'form is (((((remove. OR evolveddsssdss.) OR evolve.) OR involves.) OR involved.) OR removed.)' хайлтад зориулсан 34,254-н үр дүнгүүд 34,241 - 34,254-г харуулж байна, асуулгын хугацаа: 1.32s Үр дүнг сайжруулах
  1. 34241

    New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis Masanari Hirahara (1558075)

    Хэвлэсэн 2015
    “…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)­(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
  2. 34242

    New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis Masanari Hirahara (1558075)

    Хэвлэсэн 2015
    “…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)­(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
  3. 34243

    New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis Masanari Hirahara (1558075)

    Хэвлэсэн 2015
    “…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)­(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
  4. 34244

    Syntheses of the Uranium Complexes [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>2</sub>{N(SiMe<sub>3</sub>)(SiMe<sub>2</sub>CH<sub>2</sub>B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)}] an... Matthias Müller (19649)

    Хэвлэсэн 1998
    “…The complex [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>2</sub>{N(SiMe<sub>3</sub>)(SiMe<sub>2</sub>CH<sub>2</sub>B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)}] (<b>1</b>) is formed in the reaction between the hydride complex [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>3</sub>(H)] and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>, and H<sub>2</sub> is evolved. …”
  5. 34245

    Influence of the Bite Angle of Dianionic C,N,C-Pincer Ligands on the Chemical and Photophysical Properties of Iridium(III) and Osmium(IV) Hydride Complexes Ruth Castro-Rodrigo (2105221)

    Хэвлэсэн 2019
    “…Initially, the phenyl activation gives IrH<sub>2</sub>{κ<sup>2</sup>-<i>C</i>,<i>N</i>-(C<sub>6</sub>H<sub>4</sub>-py-OPh)}­(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> (<b>3</b>), which subsequently evolves to IrH­{κ<sup>3</sup>-<i>C</i>,<i>N</i>,<i>C</i>-(C<sub>6</sub>H<sub>4</sub>-py-OC<sub>6</sub>H<sub>4</sub>)}­(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> (<b>4</b>). …”
  6. 34246

    Eh!woza Learner Doccies Anastasia Koch (9420299)

    Хэвлэсэн 2023
    “…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”
  7. 34247

    Alkynyldiphenylphosphine d<sup>8</sup> (Pt, Rh, Ir) Complexes:  Contrasting Behavior toward <i>cis</i>-[Pt(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>(THF)<sub>2</sub>] Jesús R. Berenguer (2468818)

    Хэвлэсэн 2004
    “…Thus, treatment of <b>1</b> with 1 equiv of <i>cis</i>-[Pt(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>(THF)<sub>2</sub>] gives the double inserted cationic product [Pt(C<sub>6</sub>F<sub>5</sub>)(S)μ-{C(Ph)C(PPh<sub>2</sub>)C(PPh<sub>2</sub>)C(Ph)(C<sub>6</sub>F<sub>5</sub>)}Pt(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>C⋮CPh)](CF<sub>3</sub>SO<sub>3</sub>) (S = THF, H<sub>2</sub>O), <b>8</b> (S = H<sub>2</sub>O, X-ray), which evolves in solution to the mononuclear complex [(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>C⋮CPh)Pt{C<sub>10</sub>H<sub>4</sub>-1-C<sub>6</sub>F<sub>5</sub>-4-Ph-2,3-κ<i>PP</i>‘(PPh<sub>2</sub>)<sub>2</sub>}](CF<sub>3</sub> SO<sub>3</sub>), <b>9</b> (X-ray), containing a 1-pentafluorophenyl-2,3-bis(diphenylphosphine)-4-phenylnaphthalene ligand, formed by annulation of a phenyl group and loss of the Pt(C<sub>6</sub>F<sub>5</sub>) unit. …”
  8. 34248

    Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo<sub>2</sub>(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>(μ-R)(μ-PCy... M. Angeles Alvarez (1353513)

    Хэвлэсэн 2009
    “…Finally, the phenyl-bridged complex gives again the analogous phenyl derivative [Mo<sub>2</sub>Cp<sub>2</sub>(Ph)(μ-PCy<sub>2</sub>)(CO)(NO)<sub>2</sub>], but small amounts of dinitrosyl derivatives having terminal benzoyl, [Mo<sub>2</sub>Cp<sub>2</sub>{C(O)Ph}(μ-PCy<sub>2</sub>)(CO)(NO)<sub>2</sub>], bridging benzoyl, [Mo<sub>2</sub>Cp<sub>2</sub>{μ-κ<sup>1</sup>:η<sup>2</sup>-C(O)Ph}(μ-PCy<sub>2</sub>)(NO)<sub>2</sub>], and bridging phenyl ([Mo<sub>2</sub>Cp<sub>2</sub>{μ-κ<sup>1</sup>:η<sup>2</sup>-Ph}(μ-PCy<sub>2</sub>)(NO)<sub>2</sub>], Mo−Mo = 2.9753(5) Å)) ligands are now formed. The latter complex can be selectively generated through the photochemical decarbonylation of the major phenyl complex. …”
  9. 34249

    W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and... F. Albert Cotton (1781341)

    Хэвлэсэн 1997
    “…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”
  10. 34250

    Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... Rishabh Ujjval (9454247)

    Хэвлэсэн 2020
    “…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}­{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}­{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product.…”
  11. 34251

    Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) Thomas Gernon (11046150)

    Хэвлэсэн 2025
    “…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”
  12. 34252

    Reactivity of the Phosphinidene-Bridged Complexes [Mo<sub>2</sub>Cp(μ-κ<sup>1</sup>:κ<sup>1</sup>,η<sup>5</sup>-PC<sub>5</sub>H<sub>4</sub>)(η<sup>6</sup>-1,3,5-C<sub>6</sub>H<sub>... M. Angeles Alvarez (1353513)

    Хэвлэсэн 2012
    “…A side product was also formed during the photochemical treatment of the dicarbonyl substrate, it being finally isolated after chromatographic workup as the alkenylphosphide-chloride complex [Mo<sub>2</sub>CpCl­{μ-κ<sup>1</sup>,η<sup>5</sup>:κ<sup>1</sup>,η<sup>2</sup>-(C<sub>5</sub>H<sub>4</sub>)­PC­(CO<sub>2</sub>Me)CH­(CO<sub>2</sub>Me)}­(η<sup>6</sup>-HMes*)­(CO)] (Mo–P = 2.553(2) and 2.436(2) Ǻ).…”
  13. 34253

    Structurally Flexible and Solution Stable [Ln<sub>4</sub>TM<sub>8</sub>(OH)<sub>8</sub>(L)<sub>8</sub>(O<sub>2</sub>CR)<sub>8</sub>(MeOH)<sub><i>y</i></sub>](ClO<sub>4</sub>)<sub>4... Thomas N. Hooper (1670185)

    Хэвлэсэн 2016
    “…This family of compounds offers an excellent playground for probing how the magnetocaloric effect evolves by introducing either antiferromagnetic or ferromagnetic interactions, or magnetic anisotropy, by substituting the nonmagnetic Zn<sup>II</sup> (<b>1a</b>) with Cu<sup>II</sup> (<b>2a</b>), Ni<sup>II</sup> (<b>6a</b>) or Co<sup>II</sup> (<b>7a</b>), respectively. …”
  14. 34254

    Reactivity of Silyl-Substituted Iron–Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum–Hydride Bond. Synthesis... Isabelle Jourdain (102820)

    Хэвлэсэн 2016
    “…In contrast, treatment of <b>1a</b> with <i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH produces first [(OC)<sub>3</sub>Fe­{μ-Si­(OMe)<sub>2</sub>(OMe)}­(μ-dppm)­Pt­(<i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH<sub>2</sub>)] (<b>2b</b>), which evolves to the dimetallacyclopentenone complex [(OC)<sub>2</sub>Fe­(μ-dppm)­{μ-C­(O)­C­(H)C­(C<sub>6</sub>H<sub>4</sub>F-<i>o</i>)}­Pt­(PPh<sub>3</sub>)] (<b>4b′</b>). …”