On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units od Wolfram W. Seidel (1261020)

“...The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. ...”

Dimerization of Stu2 is required for kinetochore association. od Matthew P. Miller (2328283)

“...For clarity, cross-links within Ndc80 complex proteins and those involving Stu2 fusion regions (extreme N-terminus and eGFP) are shown in grey. ...”

Structural, Electrochemical, and Spectroscopic Investigation of Acetate Bridged Dinuclear Tetrakis-Schiff Base Macrocycles of Mn and Zn od Subhadeep Kal (1720603)

“...The electrochemical and spectroscopic analysis of these complexes will aid in future studies involving electrocatalytic processes with related dinuclear macrocycles....”

The Dinuclear Zn(II) Complex Catalyzed Cyclization of a Series of 2-Hydroxypropyl Aryl Phosphate RNA Models:  Progressive Change in Mechanism from Rate-Limiting P−O Bond Cleavage t... od Shannon E. Bunn (2438131)

“...The data are analyzed in terms of a multistep process whereby a first formed complex rearranges to a reactive complex with a doubly activated phosphate coordinated to both metal ions. ...”

Reversible Switching of the Coordination Modes of a Pyridine-Functionalized Quinonoid Zwitterion; Its Di- and Tetranuclear Palladium Complexes od Alessio Ghisolfi (1588846)

“...This switch modifies the extent of π-delocalization involving the potentially antiaromatic quinonoid moiety and is accompanied by a significant color change, from red in <b>3</b> to green in <b>4</b>. ...”

Organometallic Complexes of Scandium and Yttrium Supported by a Bulky Salicylaldimine Ligand od David J. H. Emslie (1425715)

“...These compounds are highly thermally stable, decomposing at temperatures above 140 °C via a pathway involving metalation of one of the N-aryl isopropyl methyl groups. ...”

Hormone-independent, EcR-mediated endoreplication of SC DNA is stimulated by mating. od Aaron Leiblich (3211392)

“...(F) Proposed model explaining the different forms of hormone-dependent and hormone-independent, EcR-mediated SC growth in virgin and mated males. ...”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units od Wolfram W. Seidel (1261020)

“...The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. ...”

[(Cp−CMe₂−Flu)₂Ln]^-[Li(ether)<i>_n</i>]⁺ (Ln = Y, La):  Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and... od Evgueni Kirillov (1425814)

“...The fluorenyl ligands in <b>2</b> show an unprecedented η¹ bonding mode and a rare η³ bonding mode involving, respectively, a carbon atom of a phenyl ring and the bridgehead carbon atom of the central ring and the two adjacent carbon atoms of one six-membered ring. ...”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks od Prabir Ghosh (1625659)

“...The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. ...”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units od Wolfram W. Seidel (1261020)

“...The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. ...”

Synthesis and Characterization of Dimetallic Oxorhenium(V) and Dioxorhenium(VII) Compounds, and a Study of Stoichiometric and Catalytic Reactions od James H. Espenson (2536300)

“...They, too, have similar Re₂S₂ cores that involve donor atoms from two of the dithiolate ligands; the third dithiolate chelates one of the rhenium atoms. ...”

Ligand-Induced and Reductively Induced Alkyne−Isocyanide Coupling Reactions of [Mo(CNBu^t)₃(PhC⋮CPh)(η⁵-C₅Me₅)][BF₄... od Christopher J. Adams (1847317)

“...A similar reaction of <b>4</b> with P(OMe)₃ generates [Mo{C(NHBu^t)C(Ph)C(Ph)CN}(CNBu^t){P(OMe)₃}(η⁵-C₅Me₅)][BF₄], <b>5</b>, involving the same coupling and elimination pattern. ...”

Arsenic(III) Halide Complexes with Acyclic and Macrocyclic Thio- and Selenoether Coligands:  Synthesis and Structural Properties od Nicholas J. Hill (1333515)

“...[AsCl₃([14]aneS₄)] forms an infinite sheet involving two μ²-chloro ligands on each As but bridging to two distinct As centers. ...”

Structural Diversity in Supramolecular Complexes of MCl₃ (M = As, Sb, Bi) with Constrained Thio- and Seleno-Ether Ligands od William Levason (1275612)

“...[BiCl₃{<i>o</i>-C₆H₄(SeMe)₂}] comprises distorted square pyramidal units involving pyramidal BiCl₃ primary coordination and a weakly chelating diselenoether ligand, and assembled into infinite chains through long bridging Bi···Cl interactions via all three Clʼs. ...”

Preparation, Structure, and Properties of the Corner-Shared Double Cubes [Mo₆HgQ₈(H₂O)₁₈]⁸⁺ (Q = S, Se) and Tungsten Analogue... od Vladimir P. Fedin (1491637)

“...Furthermore, on dilution of column-purified [Mo₆HgS₈(H₂O)₁₈]⁸⁺, Beer's law is not obeyed and equilibria involving 2[Mo₃S₄(H₂O)₉]⁴⁺ are apparent. ...”

Rooted phylogenetic tree of 550 base pair E1 fragment produced from Bayesian analysis using BEAST. od Isabel Fourie (11896234)

“...Phylogenetic analysis with strong posterior probability support was obtained as follows: the concatenated (ORF1 and ORF 2) and nsP region placed MIDV in its own complex as seen for analysis using nsP4, while analysis using the sP region placed MIDV within the SF complex as seen with analyses involving the E1 fragment (which forms part of the structural proteins) (Figs <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g003" target="_blank">3</a>, <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g004" target="_blank">4</a> and <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g005" target="_blank">5</a>). ...”

Tuning the Inclusion Properties and Solid-State Reactivity of Second Sphere Adducts Using Conformationally Flexible Bidentate Ligands od Fang Guo (105824)

“...We demonstrate that some of the second sphere adducts are dynamic, showing reversible guest release/uptake involving crystalline-to-amorphous-to-crystalline phase transformations. ...”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... od Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”

Near-isotropic, reconstructed volume electron microscopy (FIB-SEM) of mouse dorsal striatum (jrc_mus-dorsal-striatum) od CellMap Project Team (14322654)

“...Here, we have used focused ion beam-scanning electron microscopy to generate 3D reconstructions of intracellular organelles and their membrane appositions involving the ER (distance ≤30 nm) in different neuronal compartments. ...”