Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions -н Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

Synthesis, Structures, and DFT Bonding Analysis of New Titanium Hydrazido(2−) Complexes -н Thomas B. Parsons (1305306)

“…DFT calculations on the hydrazido ligand in a μ-η²,η¹-bridging mode showed involvement of the NN π electrons in donation to one of the Ti centers. …”

Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions -н Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

Cone Repair Surgery for Ebstein’s Anomaly in an Adult Patient -н Juan Cruz Ponceliz (18529481)

“…</p><p dir="ltr">In 1993, Da Silva et al. developed a surgical technique involving cone reconstruction of the tricuspid valve. …”

Highly Enhanced Bisignate Circular Dichroism of Ferrocene-Bridged Zn(II) Bisporphyrin <i>Tweezer</i> with Extended Chiral Substrates due to Well-Matched Host–Guest System -н Sanfaori Brahma (1839793)

“…To the best of our knowledge, these are some of the largest values reported for a chirality induction process involving bisporphyrin <i>tweezer</i> receptors. The large enhancement in the CD signal intensity is due to the well complementarity size between Zn­(II)­bisporphyrin host and the extended chiral diamines guest, which results large unidirectional twisting of two porphyrin units to accommodate the guests having preorganized binding sites with minimum host–guest steric interactions. …”

Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions -н Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

A Diprotonated Porphyrin as an Electron Mediator in Photoinduced Electron Transfer in Hydrogen-Bonded Supramolecular Assemblies -н Wataru Suzuki (423403)

“…In <b>H</b>_<b>4</b><b>DPP</b>^<b>2+</b><b>(Ru</b>^<b>II</b><b>COO</b>^<b>–</b><b>)</b>_<b>2</b>, intrasupramolecular photoinduced electron transfer (ET) occurred from the Ru^II center to the singlet excited state of <b>H</b>_<b>4</b><b>DPP</b>^<b>2+</b> to afford an ET state involving one-electron-reduced <b>H</b>_<b>4</b><b>DPP</b>^<b>•+</b> and the corresponding one-electron-oxidized Ru^III complex with the lifetime of 150 ps. …”

Template Synthesis of Iron(II) Complexes Containing Tridentate P−N−S, P−N−P, P−N−N, and Tetradentate P−N−N−P Ligands -н Paraskevi O. Lagaditis (1724386)

“…A series of mer-tridentate iron(II) complexes bearing P−N−S (<b>3</b>), P−N−P (<b>4</b>), and P−N−N (<b>5</b>) ligands have been prepared via the metal template effect in one pot involving air-stable phosphonium dimers [<i>cyclo-</i>(−PPh₂CH₂C(OH)H−)₂](Br)₂ (<b>1</b>) and [<i>cyclo-</i>(−PCy₂CH₂C(OH)H−)₂](Br)₂ (<b>2</b>), KO<i>t</i>Bu, [Fe(H₂O)₆][BF₄]₂ and 2-aminothiolphenol (for <b>3</b>), 2-(diphenylphosphino)ethylamine (for <b>4</b>), and 2-(aminomethyl)pyridine (for <b>5</b>). …”

Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions -н Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

The Dynamic Tensions Physical Culture Show -н Broderick D.V. Chow (1229721)

“…In September 2016 I was awarded an AHRC Leadership Fellows grant to investigate physical culture and the performance of masculinities. I had been involved with Olympic Weightlifting for a few years, and gym culture in general for much longer, and I had a hunch that there was indeed a link between theatre and performance and physical culture. …”

Catching Versus Technique -н David Fancher (3395588)

“…<div><br></div><div>From the outset, I would state I am not an expert but simply a lucky passionate practitioner of fishing in all its forms. Like all fishermen I have my preferred methods but am not blind to the huge range of disciplines in the sport. …”

Original date -н Hongliang Wu (22510100)

“…</p><p dir="ltr">Various forms of iron (Fe) and aluminum (Al) oxides were measured to assess their potential mediation of SOC persistence within aggregates. …”

58634: The Story of Harry Ellison -н Great War Archive Project Team (17982721)

“…</p> <p>For information, the 22nd (Labour) Battalion of the West Yorkshire (Prince of Wales Own) Regiment was formed at Millington (just east of York) in April 1916. …”

Data Collection for Adult and Sapling Cedar tree using transect tape and a tape rule.csv -н Bukunmi Omotoso (3113874)

“…In order to speed up the data collection, two individuals were involved in retrieving and measuring each variable used in this data set. …”

Performance responses from stem-meta-analysis -н Andrea E. A. Stephens (612509)

“…This might be the treatment that involved the most insects, removed most biomass, or exposed plants to herbivores for the longest period of time. …”

54863: Photograph of Horse Team, 4th Bn. (Pioneers) Coldstream Guards -н Great War Archive Project Team (17982721)

“…On August Bank Holiday 1914, Great Britain declared war on Germany, and the Coldstream were immediately involved. The 1st Battalion, as part of 1st Guards Brigade, and the 2nd and 3rd Battalions, as part of 4th Guards Brigade, all moved to France immediately.…”

Structure and sequence features of the five GTPases. -н Francesco Raimondi (228519)

“…Ultra-conserved sequences involved in nucleotide binding (G boxes) are delimited by black boxes. …”

Global_assessment_urban_ecology_reptiles.xlsx -н Paulo Brum (11934341)

“…., town, city) of the study location(s); (4) taxa involved in the study (orders: Rhynchocephalia, Squamata, Testudines, and Crocodylia; suborder only for Squamata: Lacertilia, Serpentes, and Amphisbaenia; and species). …”

Sustainability as Representation (Panel 2) -н Elke Weissmann (18176218)

“…This complex and dynamic media landscape poses new challenges and opportunities for negotiating the causes, consequences and responses to contemporary conflicts, as well as the roles and responsibilities of different actors involved in them.</p>…”

Assessing the effectiveness of a melanopsin-based signal for colour constancy - ICVS Presentation 2019 -н Daniel Garside (3367640)

“…Whilst their influence is traditionally thought to be limited to non-image-forming pathways, there is increasing evidence for a role in image-forming-, and specifically colour-, vision (Spitschan et al. 2017; Cao, Chang, and Gai 2018; Zele et al. 2018). …”