Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C–H Bond Functionalization Reactions по Jonathan B. Eastwood (15065281)

“...An investigation into species formed following precatalyst activation in Mn-catalyzed C–H bond functionalization reactions is reported. ...”

S117 dephosphorylation is required for BAK multimerization. по Abul Azad (117840)

“...Note that BMOE detects only monomeric and dimeric forms of BAK. (<b>F</b>) Purified active PP2A directly dephosphorylated BAK at S117. ...”

Kinetics and Mechanistic Aspects of As(III) Oxidation by Aqueous Chlorine, Chloramines, and Ozone:  Relevance to Drinking Water Treatment по Michael C. Dodd (1324764)

“...NH₃ had negligible effect on the efficiency of As(III) oxidation by O₃, due to the slow kinetics of the O₃−NH₃ reaction at circumneutral pH. Time-resolved measurements of As(III) loss during chlorination and ozonation of real waters were accurately modeled using the rate constants determined in this investigation....”

A Phase I Double Blind, Placebo-Controlled, Randomized Study of a Multigenic HIV-1 Adenovirus Subtype 35 Vector Vaccine in Healthy Uninfected Adults по Michael C. Keefer (102279)

“...The median spot forming cells (SFC) per 10⁶ PBMC to any antigen was 78–139 across Groups A–C and 158–174 in Group D, after each of the vaccinations with a maximum of 2991 SFC. ...”

140 H/D Isotopomers Identified by Long-Range NMR Hyperfine Shifts in Ruthenium(III) Ammine Complexes. Hyperconjugation in Ru–NH₃ Bonding по W. Michael Laidlaw (1947022)

“...When traces of partially deuterated water are present, instead of a single cyclopentadienyl (Cp) resonance shifted by the hyperfine interaction, numerous well-resolved resonances are observed. The spectra were simulated satisfactorily by giving the appropriate statistical weight to 140 possible H/D isotopomers formed by deuteration in the five ruthenium­(III) ammine ligands. ...”

MIL-96, a Porous Aluminum Trimesate 3D Structure Constructed from a Hexagonal Network of 18-Membered Rings and <i>μ</i>₃-Oxo-Centered Trinuclear Units по Thierry Loiseau (1434349)

“...The four aluminum crystallographic sites are resolved by means of ²⁷Al 3QMAS technique. ...”

Voltammetric and Spectroscopic Studies of α- and β‑[PW₁₂O₄₀]^3– Polyoxometalates in Neutral and Acidic Media: Structural Characterization as Their [... по Tadaharu Ueda (1733863)

“...¹⁸³W NMR spectra of the oxidized forms of the PW₁₂ isomers are acid dependent and in the case of β-PW₁₂ imply that the bridging oxygens between the W_I and W_II units are preferentially protonated in acidic media. ...”

Synthesis and Characterization of Phosphorescent Cyclometalated Platinum Complexes по Jason Brooks (2631703)

“...Reaction of K₂PtCl₄ with a <i>HC</i>^∧<i>N</i> ligand precursor forms the chloride-bridged dimer, <i>C</i>^∧<i>N</i>Pt(μ-Cl)₂Pt<i>C</i>^∧<i>N</i>, which is cleaved with β-diketones such as acetyl acetone (acacH) and dipivaloylmethane (dpmH) to give the corresponding monomeric <i>C</i>^∧<i>N</i>Pt(<i>O</i>^∧<i>O</i>) complex. ...”

GAPDH protein in the oocyte nucleus and cytoplasm. по Helen S. Tang (16913903)

“...The three fastest migrating species of human GAPDH resolved by native PAGE are provisionally identified as the enzyme’s monomeric, dimeric and tetrameric forms. ...”

W₂Cl₄(NR₂)₂(PR‘₃)₂ Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and... по F. Albert Cotton (1781341)

“...The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. ...”

Examining prediction formation in empirical and model position representations. по William Turner (2220598)

“...In the main analysis we consider the ‘steady state’ of position representations formed after sustained exposure to motion along a predictable trajectory, and found evidence of progressive extrapolation. ...”

Associations between zircon and Fe–Ti oxides in Hiltaba event magmatic rocks, South Australia: atomic- or pluton-scale processes? по M. R. M. Ferguson (7386296)

“...The lack of pre-magmatic zircon, consistent intra-grain and inter-grain zircon compositional trends, the predominance of oscillatory zoned zircon with morphologies indicating growth from hot, evolved silicate melts, and the lack of evidence for zircon recrystallisation, indicates that zircon crystallised in the host GRV and RDG magmas. ...”

Mutations in DNA polymerase III both drive mutation rate increase by 1,000-fold (DnaQ^L145P; ε subunit) and rescue fitness of hypermutator clones (DnaE^T771S; α... по Ricardo S. Ramiro (8555421)

“...AA, amino acids; CFU, colony-forming units; Glu, glucose; LB, lysogeny broth; Nal^R, nalidixic acid resistance; ns, not significant; OD_600nm, optical density at 600 nm; PDB, Protein Data Bank; Rif^R, rifampicin resistance; Sor, sorbitol....”

Expression and localization of the DEN1 homolog DenA (AN10456) during development of the fungus <i>Aspergillus nidulans</i>. по Martin Christmann (280300)

“...In the presence of light <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-vonZeskaKress1" target="_blank">[4]</a> an aerial filament with an apical vesicle forms the asexual developmental structure (conidiophore) <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-Morimoto1" target="_blank">[5]</a> and releases the uninucleate conidiospores (green) into the air. ...”

Eh!woza Learner Doccies по Anastasia Koch (9420299)

“...</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. ...”

New Amine-Templated Zinc Phosphates with a Temperature-Induced Increase of Structural Dimensionality по Torben R. Jensen (1267908)

“...The complete hydrogen-bond scheme is resolved for these new compounds and reveals some interesting phenomena, for example, a hydrogen shared between two phosphate groups in <b>AU</b><b>-</b><b>II</b>, thereby forming H_0.5PO₄ groups. ...”

The 5HT_1BR−mini-G_o1 complex. по Rony Nehmé (206611)

“...Free GFP-mini-G_o1 (green) resolved as a predominant peak with a retention volume of 14.9 ml (<b>d</b>) Mini-G_o1 forms a complex with purified 5HT_1BR. ...”

Hydrolysis of polyphosphate (poly-P₁₃₀) mediated by cell free extracts of <i>Escherichia coli</i> CF6032 (<i>ΔgppA Δppkx</i>) and <i>Mycobacterium smegmatis</i> mc<sup>2... по Mei Y. Choi (145305)

“...Reaction mixtures were resolved on TBE 12% polyacrylamide gels, and stained with toluidine blue, to analyze the polyphosphate products formed. ...”

Direct Kinetics and Product Measurement of Phenyl Radical + Ethylene по Te-Chun Chu (5263829)

“...At 600 K and 10 Torr, the yield ratio of the H-abstraction reaction (forming benzene + C₂H₃) is measured to be 1.1% and the H-loss channel (styrene + H) has a 2.5% yield ratio. ...”

Phase Stability in the Systems AeAl₂_-<i>_x</i>Mg<i>_x</i> (Ae = Ca, Sr, Ba):  Electron Concentration and Size Controlled Variations on the... по Shahrad Amerioun (2711896)

“...For Ae = Ba a binary compound BaAl₂ does not exist, but more Ba-rich Ba₇Al₁₃ forms. The reinvestigation of the crystal structure of Ba₇Al₁₃ by selected area and convergent beam electron diffraction in a transmission electron microscope revealed a superstructure, which subsequently could be refined from single X-ray diffraction data. ...”