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34241
The Permian Watershed tungsten deposit (northeast Queensland, Australia): fluid inclusion and stable isotope constraints
Veröffentlicht 2024“… Early, D<sub>1–2</sub> scheelite mineralisation in Carboniferous monzonite and skarn-altered conglomerate formed during regional prograde metamorphism, which reached upper greenschist to lower amphibolite facies conditions. …”
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34242
Syntheses, Structures, and Spectroscopic Properties of K<sub>9</sub>Nd[PS<sub>4</sub>]<sub>4</sub>, K<sub>3</sub>Nd[PS<sub>4</sub>]<sub>2</sub>, Cs<sub>3</sub>Nd[PS<sub>4</sub>]<su...
Veröffentlicht 2008“… Resonant Raman excitation via a B-term mechanism involving the <sup>4</sup>I<sub>15/2</sub> and <sup>4</sup>F<sub>3/2</sub> intermediate states may account for the significant intensity enhancement of the ER transitions with respect to the symmetric P−S stretching vibration ν<sub>1</sub>. …”
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34243
Creative methods and practices to mobilising public health knowledge webinar
Veröffentlicht 2025“… </p><p dir="ltr">In the field of public health, mobilising evidence and other forms of knowledge is essential to developing effective, equitable, and sustainable interventions. …”
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34244
Stereoselectivity in the Formation of Metallomacrocycles from [Mo(NO){HB(3,5-Me<sub>2</sub>C<sub>3</sub>HN<sub>2</sub>)<sub>3</sub>}I<sub>2</sub>] and Ditopic Proligands: The X-ra...
Veröffentlicht 1999“… These binuclear complexes are formed under kinetic control so that <i>syn</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2s</b>, forms more rapidly than <i>anti</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2a</b>, but in lower yield. …”
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34245
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Veröffentlicht 2015“… Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
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34246
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Veröffentlicht 2015“… Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
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34247
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Veröffentlicht 2015“… Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
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34248
Syntheses of the Uranium Complexes [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>2</sub>{N(SiMe<sub>3</sub>)(SiMe<sub>2</sub>CH<sub>2</sub>B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)}] an...
Veröffentlicht 1998“… The complex [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>2</sub>{N(SiMe<sub>3</sub>)(SiMe<sub>2</sub>CH<sub>2</sub>B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)}] (<b>1</b>) is formed in the reaction between the hydride complex [U{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>3</sub>(H)] and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>, and H<sub>2</sub> is evolved. …”
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34249
Eh!woza Learner Doccies
Veröffentlicht 2023“… </p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”
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34250
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
Veröffentlicht 1997“… The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”
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34251
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Veröffentlicht 2020“… The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product. …”
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34252
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Veröffentlicht 2025“… Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”
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34253
Reactivity of the Phosphinidene-Bridged Complexes [Mo<sub>2</sub>Cp(μ-κ<sup>1</sup>:κ<sup>1</sup>,η<sup>5</sup>-PC<sub>5</sub>H<sub>4</sub>)(η<sup>6</sup>-1,3,5-C<sub>6</sub>H<sub>...
Veröffentlicht 2012“… A side product was also formed during the photochemical treatment of the dicarbonyl substrate, it being finally isolated after chromatographic workup as the alkenylphosphide-chloride complex [Mo<sub>2</sub>CpCl{μ-κ<sup>1</sup>,η<sup>5</sup>:κ<sup>1</sup>,η<sup>2</sup>-(C<sub>5</sub>H<sub>4</sub>)PC(CO<sub>2</sub>Me)CH(CO<sub>2</sub>Me)}(η<sup>6</sup>-HMes*)(CO)] (Mo–P = 2.553(2) and 2.436(2) Ǻ). …”
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34254
Structural and Kinetic Study of Reversible CO<sub>2</sub> Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes
Veröffentlicht 2007“… Under a N<sub>2</sub> atmosphere the complexes evolve CO<sub>2</sub> and revert to the starting hydroxo complexes <b>1</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub> and <b>2</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>, a reaction the rate of which linearly depends on [H<sub>2</sub>O]. …”