Image_1_Impaired Thymic Output Can Be Related to the Low Immune Reconstitution and T Cell Repertoire Disturbances in Relapsing Visceral Leishmaniasis Associated HIV/AIDS Patients.T... di Maria Luciana Silva-Freitas (3372833)

“...Our aim was to evaluate if this gain of T cells was related to changes in the peripheral TCRVβ repertoire and inflammatory status, as well as the possible thymus involvement in the replenishment of these newly formed T lymphocytes....”

Image_3_Impaired Thymic Output Can Be Related to the Low Immune Reconstitution and T Cell Repertoire Disturbances in Relapsing Visceral Leishmaniasis Associated HIV/AIDS Patients.T... di Maria Luciana Silva-Freitas (3372833)

“...Our aim was to evaluate if this gain of T cells was related to changes in the peripheral TCRVβ repertoire and inflammatory status, as well as the possible thymus involvement in the replenishment of these newly formed T lymphocytes....”

Image_4_Impaired Thymic Output Can Be Related to the Low Immune Reconstitution and T Cell Repertoire Disturbances in Relapsing Visceral Leishmaniasis Associated HIV/AIDS Patients.T... di Maria Luciana Silva-Freitas (3372833)

“...Our aim was to evaluate if this gain of T cells was related to changes in the peripheral TCRVβ repertoire and inflammatory status, as well as the possible thymus involvement in the replenishment of these newly formed T lymphocytes....”

The effect of tachypleginA on TgMLC1 is rapid, irreversible and only occurs in intact parasites. di Aoife T. Heaslip (207534)

“...The unmodified and modified forms of TgMLC1 are indicated with blue and red arrows, respectively. ...”

Table_1_Myelin Oligodendrocyte Glycoprotein (MOG) Antibody Positive Patients in a Multi-Ethnic Canadian Cohort.XLSX di Helen Cross (3484394)

“...NMOSD seronegative patients, and those with limited forms of the disorder, become suspects for MOG antibody-associated disease. ...”

Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde di Jurjen Meeuwissen (2292484)

“...Complex studies on the 2:1 complex of phosphinourea to [Rh(acac)(CO)₂] showed that a neutral <i>trans</i>-coordinating complex [Rh(<i>H</i>L-κ<i>P</i>)(L-κ²<i>O</i>,<i>P</i>)(CO)] was formed. An anionic <i>O</i>,<i>P</i>-chelating ligand has displaced the anionic acac⁻ ligand via an acid−base reaction involving the deprotonation of an acidic urea proton, giving <i>H</i>acac. ...”

Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic... di Kyle G. Lewis (1355400)

“...It is found that Werner complexes based upon the D₃ symmetric chiral trication [Co­(en)₃]³⁺ (en = 1,2-ethylenediamine), which features an earth abundant metal and cheap ligand type, and was among the first inorganic compounds resolved into enantiomers 103 years ago, catalyze a valuable carbon–carbon bond forming reaction, the Michael addition of malonate esters to nitroalkenes, in high enantioselectivities and without requiring inert atmosphere conditions. ...”

Supporting data for PhD thesis: Advancing Protein Chemical Synthesis: Knorr Pyrazole Synthesis Mediated Salicylaldehyde Esters Regeneration In TIM-1 Synthesis and Prior Disulfide B... di Xiaolin Cheng (11147973)

“...To overcome this challenge, we developed a new strategy involving the precise formation of disulfide bonds prior to refolding, thereby eliminating the usage of redox systems and ensuring the acquisition of high-fidelity native disulfide arrangement. ...”

Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic... di Kyle G. Lewis (1355400)

“...It is found that Werner complexes based upon the D₃ symmetric chiral trication [Co­(en)₃]³⁺ (en = 1,2-ethylenediamine), which features an earth abundant metal and cheap ligand type, and was among the first inorganic compounds resolved into enantiomers 103 years ago, catalyze a valuable carbon–carbon bond forming reaction, the Michael addition of malonate esters to nitroalkenes, in high enantioselectivities and without requiring inert atmosphere conditions. ...”

Synthesis, Crystal Structure, Aqueous Speciation, and Kinetics of Substitution Reactions in a Water-Soluble Mo₃S₄ Cluster Bearing Hydroxymethyl Diphosphine Li... di Andrés G. Algarra (2478166)

“...However, whereas the first two steps involve the opening of the chelate rings formed with the alkoxo groups of the dhmpe ligands, the third one corresponds to the substitution of the coordinated water molecule. ...”

Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic... di Kyle G. Lewis (1355400)

“...It is found that Werner complexes based upon the D₃ symmetric chiral trication [Co­(en)₃]³⁺ (en = 1,2-ethylenediamine), which features an earth abundant metal and cheap ligand type, and was among the first inorganic compounds resolved into enantiomers 103 years ago, catalyze a valuable carbon–carbon bond forming reaction, the Michael addition of malonate esters to nitroalkenes, in high enantioselectivities and without requiring inert atmosphere conditions. ...”

Synthesis and Structural Characterization of an Unprecedented Nonmetal Cation Polyborate Salt Containing Two Different “Isolated” Polyborate Anions: [H₂en]₂[B... di Michael A. Beckett (129337)

“...The structure is templated by the cations with the anions forming a supramolecular H-bonded network, augmented by additional H-bonds involving the waters of crystallization and the cations....”

Two Novel Nanoporous Supramolecular Architectures Based on Copper(I) Coordination Polymers with Uniform (8, 3) and (8²10) Nets:  In Situ Formation of Tetrazolate Ligands... di Tao Wu (16763)

“...The hydro/solvothermal reactions of Cu(I)/Cu(II) salt, NaN₃, and acetonitrile in water or methanol yield two noninterpenetrated supramolecular networks containing 1D hexagonal and square nanochannels, {[Cu(Mtta)]·0.17H₂O}<i>_n</i>(<b>1</b>) and its pseudopolymorph [Cu(Mtta)]<i>_n</i> (<b>2</b>) (Mtta = 5-methyl tetrazolate), involving ligand in-situ formation by cycloaddition of nitriles and azides. ...”

Preferential Precipitation and Selective Separation of Rh(III) from Pd(II) and Pt(IV) Using 4‑Alkylanilines as Precipitants di Kazuya Matsumoto (396968)

“...Here, a selective Rh separation method involving the precipitation of Rh from an HCl solution containing palladium (Pd), platinum (Pt), and Rh is reported. 4-Butylaniline and 4-hexylaniline were used as precipitants for Rh, and selective Rh precipitation was achieved at high HCl concentrations. ...”

Efficient Synthesis of 3-Chloromethyl-2(5<i>H</i>)-furanones and 3-Chloromethyl- 5,6-dihydropyran-2-ones via the PdCl₂-Catalyzed Chlorocyclocarbonylation of 2,3- or 3,4-... di Xin Cheng (179584)

“...A mild and efficient methodology involving PdCl₂-catalyzed chlorocyclocarbonylation of 2,3- or 3,4-allenols with CuCl₂ for the synthesis of 3-chloromethyl-2(5<i>H</i>)-furanones and 3-chloromethyl-5,6-dihydropyran-2-ones was developed. ...”

Two Novel Nanoporous Supramolecular Architectures Based on Copper(I) Coordination Polymers with Uniform (8, 3) and (8²10) Nets:  In Situ Formation of Tetrazolate Ligands... di Tao Wu (16763)

“...The hydro/solvothermal reactions of Cu(I)/Cu(II) salt, NaN₃, and acetonitrile in water or methanol yield two noninterpenetrated supramolecular networks containing 1D hexagonal and square nanochannels, {[Cu(Mtta)]·0.17H₂O}<i>_n</i>(<b>1</b>) and its pseudopolymorph [Cu(Mtta)]<i>_n</i> (<b>2</b>) (Mtta = 5-methyl tetrazolate), involving ligand in-situ formation by cycloaddition of nitriles and azides. ...”

Generalisation experiments. di Miguel Brun-Usan (8703918)

“...Similar experiments yield poor performances when cells have to evolve complex forms of plasticity (blue line below the green one, see main text). ...”

Phosphinite-Ni(0) Mediated Formation of a Phosphide-Ni(II)-OCOOMe Species via Uncommon Metal–Ligand Cooperation di Yeong-Eun Kim (1622962)

“...Thus, unanticipated metal–ligand cooperation involving a phosphide based ligand is reported....”

Applications of multiple reaction monitoring targeted proteomics assays in human plasma di Georgia Kontostathi (6709712)

“...Additionally, clinical aspects involving careful study design to address biomarker clinical use should also be considered....”

Plasticity of the Nickel(II) Coordination Environment in Complexes with Hemilabile Phosphino Thioether Ligands di Charles W. Machan (1417663)

“...A series of homoligated Ni(II) complexes formed from two phosphino thioether (P,S) chelating ligands has been synthesized and characterized. ...”