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28521
Stereoselectivity in the Formation of Metallomacrocycles from [Mo(NO){HB(3,5-Me<sub>2</sub>C<sub>3</sub>HN<sub>2</sub>)<sub>3</sub>}I<sub>2</sub>] and Ditopic Proligands: The X-ra...
Опубліковано 1999“...These binuclear complexes are formed under kinetic control so that <i>syn</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2s</b>, forms more rapidly than <i>anti</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2a</b>, but in lower yield. ...”
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28522
Mixed-Metal Cluster Chemistry. 30. Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes
Опубліковано 2007“...Some insight into the mechanism by which these clusters function as optical limiters has been gleaned from complementary pump−probe studies, with their behavior consistent with a fast nonlinear absorption process followed by reverse saturable absorption involving metastable excited states of greater than nanosecond lifetime....”
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28523
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
Опубліковано 1997“...The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. ...”
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28524
Eh!woza Learner Doccies
Опубліковано 2023“...</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. ...”
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28525
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Опубліковано 2020“...The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product....”
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28526
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Опубліковано 2025“...Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. ...”
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28527
Degradation of triazine-2-14C metsulfuron–methyl in soil from an oil palm plantation
Опубліковано 2015“...Lastly the ethylene glycol bottle was connected to a 0.1 M KOH (25 mL) bottle to trap 14CO2 evolved as a result of microbial activity (Fig. 1). ...”