Rezultaty 1.841 - 1.860 Rezultaty od 28.093 Dla wyszukiwania 'form is (((((removedds. OR evolvesdss.) OR resolves.) OR involved.) OR involves.) OR resolve.)', Czas wyszukiwania: 0,71s Redukuj rezultaty
  1. 1841
  2. 1842
  3. 1843
  4. 1844
  5. 1845
  6. 1846
  7. 1847
  8. 1848
  9. 1849
  10. 1850

    Evidence for the Involvement of 5f Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes od Thibault Cantat (1574710)

    Wydane 2008
    “…The insertion of a second diazoalkane molecule into the sole metal−carbon bond in the mono(hydrazonato) complexes involves a high energy barrier (∼20 kcal/mol) for the zirconium(IV) system, whereas the actinides can facilitate the approach of the diazoalkane by coordination (formation of an adduct) and its insertion into the An−C bond with a very low barrier on the potential energy surface.…”
  11. 1851
  12. 1852
  13. 1853
  14. 1854
  15. 1855
  16. 1856
  17. 1857
  18. 1858
  19. 1859
  20. 1860