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28081
Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H<sub>2</sub>meppp = <i>meso</i>-1,3-Bis[...
Опубліковано 2014“...The reaction is assumed to involve an alkenyl complex, [Ni(μ-meppp)RhCp*(CHCHPh)]NO<sub>3</sub> (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. ...”
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28082
Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H<sub>2</sub>meppp = <i>meso</i>-1,3-Bis[...
Опубліковано 2014“...The reaction is assumed to involve an alkenyl complex, [Ni(μ-meppp)RhCp*(CHCHPh)]NO<sub>3</sub> (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. ...”
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28083
Creative methods and practices to mobilising public health knowledge webinar
Опубліковано 2025“...</p><p dir="ltr">In the field of public health, mobilising evidence and other forms of knowledge is essential to developing effective, equitable, and sustainable interventions. ...”
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28084
Stereoselectivity in the Formation of Metallomacrocycles from [Mo(NO){HB(3,5-Me<sub>2</sub>C<sub>3</sub>HN<sub>2</sub>)<sub>3</sub>}I<sub>2</sub>] and Ditopic Proligands: The X-ra...
Опубліковано 1999“...These binuclear complexes are formed under kinetic control so that <i>syn</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2s</b>, forms more rapidly than <i>anti</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2a</b>, but in lower yield. ...”
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28085
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Опубліковано 2015“...Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. ...”
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28086
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Опубліковано 2015“...Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. ...”
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28087
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Опубліковано 2015“...Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. ...”
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28088
Mixed-Metal Cluster Chemistry. 30. Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes
Опубліковано 2007“...Some insight into the mechanism by which these clusters function as optical limiters has been gleaned from complementary pump−probe studies, with their behavior consistent with a fast nonlinear absorption process followed by reverse saturable absorption involving metastable excited states of greater than nanosecond lifetime....”
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28089
Eh!woza Learner Doccies
Опубліковано 2023“...</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. ...”
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28090
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
Опубліковано 1997“...The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. ...”
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28091
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Опубліковано 2020“...The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product....”
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28092
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Опубліковано 2025“...Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. ...”
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28093
17- and 19-Electron Complexes [Fe<sup>III</sup>(η<sup>5</sup>-C<sub>5</sub>R<sub>5</sub>)(S<sub>2</sub>CNMe<sub>2</sub>)L]<sup><i>n</i>+</sup> (<i>n</i> = 1, 0): Electronic Struct...
Опубліковано 1996“...The cyclic voltammogram of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b><sup>+/<b>0</b>/-</sup>, <b>9‘</b><sup>+/<b>0</b>/-</sup>, and solvent (DMF) adducts in 18- and 19e states....”