A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction por Alexander V. Astakhov (1450873)

“…Metal complexes bearing N-heterocyclic carbene (NHC) ligands are typically considered the system of choice for homogeneous catalysis with well-defined molecular active species due to their stable metal–ligand framework. A detailed study involving 19 different Pd-NHC complexes with imidazolium, benzimidazolium, and triazolium ligands has been carried out in the present work and revealed a new mode of operation of metal-NHC systems. …”

Lewis Acid Catalyzed Three-Component Hetero-Diels−Alder (Povarov) Reaction of <i>N</i>-Arylimines with Strained Norbornene-Derived Dienophiles por Chris D. Smith (2096089)

“…These observations may be rationalized by two competing mechanistic models, involving either a concerted asynchronous [4 + 2]-like mechanism or a stepwise mechanism.…”

Data_Sheet_4_The relationship between aesthetic preferences of people for ceramic tile design and neural responses: An event-related potential study.ZIP por Jiayin Chen (232428)

“…This study provides relevant information for quantitative aesthetic assessments of environmental design, interior design, and marketing involving ceramic tiles.</p>…”

Specific Hsp100 Chaperones Determine the Fate of the First Enzyme of the Plastidial Isoprenoid Pathway for Either Refolding or Degradation by the Stromal Clp Protease in Arabidopsi... por Pablo Pulido (2185855)

“…<div><p>The lifespan and activity of proteins depend on protein quality control systems formed by chaperones and proteases that ensure correct protein folding and prevent the formation of toxic aggregates. …”

Assembly of Heteroleptic Copper Complexes with Silver Salts: From Discrete Trinuclear Complexes to Infinite Networks por Dmitry Pogozhev (2246500)

“…The X-ray crystal structures of these complexes revealed that, albeit no particular association mode is observed for the acac capping ligand, one-dimensional networks are formed with the acacCN capping ligand. Whereas the imidazole peripheral ligand is coordinated to the copper center of a neighboring complex in the structure of (acacCN)Cu(dpm-imid), such an interaction is absent for the pyrazole appended derivative, (acacCN)Cu(dpm-pz), leading to an association mode involving the peripheral nitrile group of the acacCN ligand. …”

Data_Sheet_2_The relationship between aesthetic preferences of people for ceramic tile design and neural responses: An event-related potential study.ZIP por Jiayin Chen (232428)

“…This study provides relevant information for quantitative aesthetic assessments of environmental design, interior design, and marketing involving ceramic tiles.</p>…”

RNA Silencing of Mcl-1 Enhances ABT-737-Mediated Apoptosis in Melanoma: Role for a Caspase-8-Dependent Pathway por Angela M. Keuling (261149)

“…ABT-737, a small-molecule inhibitor of Bcl-2, Bcl-xl and Bcl-w, has demonstrated efficacy in several forms of leukemia, lymphoma as well as solid tumors. …”

Total Syntheses of Amphidinolide T1, T3, T4, and T5 por Christophe Aïssa (2464921)

“…All individual members, except amphidinolide T3 (<b>3</b>), derive from compound <b>39</b> as a common synthetic intermediate which is formed from three building blocks of similar size and complexity. …”

A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction por Alexander V. Astakhov (1450873)

“…Metal complexes bearing N-heterocyclic carbene (NHC) ligands are typically considered the system of choice for homogeneous catalysis with well-defined molecular active species due to their stable metal–ligand framework. A detailed study involving 19 different Pd-NHC complexes with imidazolium, benzimidazolium, and triazolium ligands has been carried out in the present work and revealed a new mode of operation of metal-NHC systems. …”

Image_1_Rare Copy Number Variants in Array-Based Comparative Genomic Hybridization in Early-Onset Skeletal Fragility.TIF por Alice Costantini (5494076)

“…<p>Early-onset osteoporosis is characterized by low bone mineral density (BMD) and fractures since childhood or young adulthood. Several monogenic forms have been identified but the contributing genes remain inadequately characterized. …”

A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction por Alexander V. Astakhov (1450873)

“…Metal complexes bearing N-heterocyclic carbene (NHC) ligands are typically considered the system of choice for homogeneous catalysis with well-defined molecular active species due to their stable metal–ligand framework. A detailed study involving 19 different Pd-NHC complexes with imidazolium, benzimidazolium, and triazolium ligands has been carried out in the present work and revealed a new mode of operation of metal-NHC systems. …”

A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction por Alexander V. Astakhov (1450873)

“…Metal complexes bearing N-heterocyclic carbene (NHC) ligands are typically considered the system of choice for homogeneous catalysis with well-defined molecular active species due to their stable metal–ligand framework. A detailed study involving 19 different Pd-NHC complexes with imidazolium, benzimidazolium, and triazolium ligands has been carried out in the present work and revealed a new mode of operation of metal-NHC systems. …”

Covalent Bonding and Atomic-Level Plasticity Increase Adhesion in Silicon–Diamond Nanocontacts por Zachary B. Milne (7507097)

“…First, covalent bonds formed across the interface, where the number of bonds formed was affected by the hydrogen termination of the substrate, the tip roughness, the applied stress, and the stochastic nature of bond formation. …”

Lewis Acid Catalyzed Three-Component Hetero-Diels−Alder (Povarov) Reaction of <i>N</i>-Arylimines with Strained Norbornene-Derived Dienophiles por Chris D. Smith (2096089)

“…These observations may be rationalized by two competing mechanistic models, involving either a concerted asynchronous [4 + 2]-like mechanism or a stepwise mechanism.…”

Assembly of Heteroleptic Copper Complexes with Silver Salts: From Discrete Trinuclear Complexes to Infinite Networks por Dmitry Pogozhev (2246500)

“…The X-ray crystal structures of these complexes revealed that, albeit no particular association mode is observed for the acac capping ligand, one-dimensional networks are formed with the acacCN capping ligand. Whereas the imidazole peripheral ligand is coordinated to the copper center of a neighboring complex in the structure of (acacCN)Cu(dpm-imid), such an interaction is absent for the pyrazole appended derivative, (acacCN)Cu(dpm-pz), leading to an association mode involving the peripheral nitrile group of the acacCN ligand. …”

Covalent Bonding and Atomic-Level Plasticity Increase Adhesion in Silicon–Diamond Nanocontacts por Zachary B. Milne (7507097)

“…First, covalent bonds formed across the interface, where the number of bonds formed was affected by the hydrogen termination of the substrate, the tip roughness, the applied stress, and the stochastic nature of bond formation. …”

Total Syntheses of Amphidinolide T1, T3, T4, and T5 por Christophe Aïssa (2464921)

“…All individual members, except amphidinolide T3 (<b>3</b>), derive from compound <b>39</b> as a common synthetic intermediate which is formed from three building blocks of similar size and complexity. …”

Image_2_Rare Copy Number Variants in Array-Based Comparative Genomic Hybridization in Early-Onset Skeletal Fragility.TIF por Alice Costantini (5494076)

“…<p>Early-onset osteoporosis is characterized by low bone mineral density (BMD) and fractures since childhood or young adulthood. Several monogenic forms have been identified but the contributing genes remain inadequately characterized. …”

Thirty-eighth Annual Report of the Vermont Bird Records Committee por Kent McFarland (457593)

“…The 38th annual report of the VBRC covers the evaluation of 50 records involving 28 species and 3 subspecies or ‘identifiable subspecific forms’. …”

Data_Sheet_1_The relationship between aesthetic preferences of people for ceramic tile design and neural responses: An event-related potential study.ZIP por Jiayin Chen (232428)

“…This study provides relevant information for quantitative aesthetic assessments of environmental design, interior design, and marketing involving ceramic tiles.</p>…”