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34241
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Хэвлэсэн 2015“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
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34242
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Хэвлэсэн 2015“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
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34243
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Хэвлэсэн 2015“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
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34244
Syntheses of the Uranium Complexes [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>2</sub>{N(SiMe<sub>3</sub>)(SiMe<sub>2</sub>CH<sub>2</sub>B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)}] an...
Хэвлэсэн 1998“…The complex [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>2</sub>{N(SiMe<sub>3</sub>)(SiMe<sub>2</sub>CH<sub>2</sub>B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)}] (<b>1</b>) is formed in the reaction between the hydride complex [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>3</sub>(H)] and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>, and H<sub>2</sub> is evolved. …”
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34245
Influence of the Bite Angle of Dianionic C,N,C-Pincer Ligands on the Chemical and Photophysical Properties of Iridium(III) and Osmium(IV) Hydride Complexes
Хэвлэсэн 2019“…Initially, the phenyl activation gives IrH<sub>2</sub>{κ<sup>2</sup>-<i>C</i>,<i>N</i>-(C<sub>6</sub>H<sub>4</sub>-py-OPh)}(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> (<b>3</b>), which subsequently evolves to IrH{κ<sup>3</sup>-<i>C</i>,<i>N</i>,<i>C</i>-(C<sub>6</sub>H<sub>4</sub>-py-OC<sub>6</sub>H<sub>4</sub>)}(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> (<b>4</b>). …”
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34246
Eh!woza Learner Doccies
Хэвлэсэн 2023“…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”
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34247
Alkynyldiphenylphosphine d<sup>8</sup> (Pt, Rh, Ir) Complexes: Contrasting Behavior toward <i>cis</i>-[Pt(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>(THF)<sub>2</sub>]
Хэвлэсэн 2004“…Thus, treatment of <b>1</b> with 1 equiv of <i>cis</i>-[Pt(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>(THF)<sub>2</sub>] gives the double inserted cationic product [Pt(C<sub>6</sub>F<sub>5</sub>)(S)μ-{C(Ph)C(PPh<sub>2</sub>)C(PPh<sub>2</sub>)C(Ph)(C<sub>6</sub>F<sub>5</sub>)}Pt(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>C⋮CPh)](CF<sub>3</sub>SO<sub>3</sub>) (S = THF, H<sub>2</sub>O), <b>8</b> (S = H<sub>2</sub>O, X-ray), which evolves in solution to the mononuclear complex [(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>C⋮CPh)Pt{C<sub>10</sub>H<sub>4</sub>-1-C<sub>6</sub>F<sub>5</sub>-4-Ph-2,3-κ<i>PP</i>‘(PPh<sub>2</sub>)<sub>2</sub>}](CF<sub>3</sub> SO<sub>3</sub>), <b>9</b> (X-ray), containing a 1-pentafluorophenyl-2,3-bis(diphenylphosphine)-4-phenylnaphthalene ligand, formed by annulation of a phenyl group and loss of the Pt(C<sub>6</sub>F<sub>5</sub>) unit. …”
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34248
Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo<sub>2</sub>(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>(μ-R)(μ-PCy...
Хэвлэсэн 2009“…Finally, the phenyl-bridged complex gives again the analogous phenyl derivative [Mo<sub>2</sub>Cp<sub>2</sub>(Ph)(μ-PCy<sub>2</sub>)(CO)(NO)<sub>2</sub>], but small amounts of dinitrosyl derivatives having terminal benzoyl, [Mo<sub>2</sub>Cp<sub>2</sub>{C(O)Ph}(μ-PCy<sub>2</sub>)(CO)(NO)<sub>2</sub>], bridging benzoyl, [Mo<sub>2</sub>Cp<sub>2</sub>{μ-κ<sup>1</sup>:η<sup>2</sup>-C(O)Ph}(μ-PCy<sub>2</sub>)(NO)<sub>2</sub>], and bridging phenyl ([Mo<sub>2</sub>Cp<sub>2</sub>{μ-κ<sup>1</sup>:η<sup>2</sup>-Ph}(μ-PCy<sub>2</sub>)(NO)<sub>2</sub>], Mo−Mo = 2.9753(5) Å)) ligands are now formed. The latter complex can be selectively generated through the photochemical decarbonylation of the major phenyl complex. …”
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34249
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
Хэвлэсэн 1997“…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”
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34250
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Хэвлэсэн 2020“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product.…”
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34251
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Хэвлэсэн 2025“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”
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34252
Reactivity of the Phosphinidene-Bridged Complexes [Mo<sub>2</sub>Cp(μ-κ<sup>1</sup>:κ<sup>1</sup>,η<sup>5</sup>-PC<sub>5</sub>H<sub>4</sub>)(η<sup>6</sup>-1,3,5-C<sub>6</sub>H<sub>...
Хэвлэсэн 2012“…A side product was also formed during the photochemical treatment of the dicarbonyl substrate, it being finally isolated after chromatographic workup as the alkenylphosphide-chloride complex [Mo<sub>2</sub>CpCl{μ-κ<sup>1</sup>,η<sup>5</sup>:κ<sup>1</sup>,η<sup>2</sup>-(C<sub>5</sub>H<sub>4</sub>)PC(CO<sub>2</sub>Me)CH(CO<sub>2</sub>Me)}(η<sup>6</sup>-HMes*)(CO)] (Mo–P = 2.553(2) and 2.436(2) Ǻ).…”
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34253
Structurally Flexible and Solution Stable [Ln<sub>4</sub>TM<sub>8</sub>(OH)<sub>8</sub>(L)<sub>8</sub>(O<sub>2</sub>CR)<sub>8</sub>(MeOH)<sub><i>y</i></sub>](ClO<sub>4</sub>)<sub>4...
Хэвлэсэн 2016“…This family of compounds offers an excellent playground for probing how the magnetocaloric effect evolves by introducing either antiferromagnetic or ferromagnetic interactions, or magnetic anisotropy, by substituting the nonmagnetic Zn<sup>II</sup> (<b>1a</b>) with Cu<sup>II</sup> (<b>2a</b>), Ni<sup>II</sup> (<b>6a</b>) or Co<sup>II</sup> (<b>7a</b>), respectively. …”
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34254
Reactivity of Silyl-Substituted Iron–Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum–Hydride Bond. Synthesis...
Хэвлэсэн 2016“…In contrast, treatment of <b>1a</b> with <i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH produces first [(OC)<sub>3</sub>Fe{μ-Si(OMe)<sub>2</sub>(OMe)}(μ-dppm)Pt(<i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH<sub>2</sub>)] (<b>2b</b>), which evolves to the dimetallacyclopentenone complex [(OC)<sub>2</sub>Fe(μ-dppm){μ-C(O)C(H)C(C<sub>6</sub>H<sub>4</sub>F-<i>o</i>)}Pt(PPh<sub>3</sub>)] (<b>4b′</b>). …”