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30961
Unusual Recognition and Separation of Hydrated Metal Sulfates [M<sub>2</sub>(μ-SO<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub><i>n</i></sub>, M = Zn<sup>II</sup>, Cd<sup>II</sup>,...
Опубликовано 2016“...Finally, <b>L1</b> is found to be highly efficient in removing ZnSO<sub>4</sub> from both aqueous and semiaqueous medium as complex <b>1</b> in the presence of other competing Zn<sup>II</sup> salts via precipitation through crystallization. ...”
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30962
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
Опубликовано 1997“...The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. ...”
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30963
An Approach to Modified Bedside Percutaneous Tracheostomy During the COVID-19 Pandemic
Опубликовано 2020“...To standardize patient selection, they formed an institutional advisory team composed of intensive care specialists, pulmonologists, surgeons, and palliative care consultants for careful consideration of individualized timing, risks, and benefits....”
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30964
Exceptional Thermal Stability in a Supramolecular Organic Framework: Porosity and Gas Storage
Опубликовано 2010“...In the solid state [L<sup>1</sup>]·2.5DMF·3MeOH (<b>SOF-1</b>) crystallizes in the monoclinic space group <i>P</i>2<sub>1</sub>/<i>c</i> and forms a 3D stable supramolecular organic framework via strong N−H···N<sub>py</sub> hydrogen bonds and π−π interactions. ...”
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30965
1736: L/Cpl Benjamin Elsegood (photographs; medals)
Опубликовано 2024“...The 1st Bttn (part of III Corps) was formed up at Hazebrouck, comprising the troops who had moved north from The Aisne and those (including Ben) joining from the UK, and advanced to the German lines east of Hazebrouck on 13 October 1014. 18th Infantry Bde., including 1st W. ...”
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30966
Two Versatile <i>N</i>,<i>N</i>‘-Bipyridine-Type Ligands for Preparing Organic−Inorganic Coordination Polymers: New Cobalt- and Nickel-Containing Framework Materials
Опубликовано 2001“...Thermogravimetric studies showed that after complete removal of the solvents, the frameworks are stable to temperatures between 234 °C and 260 °C....”
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30967
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Опубликовано 2020“...The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product....”
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30968
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Опубликовано 2025“...Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. ...”
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30969
Data from: Ectoparasites modify escape behaviour, but not performance, in a coral reef fish
Опубликовано 2014“...Increasing intensity was assumed to be related to more energetically costly forms of locomotion, and therefore provided an estimate of the costs of flight. ...”
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30970
File S1 - Systematic Dissection of the <i>Agrobacterium</i> Type VI Secretion System Reveals Machinery and Secreted Components for Subcomplex Formation
Опубликовано 2013“...Two TssB-specific protein bands are detected when expressed in <i>E. coli</i>, which suggests that a truncated TssB (*) may be formed by proteolysis due to the overexpression in <i>E. coli....”
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30971
17- and 19-Electron Complexes [Fe<sup>III</sup>(η<sup>5</sup>-C<sub>5</sub>R<sub>5</sub>)(S<sub>2</sub>CNMe<sub>2</sub>)L]<sup><i>n</i>+</sup> (<i>n</i> = 1, 0): Electronic Struct...
Опубликовано 1996“...The cyclic voltammogram of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b><sup>+/<b>0</b>/-</sup>, <b>9‘</b><sup>+/<b>0</b>/-</sup>, and solvent (DMF) adducts in 18- and 19e states....”
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30972
Deprotonation of μ-Vinyliminium Ligands in Diiron Complexes: A Route for the Synthesis of Mono- and Polynuclear Species Containing Novel Multidentate Ligands
Опубликовано 2005“...The C<sub>β</sub>−H hydrogen in the diiron vinyliminium complexes [Fe<sub>2</sub>{μ-η<sup>1</sup>:η<sup>3</sup>-C<sub>γ</sub>(R‘)C<sub>β</sub>HC<sub>α</sub>N(Me)(R)}(μ-CO)(CO)(Cp)<sub>2</sub>][SO<sub>3</sub>CF<sub>3</sub>] (R = Me, <b>1</b>; R = Bz, <b>2</b> (Bz = CH<sub>2</sub>Ph); R = Xyl, <b>3 (</b>Xyl <b>=</b>2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)) is easily removed by sodium hydride; different products are consequently formed, depending on the nature of the substituents R and R‘. ...”
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30973
Deprotonation of μ-Vinyliminium Ligands in Diiron Complexes: A Route for the Synthesis of Mono- and Polynuclear Species Containing Novel Multidentate Ligands
Опубликовано 2005“...The C<sub>β</sub>−H hydrogen in the diiron vinyliminium complexes [Fe<sub>2</sub>{μ-η<sup>1</sup>:η<sup>3</sup>-C<sub>γ</sub>(R‘)C<sub>β</sub>HC<sub>α</sub>N(Me)(R)}(μ-CO)(CO)(Cp)<sub>2</sub>][SO<sub>3</sub>CF<sub>3</sub>] (R = Me, <b>1</b>; R = Bz, <b>2</b> (Bz = CH<sub>2</sub>Ph); R = Xyl, <b>3 (</b>Xyl <b>=</b>2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)) is easily removed by sodium hydride; different products are consequently formed, depending on the nature of the substituents R and R‘. ...”
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30974
Cary spongy moth pupal predation and natural pupation data
Опубликовано 2025“...<p dir="ltr">The Forest Response to Stress and Damage (frequently referred to as FORSTAD) and long term forest monitoring project began in 1992 to study how mixed-oak forests respond to multiple forms of environmental change. The research took place at Cary Institute of Ecosystem Studies in the Hudson Valley of New York. ...”
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30975
S1 File - Germinal Center Kinases SmKIN3 and SmKIN24 Are Associated with the <i>Sordaria macrospora</i> Striatin-Interacting Phosphatase and Kinase (STRIPAK) Complex
Опубликовано 2015“...Expression of <i>Smkin24</i> with remaining intron I but removed intron II-IV results in a protein comprising aa 94–882 of the protein derived from <i>Smkin24</i> without introns. ...”
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30976
Deprotonation of μ-Vinyliminium Ligands in Diiron Complexes: A Route for the Synthesis of Mono- and Polynuclear Species Containing Novel Multidentate Ligands
Опубликовано 2005“...The C<sub>β</sub>−H hydrogen in the diiron vinyliminium complexes [Fe<sub>2</sub>{μ-η<sup>1</sup>:η<sup>3</sup>-C<sub>γ</sub>(R‘)C<sub>β</sub>HC<sub>α</sub>N(Me)(R)}(μ-CO)(CO)(Cp)<sub>2</sub>][SO<sub>3</sub>CF<sub>3</sub>] (R = Me, <b>1</b>; R = Bz, <b>2</b> (Bz = CH<sub>2</sub>Ph); R = Xyl, <b>3 (</b>Xyl <b>=</b>2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)) is easily removed by sodium hydride; different products are consequently formed, depending on the nature of the substituents R and R‘. ...”
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30977
Deprotonation of μ-Vinyliminium Ligands in Diiron Complexes: A Route for the Synthesis of Mono- and Polynuclear Species Containing Novel Multidentate Ligands
Опубликовано 2005“...The C<sub>β</sub>−H hydrogen in the diiron vinyliminium complexes [Fe<sub>2</sub>{μ-η<sup>1</sup>:η<sup>3</sup>-C<sub>γ</sub>(R‘)C<sub>β</sub>HC<sub>α</sub>N(Me)(R)}(μ-CO)(CO)(Cp)<sub>2</sub>][SO<sub>3</sub>CF<sub>3</sub>] (R = Me, <b>1</b>; R = Bz, <b>2</b> (Bz = CH<sub>2</sub>Ph); R = Xyl, <b>3 (</b>Xyl <b>=</b>2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)) is easily removed by sodium hydride; different products are consequently formed, depending on the nature of the substituents R and R‘. ...”
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30978
Enhancing accessibility of Excel spreadsheets
Опубликовано 2024“...</li><li><a href="https://youtu.be/71EuSZwCtVE">Excel 2013 & 2016: Accessible Excel Forms, Part 1 (YouTube video)</a>. Governors Committee on People with Disabilities....”
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30979
Multifocal Lung Cancer Discussion and Case Presentation
Опубликовано 2018“...Within the left lower lobe of the lung, the pathologic assessment revealed adenocarcinoma forming 10 nodules that ranged in size from 0.4 - 1.0 cm, with each tumor having a negative margin. ...”
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30980
Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient <i>Tris</i>(aryl)boranes B(C<sub>6</sub>F<sub>5</sub>...
Опубликовано 2011“...Reaction of C<sub>6</sub>Cl<sub>5</sub>Li with BCl<sub>3</sub> in a Et<sub>2</sub>O/hexane slurry selectively produced B(C<sub>6</sub>Cl<sub>5</sub>)<sub>2</sub>Cl, which undergoes B–Cl exchange with CuC<sub>6</sub>F<sub>5</sub> to afford B(C<sub>6</sub>F<sub>5</sub>)(C<sub>6</sub>Cl<sub>5</sub>)<sub>2</sub> (<b>5</b>). While <b>3</b> forms a complex with H<sub>2</sub>O, which can be rapidly removed under vacuum or in the presence of molecular sieves, B(C<sub>6</sub>Cl<sub>5</sub>)<sub>3</sub> (<b>6</b>) is completely stable to refluxing toluene/H<sub>2</sub>O for several days. ...”