Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ανά Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ανά Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... ανά Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”

Proton-Coupled Electron Transfer to a Molybdenum Ethylene Complex Yields a β‑Agostic Ethyl: Structure, Dynamics and Mechanism ανά Máté J. Bezdek (1980178)

“…Comparison of p<i>K</i>_a and electrochemical data for the complexes <b>[1-C₂H₄]⁺</b> and <b>[1-NH₃]⁺</b> in combination with a deuterium kinetic isotope effect (<i>k</i>_H/<i>k</i>_D) of 3.5(2) at 23 °C support a PCET process involving initial electron transfer followed by protonation leading to the formation of <b>[1-CH₂CH₃]⁺</b> and <b>[1-NH₂]⁺</b> or a concerted pathway. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... ανά Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ανά Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Impact of Photosensitizing Multilayered Structure on Ruthenium(II)-Dye-Sensitized TiO₂‑Nanoparticle Photocatalysts ανά Sogo Furugori (4275475)

“…Thus, crucial aspects of the energy- and electron-transfer mechanism for the photocatalytic H₂ and O₂ evolution reactions involve not only the Ru­(II)-complex-TiO₂ interface but also the multilayered structure of the Ru­(II)-photosensitizers on the Pt–TiO₂ surface.…”

Multiple sequence alignment of the NpDps4 with a selection of its homolog sequences from six cyanobacterial phylogenetic groups. ανά Christoph Howe (7114679)

“…Amino acids of the ferroxidase center (FOC) are indicated by an asterisk *A, *B or *A/B indicating the involvement of metal coordination at site A and/or B in regards to the His-type FOC of NpDps4 and TeDpsA. …”

Tuning the Inclusion Properties and Solid-State Reactivity of Second Sphere Adducts Using Conformationally Flexible Bidentate Ligands ανά Fang Guo (105824)

“…We demonstrate that some of the second sphere adducts are dynamic, showing reversible guest release/uptake involving crystalline-to-amorphous-to-crystalline phase transformations. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ανά Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

New Insights into the Visible-Light-Induced DNA Cleavage Activity of Dipyridoquinoxaline Complexes of Bivalent 3d-Metal Ions ανά Mithun Roy (2090650)

“…The DNA cleavage reactions at visible light under aerobic conditions involve the formation of hydroxyl radical. The Co^II complex shows photocleavage of DNA under an argon atmosphere. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ανά Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ανά Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... ανά Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ανά Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ανά Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

P−C and C−C Bond Formation by Michael Addition in Platinum-Catalyzed Hydrophosphination and in the Stoichiometric Reactions of Platinum Phosphido Complexes with Activated Alkenes... ανά Corina Scriban (1989502)

“…Subsequent C−H bond formation involving the Pt−H and the carbanion would yield the product R₂PCH₂CH₂X (<b>3</b>) and regenerate the catalyst, while attack of the carbanion on another alkene would yield byproducts derived from more than one alkene, such as R₂P(CH₂CH(X))<i>_n</i>CH₂CH₂X (<b>7</b>). …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ανά Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

New Insights into the Visible-Light-Induced DNA Cleavage Activity of Dipyridoquinoxaline Complexes of Bivalent 3d-Metal Ions ανά Mithun Roy (2090650)

“…The DNA cleavage reactions at visible light under aerobic conditions involve the formation of hydroxyl radical. The Co^II complex shows photocleavage of DNA under an argon atmosphere. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... ανά Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”