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30981
Ultrafast Chemistry under Nonequilibrium Conditions and the Shock to Deflagration Transition at the Nanoscale
منشور في 2015"…Within 30 ps, a local deflagration wave develops; it propagates at 0.25 km/s and consists of an ultrathin reaction zone of only ∼5 nm, thus involving large temperature and composition gradients. …"
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30982
Ultrafast Chemistry under Nonequilibrium Conditions and the Shock to Deflagration Transition at the Nanoscale
منشور في 2015"…Within 30 ps, a local deflagration wave develops; it propagates at 0.25 km/s and consists of an ultrathin reaction zone of only ∼5 nm, thus involving large temperature and composition gradients. …"
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30983
Complexation of Quaternary Ammonium Ions by Tetraester Derivatives of [3.1.3.1]Homooxacalixarene in Mobile and in Fixed Conformation
منشور في 2006"…In the tetraalkylation of <i>p</i>-<i>tert</i>-butyl[3.1.3.1]homooxacalixarene with BrCH<sub>2</sub>CO<sub>2</sub>R and K<sub>2</sub>CO<sub>3</sub> in acetone, the initially formed cone conformer is converted into the more stable 1,4-alternate conformer when R = Me or Et, but not when R = <i>i</i>-Pr or <i>t</i>-Bu. …"
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30984
X-ray structure of SaHPPK with the 8-mercaptoguanine inhibitor bound.
منشور في 2012"…C, Intermolecular interactions (orange) involving 8-mercaptoguanine. Two side chain conformers for Asp95 were modelled and are shown. …"
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30985
Electronic_supplementary_data_cytb_sequence from Into the dark: patterns of middle ear adaptations in subterranean eulipotyphlan mammals
منشور في 2017"…Quantitative shapes were found to strongly reflect the degree of subterranean lifestyle and weakly involve phylogeny. Our analyses demonstrate that subterranean adaptation should include a relatively shorter anterior process of the malleus, an enlarged incus, an enlarged stapes footplate and a reduction of the orbicular apophysis. …"
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30986
The threads and traces of fashion: commerce and sociability in São Paulo at the beginning of the 20 th century
منشور في 2018"…<p></p><p>ABSTRACT The turn of the 20th century witnessed profound transformations in the city of São Paulo and new forms of its inhabitants will be related to urban space. …"
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30987
Mapping Out the Molecular Interplay in Monohalobenzene Inclusion Complexes of <i>p</i>-H-calix[5]arene Using Hirshfeld Surfaces
منشور في 2008"…All but the iodobenzene complexes are isostructural forming columnar arrays involving three crystallographically related 1:1 host–guest supermolecules (halobenzene∩calix[5]arene); three halobenzene molecules from different supermolecules are associated via C−H···X interactions for hydrogen atoms <i>ortho</i> to the halogen atoms, effectively creating a larger cavity from close proximity of three calix[5]arenes. …"
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30988
Ultrafast Chemistry under Nonequilibrium Conditions and the Shock to Deflagration Transition at the Nanoscale
منشور في 2015"…Within 30 ps, a local deflagration wave develops; it propagates at 0.25 km/s and consists of an ultrathin reaction zone of only ∼5 nm, thus involving large temperature and composition gradients. …"
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30989
Musical Melody and Speech Intonation: Singing a Different Tune
منشور في 2012"…Given these similarities, and the fact that pitch perception and production involve the same peripheral transduction system (cochlea) and the same production mechanism (vocal tract), it might be natural to assume that pitch processing in speech and music would also depend on the same underlying cognitive and neural mechanisms. …"
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30990
Polycyclic Ring Formation Using Bis-diazolactams for Cascade Stitching
منشور في 2016"…The initial reaction can be paired with a subsequent tandem cascade sequence involving dipole formation/cycloaddition in either an intra- or intermolecular sense to generate polycyclic <i>N</i>-heterocycles in one pot, with the formation up to three new rings in a single operation. …"
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30991
Mapping Out the Molecular Interplay in Monohalobenzene Inclusion Complexes of <i>p</i>-H-calix[5]arene Using Hirshfeld Surfaces
منشور في 2008"…All but the iodobenzene complexes are isostructural forming columnar arrays involving three crystallographically related 1:1 host–guest supermolecules (halobenzene∩calix[5]arene); three halobenzene molecules from different supermolecules are associated via C−H···X interactions for hydrogen atoms <i>ortho</i> to the halogen atoms, effectively creating a larger cavity from close proximity of three calix[5]arenes. …"
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30992
Wave Packet Dynamics at an Extended Seam of Conical Intersection: Mechanism of the Light-Induced Wolff Rearrangement
منشور في 2015"…The passage of the wave packet through the extended seam explains the competition between concerted ketene formation and a stepwise mechanism involving a carbene. The two primary photoproducts are formed in the first 100 fs of the simulation, in agreement with recent ultrafast spectroscopy measurements.…"
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30993
Ultrafast Chemistry under Nonequilibrium Conditions and the Shock to Deflagration Transition at the Nanoscale
منشور في 2015"…Within 30 ps, a local deflagration wave develops; it propagates at 0.25 km/s and consists of an ultrathin reaction zone of only ∼5 nm, thus involving large temperature and composition gradients. …"
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30994
Ultrafast Chemistry under Nonequilibrium Conditions and the Shock to Deflagration Transition at the Nanoscale
منشور في 2015"…Within 30 ps, a local deflagration wave develops; it propagates at 0.25 km/s and consists of an ultrathin reaction zone of only ∼5 nm, thus involving large temperature and composition gradients. …"
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30995
Supplementary Material for: Voltage-Gated Sodium Channel β<sub>1</sub> Gene: An Overview
منشور في 2021"…<b><i>Background:</i></b> Voltage-gated sodium channels are protein complexes composed of 2 subunits, namely, pore-forming α- and regulatory β-subunits. A β-subunit consists of 5 proteins encoded by 4 genes (i.e., <i>SCN1B–SCN4B</i>). …"
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30996
Ultrafast Chemistry under Nonequilibrium Conditions and the Shock to Deflagration Transition at the Nanoscale
منشور في 2015"…Within 30 ps, a local deflagration wave develops; it propagates at 0.25 km/s and consists of an ultrathin reaction zone of only ∼5 nm, thus involving large temperature and composition gradients. …"
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30997
Ultrafast Chemistry under Nonequilibrium Conditions and the Shock to Deflagration Transition at the Nanoscale
منشور في 2015"…Within 30 ps, a local deflagration wave develops; it propagates at 0.25 km/s and consists of an ultrathin reaction zone of only ∼5 nm, thus involving large temperature and composition gradients. …"
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30998
Dataset for: Structure of a new Usnic acid derivative from a deacylating Mannich reaction. NMR studies supported by theoretical calculations of chemical shifts.
منشور في 2018"…It was found that the hydrogen bond involving the OH-9 group in chloroform forms a strong hydrogen bond than in usnic acid itself and that this hydrogen bond becomes even stronger in the more polar solvent, dimethylsulfoxide. …"
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30999
A contemporary and innovative care model for older adults
منشور في 2021"…There will also be medical records that cover clinical and social aspects, as well as a quality information system - all involving advanced technology, accessible by doctors and clients at any time via cloud technology and a cell phone app. …"
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31000
Ultrafast Chemistry under Nonequilibrium Conditions and the Shock to Deflagration Transition at the Nanoscale
منشور في 2015"…Within 30 ps, a local deflagration wave develops; it propagates at 0.25 km/s and consists of an ultrathin reaction zone of only ∼5 nm, thus involving large temperature and composition gradients. …"