Metallophilicity in Annular Ru₂M₂ Derivatives of (HMB)Ru^II(tpdt) versus (Bis)-η²-dithiolate Bonding in Ru₂M Derivatives of Cp... Tekijä Richard Y. C. Shin (2377501)

“…Complex <b>6 </b>was formed in a reversible process with [{(HMB)Ru^II(μ-η¹:η³-tpdt)}(AuPPh₃)]⁺ (<b>5</b>) involving dissociation/association of PPh₃. …”

Synthetic and Structural Investigations on the Reactivity of the Cd–I Bond in [ICd{Zr₂(OPr^<i>i</i>)₉}] to Construct New Mixed-Metal Alkoxides Tekijä Corinna Hegemann (1616161)

“…In solution and in the solid state, <b>1</b>–<b>7</b> exist as monomers, whereas compounds <b>8</b>–<b>12</b> form dimers.…”

Assembly of Cyclometalated Platinum(II) Complexes via 1,1′-Bis(diphenylphosphino)ferrocene Ligand: Kinetics and Mechanisms Tekijä S. Masoud Nabavizadeh (2100157)

“…On the basis of low-temperature ³¹P NMR studies involving the starting complex [Pt(<i>p</i>-MeC₆H₄)(ppy)(SMe₂)], <b>1b</b>, we suggest that dppf displaces the labile ligand SMe₂ to give an uncommon complex, [Pt(<i>p</i>-MeC₆H₄)(ppy)(dppf-κ¹<i>P</i>)], <b>A</b>, in which dppf-κ¹<i>P</i> is a monodentate dppf ligand, which rapidly forms an equilibrium with the chelating dppf isomer complex [Pt(<i>p</i>-MeC₆H₄)(dppf)(ppy-κ¹<i>C</i>)], <b>B</b>, in which ppy<i>-</i>κ¹<i>C</i> is the deprotonated ppy ligand that is C-ligated with the dangling N atom. …”

Synthesis, Structure and Magnetic Behavior of Five-Coordinate Bis(iminopyrrolyl) Complexes of Cobalt(II) containing PMe₃ and THF Ligands Tekijä Sónia A. Carabineiro (2415823)

“…A third route was tested, involving the addition of excesses of PMe₃ to the complexes [Co(κ²<i>N</i>,<i>N′</i>-NC₄H₃C(R)N-2,6-ⁱPr₂C₆H₃)₂] (R = H <b>1e</b>; Me <b>1f</b>), which was only successful for the synthesis of <b>3a</b>, in lower yields (ca. 30%). …”

Synthesis and Reactions of the Triruthenamonocarboncarborane Cluster Complex [NHMe₃][Ru₃(CO)₈(<i>η</i>⁵-7-CB₁₀H₁₁)... Tekijä Dianne D. Ellis (2696509)

“…A novel feature of the structure is a three-center−two-electron B−H⇀Cu bond involving the B(2) site in the <i>nido</i>-10-Cu(PPh₃)-7-CB₁₀H₁₀ cage system. …”

AMBILE_Shah_Jo_Risalo_Labeled Tekijä Abdul Majid Bhurgri Institute of Language Engineering Hyderabad (22197295)

“…</p><h2><b>Acknowledgments</b></h2><p dir="ltr">Special thanks to the <a href="https://bhittaipedia.org/p/bhittai-pedia-team" rel="noopener" target="_new"><b>AMBILE team</b></a> for their involvement in data compilation and cleaning.</p><h2><b>Contact</b></h2><p dir="ltr">For any queries, collaboration opportunities, or contributions, please contact:</p><ul><li><b>Email</b>: <a href="mailto:datasets@sindh.ai" rel="noopener" target="_blank">datasets@sindh.ai</a></li></ul><p></p>…”

Digital Humanities Summer Institute 2014: A #dhsi2014 Archive Tekijä Ernesto Priego (4758012)

“…Some work was done to ensure the chronology was complete; I have highlighted an apparent gap in the tweets between 05/06/2014 23:41 and 06/06/2014 10:19; this could be due to a later start on the morning of the last day of activities, though one could have expected other tweets form other time zones coming it at that time, so it’s possible I have missed them. …”

Alkenyl Derivatives of the Unsaturated Dimolybdenum Hydride Complex [Mo₂(η⁵-C₅H₅)₂(μ-H)(μ-PCy₂)(CO)₂]... Tekijä M. Angeles Alvarez (1353513)

“…In solution, both compounds exhibit an isomeric equilibrium (rapid on the NMR time scale) involving the alternate π-binding of the alkenyl ligand to each of the metal centers. …”

Model development and model selection. Tekijä Marco Binder (449237)

“…(B) Different hypotheses for the involvement of a host function at all feasible steps in the viral lifecycle were assessed to explain differences observed in the replication dynamics of Huh7-Lunet and Huh-7 lp cells. …”

Light-Induced Oxidative Stress, <em>N</em>-Formylkynurenine, and Oxygenic Photosynthesis Tekijä Tina M. Dreaden Kasson (147185)

“…The yield of this modification increases under light stress conditions, in parallel with the decrease in oxygen evolving activity. In this work, we show that this modification, NFK365-CP43, is present in thylakoid membranes and may be formed by reactive oxygen species produced at the Mn₄CaO₅ cluster in the oxygen-evolving complex. …”

Efforts and outcomes of making the ROAD database reusable Tekijä Christian Sommer (9470378)

“…However, through the involvement of all participants, a democratic consensus could be reached that strengthens the further sustainable development of the project. …”

Origin of late Carboniferous highly fractionated high-K calc-alkaline I-type granites from the eastern Pontides (Şiran, northern Turkey) Tekijä Gültekin Topuz (2737591)

“…In this study, we present geological, U-Pb zircon age, elemental abundance and Sr-Nd-Pb isotopic data on two highly evolved Carboniferous granite bodies within the Early to Late Jurassic volcaniclastic rocks in the Şiran region. …”

Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions Tekijä Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions Tekijä Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions Tekijä Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions Tekijä Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions Tekijä Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

Synthesis, Structures, and DFT Bonding Analysis of New Titanium Hydrazido(2−) Complexes Tekijä Thomas B. Parsons (1305306)

“…DFT calculations on the hydrazido ligand in a μ-η²,η¹-bridging mode showed involvement of the NN π electrons in donation to one of the Ti centers. …”

Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions Tekijä Falguni Basuli (2361007)

“…Complex <b>1</b> was found to decompose rapidly to several products, of which the titanacycle Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](CH₂Si(Me)₃) (<b>5</b>) and dimer [TiNAr([Ar]NC(Me)CHC(μ-CH₂)CH^tBu)]₂ (<b>6</b>) were formed. Complex <b>5</b> was prepared in better yield through an independent synthesis involving Ti[2,6-(CMe₂)(CHMe₂)C₆H₃]NC(Me)CHC(Me)N[2,6-(CMe₂)(CHMe₂)C₆H₃](OTf) and LiCH₂SiMe₃. …”

Cone Repair Surgery for Ebstein’s Anomaly in an Adult Patient Tekijä Juan Cruz Ponceliz (18529481)

“…</p><p dir="ltr">In 1993, Da Silva et al. developed a surgical technique involving cone reconstruction of the tricuspid valve. …”