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31501
Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C–H Bond Functionalization Reactions
יצא לאור 2023"...An investigation into species formed following precatalyst activation in Mn-catalyzed C–H bond functionalization reactions is reported. ..."
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31502
S117 dephosphorylation is required for BAK multimerization.
יצא לאור 2012"...Note that BMOE detects only monomeric and dimeric forms of BAK. (<b>F</b>) Purified active PP2A directly dephosphorylated BAK at S117. ..."
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31503
Kinetics and Mechanistic Aspects of As(III) Oxidation by Aqueous Chlorine, Chloramines, and Ozone: Relevance to Drinking Water Treatment
יצא לאור 2006"...NH<sub>3</sub> had negligible effect on the efficiency of As(III) oxidation by O<sub>3</sub>, due to the slow kinetics of the O<sub>3</sub>−NH<sub>3</sub> reaction at circumneutral pH. Time-resolved measurements of As(III) loss during chlorination and ozonation of real waters were accurately modeled using the rate constants determined in this investigation...."
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31504
A Phase I Double Blind, Placebo-Controlled, Randomized Study of a Multigenic HIV-1 Adenovirus Subtype 35 Vector Vaccine in Healthy Uninfected Adults
יצא לאור 2012"...The median spot forming cells (SFC) per 10<sup>6</sup> PBMC to any antigen was 78–139 across Groups A–C and 158–174 in Group D, after each of the vaccinations with a maximum of 2991 SFC. ..."
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31505
140 H/D Isotopomers Identified by Long-Range NMR Hyperfine Shifts in Ruthenium(III) Ammine Complexes. Hyperconjugation in Ru–NH<sub>3</sub> Bonding
יצא לאור 2013"...When traces of partially deuterated water are present, instead of a single cyclopentadienyl (Cp) resonance shifted by the hyperfine interaction, numerous well-resolved resonances are observed. The spectra were simulated satisfactorily by giving the appropriate statistical weight to 140 possible H/D isotopomers formed by deuteration in the five ruthenium(III) ammine ligands. ..."
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31506
MIL-96, a Porous Aluminum Trimesate 3D Structure Constructed from a Hexagonal Network of 18-Membered Rings and <i>μ</i><sub>3</sub>-Oxo-Centered Trinuclear Units
יצא לאור 2006"...The four aluminum crystallographic sites are resolved by means of <sup>27</sup>Al 3QMAS technique. ..."
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31507
Voltammetric and Spectroscopic Studies of α- and β‑[PW<sub>12</sub>O<sub>40</sub>]<sup>3–</sup> Polyoxometalates in Neutral and Acidic Media: Structural Characterization as Their [...
יצא לאור 2017"...<sup>183</sup>W NMR spectra of the oxidized forms of the PW<sub>12</sub> isomers are acid dependent and in the case of β-PW<sub>12</sub> imply that the bridging oxygens between the W<sub>I</sub> and W<sub>II</sub> units are preferentially protonated in acidic media. ..."
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31508
Synthesis and Characterization of Phosphorescent Cyclometalated Platinum Complexes
יצא לאור 2002"...Reaction of K<sub>2</sub>PtCl<sub>4</sub> with a <i>HC</i><sup>∧</sup><i>N</i> ligand precursor forms the chloride-bridged dimer, <i>C</i><sup>∧</sup><i>N</i>Pt(μ-Cl)<sub>2</sub>Pt<i>C</i><sup>∧</sup><i>N</i>, which is cleaved with β-diketones such as acetyl acetone (acacH) and dipivaloylmethane (dpmH) to give the corresponding monomeric <i>C</i><sup>∧</sup><i>N</i>Pt(<i>O</i><sup>∧</sup><i>O</i>) complex. ..."
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31509
GAPDH protein in the oocyte nucleus and cytoplasm.
יצא לאור 2023"...The three fastest migrating species of human GAPDH resolved by native PAGE are provisionally identified as the enzyme’s monomeric, dimeric and tetrameric forms. ..."
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31510
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
יצא לאור 1997"...The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. ..."
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31511
Examining prediction formation in empirical and model position representations.
יצא לאור 2025"...In the main analysis we consider the ‘steady state’ of position representations formed after sustained exposure to motion along a predictable trajectory, and found evidence of progressive extrapolation. ..."
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31512
Associations between zircon and Fe–Ti oxides in Hiltaba event magmatic rocks, South Australia: atomic- or pluton-scale processes?
יצא לאור 2019"...The lack of pre-magmatic zircon, consistent intra-grain and inter-grain zircon compositional trends, the predominance of oscillatory zoned zircon with morphologies indicating growth from hot, evolved silicate melts, and the lack of evidence for zircon recrystallisation, indicates that zircon crystallised in the host GRV and RDG magmas. ..."
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31513
Mutations in DNA polymerase III both drive mutation rate increase by 1,000-fold (DnaQ<sup>L145P</sup>; ε subunit) and rescue fitness of hypermutator clones (DnaE<sup>T771S</sup>; α...
יצא לאור 2020"...AA, amino acids; CFU, colony-forming units; Glu, glucose; LB, lysogeny broth; Nal<sup>R</sup>, nalidixic acid resistance; ns, not significant; OD<sub>600nm</sub>, optical density at 600 nm; PDB, Protein Data Bank; Rif<sup>R</sup>, rifampicin resistance; Sor, sorbitol...."
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31514
Expression and localization of the DEN1 homolog DenA (AN10456) during development of the fungus <i>Aspergillus nidulans</i>.
יצא לאור 2013"...In the presence of light <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-vonZeskaKress1" target="_blank">[4]</a> an aerial filament with an apical vesicle forms the asexual developmental structure (conidiophore) <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-Morimoto1" target="_blank">[5]</a> and releases the uninucleate conidiospores (green) into the air. ..."
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31515
Eh!woza Learner Doccies
יצא לאור 2023"...</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. ..."
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31516
New Amine-Templated Zinc Phosphates with a Temperature-Induced Increase of Structural Dimensionality
יצא לאור 2005"...The complete hydrogen-bond scheme is resolved for these new compounds and reveals some interesting phenomena, for example, a hydrogen shared between two phosphate groups in <b>AU</b><b>-</b><b>II</b>, thereby forming H<sub>0.5</sub>PO<sub>4</sub> groups. ..."
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31517
The 5HT<sub>1B</sub>R−mini-G<sub>o1</sub> complex.
יצא לאור 2017"...Free GFP-mini-G<sub>o1</sub> (green) resolved as a predominant peak with a retention volume of 14.9 ml (<b>d</b>) Mini-G<sub>o1</sub> forms a complex with purified 5HT<sub>1B</sub>R. ..."
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31518
Hydrolysis of polyphosphate (poly-P<sub>130</sub>) mediated by cell free extracts of <i>Escherichia coli</i> CF6032 (<i>ΔgppA Δppkx</i>) and <i>Mycobacterium smegmatis</i> mc<sup>2...
יצא לאור 2012"...Reaction mixtures were resolved on TBE 12% polyacrylamide gels, and stained with toluidine blue, to analyze the polyphosphate products formed. ..."
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31519
Direct Kinetics and Product Measurement of Phenyl Radical + Ethylene
יצא לאור 2020"...At 600 K and 10 Torr, the yield ratio of the H-abstraction reaction (forming benzene + C<sub>2</sub>H<sub>3</sub>) is measured to be 1.1% and the H-loss channel (styrene + H) has a 2.5% yield ratio. ..."
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31520
Phase Stability in the Systems AeAl<sub>2</sub><sub>-</sub><i><sub>x</sub></i>Mg<i><sub>x</sub></i> (Ae = Ca, Sr, Ba): Electron Concentration and Size Controlled Variations on the...
יצא לאור 2004"...For Ae = Ba a binary compound BaAl<sub>2</sub> does not exist, but more Ba-rich Ba<sub>7</sub>Al<sub>13</sub> forms. The reinvestigation of the crystal structure of Ba<sub>7</sub>Al<sub>13</sub> by selected area and convergent beam electron diffraction in a transmission electron microscope revealed a superstructure, which subsequently could be refined from single X-ray diffraction data. ..."