimers linked by pairwise Au···Au contacts. …”

Imine Hydrolysis and Role of a Rhodium(I)−Imine−Amine Complex in Homogeneous H₂-Hydrogenation of the Imine and a Rare Example of Inequivalent NH₂ Protons by Paolo Marcazzan (2688205)

“…A Rh-catalyzed, homogeneous hydrogenation of the imine, PhCH₂NCHPh, is shown to involve a Rh−imine−amine species that subsequently activates H₂, the amine (benzylamine) being formed via a Rh-catalyzed hydrolysis of the imine by adventitious water. …”

Enantioselective Synthesis of β‑Allenoates via Phosphine-Catalyzed and ZnI₂‑Promoted Preparation of Oxazolidines and Propargylamines Using Chiral Amines, 1‑Alkynes, and... by Mariappan Periasamy (1393039)

“…The results are discussed considering a mechanism involving oxazolidine and iminium ions formed <i>in situ</i> followed by addition of alkynyl zinc complex to produce the propargylamine that gives the corresponding allenoate via a 1,5-hydrogen shift in the presence of ZnI₂.…”

Probing the Mechanism of the PCl₅−Initiated Living Cationic Polymerization of the Phosphoranimine Cl₃PNSiMe₃ using Model Compound Chemistry by Vivienne Blackstone (2042818)

“…In addition, experiments involving [Ph₃PNPPh₃][PCl₆] ([<b>9</b>][PCl₆]) and the <i>N</i>-silylphosphoranimines R₃PNSiMe₃ <b>3a</b> (R = Ph) and <b>3b</b> (R = <i>p</i>-CF₃C₆H₄), showed that the [PCl₆]⁻ anion, which is formed in the early stages of the polymerization and has hitherto been assumed to be an innocent spectator counteranion, is actually reactive under the reaction conditions and can initiate oligomerization and polymerization. …”

Probing the Mechanism of the PCl₅−Initiated Living Cationic Polymerization of the Phosphoranimine Cl₃PNSiMe₃ using Model Compound Chemistry by Vivienne Blackstone (2042818)

“…In addition, experiments involving [Ph₃PNPPh₃][PCl₆] ([<b>9</b>][PCl₆]) and the <i>N</i>-silylphosphoranimines R₃PNSiMe₃ <b>3a</b> (R = Ph) and <b>3b</b> (R = <i>p</i>-CF₃C₆H₄), showed that the [PCl₆]⁻ anion, which is formed in the early stages of the polymerization and has hitherto been assumed to be an innocent spectator counteranion, is actually reactive under the reaction conditions and can initiate oligomerization and polymerization. …”

Probing the Mechanism of the PCl₅−Initiated Living Cationic Polymerization of the Phosphoranimine Cl₃PNSiMe₃ using Model Compound Chemistry by Vivienne Blackstone (2042818)

“…In addition, experiments involving [Ph₃PNPPh₃][PCl₆] ([<b>9</b>][PCl₆]) and the <i>N</i>-silylphosphoranimines R₃PNSiMe₃ <b>3a</b> (R = Ph) and <b>3b</b> (R = <i>p</i>-CF₃C₆H₄), showed that the [PCl₆]⁻ anion, which is formed in the early stages of the polymerization and has hitherto been assumed to be an innocent spectator counteranion, is actually reactive under the reaction conditions and can initiate oligomerization and polymerization. …”