Structural, Electrochemical, and Spectroscopic Investigation of Acetate Bridged Dinuclear Tetrakis-Schiff Base Macrocycles of Mn and Zn od Subhadeep Kal (1720603)

“…The electrochemical and spectroscopic analysis of these complexes will aid in future studies involving electrocatalytic processes with related dinuclear macrocycles.…”

The Dinuclear Zn(II) Complex Catalyzed Cyclization of a Series of 2-Hydroxypropyl Aryl Phosphate RNA Models:  Progressive Change in Mechanism from Rate-Limiting P−O Bond Cleavage t... od Shannon E. Bunn (2438131)

“…The data are analyzed in terms of a multistep process whereby a first formed complex rearranges to a reactive complex with a doubly activated phosphate coordinated to both metal ions. …”

Reversible Switching of the Coordination Modes of a Pyridine-Functionalized Quinonoid Zwitterion; Its Di- and Tetranuclear Palladium Complexes od Alessio Ghisolfi (1588846)

“…This switch modifies the extent of π-delocalization involving the potentially antiaromatic quinonoid moiety and is accompanied by a significant color change, from red in <b>3</b> to green in <b>4</b>. …”

Organometallic Complexes of Scandium and Yttrium Supported by a Bulky Salicylaldimine Ligand od David J. H. Emslie (1425715)

“…These compounds are highly thermally stable, decomposing at temperatures above 140 °C via a pathway involving metalation of one of the N-aryl isopropyl methyl groups. …”

Hormone-independent, EcR-mediated endoreplication of SC DNA is stimulated by mating. od Aaron Leiblich (3211392)

“…(F) Proposed model explaining the different forms of hormone-dependent and hormone-independent, EcR-mediated SC growth in virgin and mated males. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units od Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

[(Cp−CMe₂−Flu)₂Ln]^-[Li(ether)<i>_n</i>]⁺ (Ln = Y, La):  Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and... od Evgueni Kirillov (1425814)

“…The fluorenyl ligands in <b>2</b> show an unprecedented η¹ bonding mode and a rare η³ bonding mode involving, respectively, a carbon atom of a phenyl ring and the bridgehead carbon atom of the central ring and the two adjacent carbon atoms of one six-membered ring. …”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks od Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units od Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

Synthesis and Characterization of Dimetallic Oxorhenium(V) and Dioxorhenium(VII) Compounds, and a Study of Stoichiometric and Catalytic Reactions od James H. Espenson (2536300)

“…They, too, have similar Re₂S₂ cores that involve donor atoms from two of the dithiolate ligands; the third dithiolate chelates one of the rhenium atoms. …”

Ligand-Induced and Reductively Induced Alkyne−Isocyanide Coupling Reactions of [Mo(CNBu^t)₃(PhC⋮CPh)(η⁵-C₅Me₅)][BF₄... od Christopher J. Adams (1847317)

“…A similar reaction of <b>4</b> with P(OMe)₃ generates [Mo{C(NHBu^t)C(Ph)C(Ph)CN}(CNBu^t){P(OMe)₃}(η⁵-C₅Me₅)][BF₄], <b>5</b>, involving the same coupling and elimination pattern. …”

Serial imaging reveals regional dynamics of gut bacterial colonization. od Leslie Ann Jaramillo Koyama (8363442)

“…<i>plantarum</i> was removed, and individual animals were imaged as indicated. …”

sEMG of Swallowing, Coughing and Speech od Johnny McNulty (6766148)

“…The  posterior two electrodes formed the intercostal recording dipole. The  anterior electrode and a single electrode placed on the left 9th/10th  intercostal space formed the diaphragm recording dipole. …”

Arsenic(III) Halide Complexes with Acyclic and Macrocyclic Thio- and Selenoether Coligands:  Synthesis and Structural Properties od Nicholas J. Hill (1333515)

“…[AsCl₃([14]aneS₄)] forms an infinite sheet involving two μ²-chloro ligands on each As but bridging to two distinct As centers. …”

Structural Diversity in Supramolecular Complexes of MCl₃ (M = As, Sb, Bi) with Constrained Thio- and Seleno-Ether Ligands od William Levason (1275612)

“…[BiCl₃{<i>o</i>-C₆H₄(SeMe)₂}] comprises distorted square pyramidal units involving pyramidal BiCl₃ primary coordination and a weakly chelating diselenoether ligand, and assembled into infinite chains through long bridging Bi···Cl interactions via all three Clʼs. …”

Examining prediction formation in empirical and model position representations. od William Turner (2220598)

“…In the main analysis we consider the ‘steady state’ of position representations formed after sustained exposure to motion along a predictable trajectory, and found evidence of progressive extrapolation. …”

Associations between zircon and Fe–Ti oxides in Hiltaba event magmatic rocks, South Australia: atomic- or pluton-scale processes? od M. R. M. Ferguson (7386296)

“…The lack of pre-magmatic zircon, consistent intra-grain and inter-grain zircon compositional trends, the predominance of oscillatory zoned zircon with morphologies indicating growth from hot, evolved silicate melts, and the lack of evidence for zircon recrystallisation, indicates that zircon crystallised in the host GRV and RDG magmas. …”

Mutations in DNA polymerase III both drive mutation rate increase by 1,000-fold (DnaQ^L145P; ε subunit) and rescue fitness of hypermutator clones (DnaE^T771S; α... od Ricardo S. Ramiro (8555421)

“…AA, amino acids; CFU, colony-forming units; Glu, glucose; LB, lysogeny broth; Nal^R, nalidixic acid resistance; ns, not significant; OD_600nm, optical density at 600 nm; PDB, Protein Data Bank; Rif^R, rifampicin resistance; Sor, sorbitol.…”

Expression and localization of the DEN1 homolog DenA (AN10456) during development of the fungus <i>Aspergillus nidulans</i>. od Martin Christmann (280300)

“…In the presence of light <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-vonZeskaKress1" target="_blank">[4]</a> an aerial filament with an apical vesicle forms the asexual developmental structure (conidiophore) <a href="http://www.plosgenetics.org/article/info:doi/10.1371/journal.pgen.1003275#pgen.1003275-Morimoto1" target="_blank">[5]</a> and releases the uninucleate conidiospores (green) into the air. …”

Cary spongy moth larval data od Clive G. Jones (15632745)

“…<p dir="ltr">The Forest Response to Stress and Damage (frequently referred to as FORSTAD) and long term forest monitoring project began in 1992 to study how mixed-oak forests respond to multiple forms of environmental change. The research took place at Cary Institute of Ecosystem Studies in the Hudson Valley of New York. …”