Partial in Situ Reduction of Copper(II) Resulting in One-Pot Formation of 2D Neutral and 3D Cationic Copper(I) Iodide–Pyrazine Coordination Polymers: Structure and Emissive Propert... af Iurie L. Malaestean (3932111)

“...By using either Cu­(CH₃COO)₂·H₂O or Cu­(BF₄)₂ as starting materials, both known forms, yellow [(Cu^II)₂(bpy)]_<i>n</i> and orange [Cu^II­(bpy)]_<i>n</i>, precipitated successively. ...”

Table_3_Plastome phylogenomics reveals an early Pliocene North- and Central America colonization by long-distance dispersal from South America of a highly diverse bromeliad lineage... af Sandra I. Vera-Paz (13183560)

“...Assessing the geographic origin and dispersal history of highly diverse lineages of rapid diversification can be hindered by the lack of appropriately sampled, resolved, and strongly supported phylogenetic contexts. ...”

Iodide Ion Pairing with Highly Charged Ruthenium Polypyridyl Cations in CH₃CN af Wesley B. Swords (1607437)

“...The diastereotopic H atoms on the methylene carbon that link the amine to the bipyridine ring were uniquely sensitive to the presence of iodide; analysis revealed that an iodide “binding pocket” exists wherein iodide forms an adduct with the 3 and 3′ bipyridyl H atoms and the quaternized amine. ...”

Reactivity of a Fe(III)-Bound Methoxide Supported with a Tris(thiolato)phosphine Ligand: Activation of C–Cl Bond in CH₂Cl₂ by Nucleophilic Attack of a Fe(III)... af Kai-Chun Chang (633026)

“...The bound methoxide in <b>1</b> is labile and can be replaced by a CH₃CN molecule. The forming Fe^III–CH₃CN species can be further reduced by cobaltcene quantitatively to a stable Fe^II–CH₃CN complex, [Fe­(PS3″)­(CH₃CN)]⁻. ...”

Table_2_Plastome phylogenomics reveals an early Pliocene North- and Central America colonization by long-distance dispersal from South America of a highly diverse bromeliad lineage... af Sandra I. Vera-Paz (13183560)

“...Assessing the geographic origin and dispersal history of highly diverse lineages of rapid diversification can be hindered by the lack of appropriately sampled, resolved, and strongly supported phylogenetic contexts. ...”

MdFDIA: A Mass Defect Based Four-Plex Data-Independent Acquisition Strategy for Proteome Quantification af Yi Di (4445635)

“...The subtle mass differences between the four labeled forms in MS² scans can be resolved on an Orbitrap Fusion Lumos instrument to facilitate quantification without abundance information encoded in MS² spectra. ...”

Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η³(<i>BCC</i>)-Triarylborane Coordination af David J. H. Emslie (1425715)

“...By contrast, the TXPB ligand in <b>2</b> is bound to palladium not only via the phosphine and thioether donors but also through a Pd-(η³-BAr₃) linkage involving boron and the <i>ipso</i>- and <i>ortho</i>-carbon atoms of one <i>B</i>-phenyl ring. ...”

C−C and C−N Coupling Reactions of an Imidotitanium Complex with Isocyanides af Allan Bashall (3077106)

“...These products are thought to be formed in a reaction sequence involving intermediates that are analogous to the stable complexes <b>2</b> and <b>3a</b>−<b>h</b>. ...”

Assembly of Soft Metal Complexes of an O₄S₂‑Macrocycle Displaying Endocyclic Monomer, Dumbbell-Like Dimer, and Endo-/Exocyclic Polymer Structures af Huiyeong Ju (1493002)

“...The X-ray structures of seven complexes (<b>1</b>–<b>7</b>) have been determined, and a range of structural types and coordination modes, including discrete to continuous forms, mono- to multinuclear, and endo- to exocyclic structures involving M–S bonds, are presented. ...”

Influence of the Ligand Alkyl Chain Length on the Solubility, Aqueous Speciation, and Kinetics of Substitution Reactions of Water-Soluble M₃S₄ (M = Mo, W) Clu... af Tomás F. Beltrán (1687288)

“...On the basis of the kinetic results, a mechanism with two parallel reaction pathways involving water and OH^– attacks is proposed for the formal substitution of halides by hydroxo ligands. ...”

Distinct GluN1 and GluN2 Structural Determinants for Subunit-Selective Positive Allosteric Modulation of <i>N</i>‑Methyl‑d‑aspartate Receptors af Katie L. Strong (4172584)

“...Several neurological disorders may involve NMDAR hypofunction, which has driven therapeutic interest in positive allosteric modulators (PAMs) of NMDAR function. ...”

Mononuclear Titanium(IV)−Citrate Complexes from Aqueous Solutions:  pH-Specific Synthesis and Structural and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)−Citrate Spec... af E. T. Kefalas (2679103)

“...In an effort to comprehend the involvement of titanium in requisite biological interactions with physiological ligands, synthetic efforts were launched targeting aqueous soluble species of Ti(IV). ...”

Trinuclear Nickel Complexes with Triplesalen Ligands:  Simultaneous Occurrence of Mixed Valence and Valence Tautomerism in the Oxidized Species af Thorsten Glaser (1354377)

“...Thus, these oxidized forms exhibit the phenomena of valence tautomerism and mixed valence simultaneously. ...”

Alkylation, Cation Formation, and Insertion Reactions in Titanium Tris(ketimide) Complexes af M. João Ferreira (2512048)

“...Above 60 °C, C₆F₅ is transferred to the metal center and Ti(NC^tBu₂)₃(C₆F₅) (<b>9</b>) forms. This compound participates in a dynamic process in solution involving Ti···F interactions. ...”

Trinuclear Nickel Complexes with Triplesalen Ligands:  Simultaneous Occurrence of Mixed Valence and Valence Tautomerism in the Oxidized Species af Thorsten Glaser (1354377)

“...Thus, these oxidized forms exhibit the phenomena of valence tautomerism and mixed valence simultaneously. ...”

Study selection flow chart. af Stella Sarpomaa Oppong (22530606)

“...</p><p>Methods</p><p>Studies will be considered eligible if they are randomized controlled trials (RCTs), quasi-experimental studies, and Observational studies (cohort, case-control, cross-sectional studies) involving women and couples with infertility problems and living in a LMIC who received a psychosocial intervention to improve marital intimacy, sexual satisfaction, and QoL. ...”

Network assessment of demethylation treatment in melanoma: Differential transcriptome-methylome and antigen profile signatures af Zhijie Jiang (355840)

“...Overall, the non-metastatic SKMEL-2 map reveals post-treatment re-activation of a richer pathway landscape, involving cadherins and integrins as signatures of cell adhesion and proliferation. ...”

Data supporting the figures and supplementary figures and tables in the published article: Suppression of FOXM1 activities and breast cancer growth in vitro and in vivo by a new cl... af Yvonne Ziegler (7548729)

“...</div><div><br></div><div><b>Study approval:</b> All experiments involving animals were conducted in accordance with National Institutes of Health (NIH) standards for the care and use of animals, with protocols approved by the University of Illinois IACUC....”

Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η³(<i>BCC</i>)-Triarylborane Coordination af David J. H. Emslie (1425715)

“...By contrast, the TXPB ligand in <b>2</b> is bound to palladium not only via the phosphine and thioether donors but also through a Pd-(η³-BAr₃) linkage involving boron and the <i>ipso</i>- and <i>ortho</i>-carbon atoms of one <i>B</i>-phenyl ring. ...”

Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η³(<i>BCC</i>)-Triarylborane Coordination af David J. H. Emslie (1425715)

“...By contrast, the TXPB ligand in <b>2</b> is bound to palladium not only via the phosphine and thioether donors but also through a Pd-(η³-BAr₃) linkage involving boron and the <i>ipso</i>- and <i>ortho</i>-carbon atoms of one <i>B</i>-phenyl ring. ...”