Thiophene-NPN Ligand Supported Rare-Earth Metal Bis(alkyl) Complexes. Synthesis and Catalysis toward Highly <i>trans</i>-1,4 Selective Polymerization of Butadiene Autor Dun Wang (525747)

“…Each metal ion is coordinated by a NPN ligand, two <i>trans</i>-located alkyl groups, and a THF molecule, forming a distorted trigonal-bipyramidal geometry. …”

Altered Expression of Human Smooth Muscle Myosin Phosphatase Targeting (MYPT) Isovariants with Pregnancy and Labor Autor Jon Lartey (320918)

“…</p><p>Results</p><p>We found a reduction in the expression of PPP1R12A, PPP1R12BLZ+, PPP1R16A and PPP1R16B mRNA in late pregnancy (not-in-labor) relative to non-pregnancy. …”

Activation of Acetyl Ligands through Hydrogen Bonds: A New Way to Platinum(II) Complexes Bearing Protonated Iminoacetyl Ligands Autor Tim Kluge (1848478)

“…The hydrogen-bond activated acetyl and iminoacetyl ligands in type <b>5</b>, <b>7</b>, and <b>8</b> complexes were found to undergo in CD₃OD solutions facile H/D exchange reactions resulting in complexes bearing C­(CD₃)O/C­(CD₃)NDR′ ligands. …”

Synthesis, Characterization, and Electrochemical Properties of Benzyloxy-Functionalized Diiron 1,3-Propanedithiolate Complexes Relevant to the Active Site of [FeFe]-Hydrogenases Autor Li-Cheng Song (1415671)

“…The benzyloxy-functionalized all-carbonyl complex [(μ-SCH₂)₂CH­(OCH₂Ph)]­Fe₂(CO)₆ (<b>A</b>) can be prepared by condensation reaction of 2-benzyloxy-1,3-dibromopropane with the in situ generated (μ-LiS)₂Fe₂(CO)₆, whereas it reacts with the in situ formed N-heterocyclic carbene 1-mesityl-3-methylimidazol-2-ylidene (I_Mes/Me) to give the corresponding carbene monosubstituted complex [(μ-SCH₂)₂CH­(OCH₂Ph)]­Fe₂(CO)₅(I_Mes/Me) (<b>1</b>). …”

Adherence to Option B+ ART by study arm. Autor Alexander Amone (6397007)

“…We used Log-rank and Chi-Square p-values to test the equality of Kaplan-Meier survival probabilities and hazard rates (HR) for failure to retain in care for any reason by study arm.</p><p>Results</p><p>There was no significant difference in adherence to PMTCT clinic visits or to ART or in median viral loads between FLC and SOC arms at any follow-up time points. …”

Structural Features of the Modulated BiCu₂(P_1-<i>_x</i>V<i>_x</i>)O₆ Solid Solution; 4-D Treatment of <i>x</i> = 0.87 Compound... Autor Olivier Mentré (2450311)

“…Furthermore, between two ribbons the Cu²⁺ arrangement forms magnetically isolated zigzag copper two-leg ladders. …”

Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites Autor Su-Yun Zhang (2194498)

“…The existence of V⁴⁺ ions in Sr₂(VO)₃(SeO₃)₅ is also confirmed by magnetic measurements. The results of optical diffuse-reflectance spectrum measurements and electronic structure calculations based on density functional theory (DFT) methods indicate that all six compounds are wide-band gap semiconductors.…”

Stimulation of genes regulated through the Imd pathway by bacteria and zymosan in Aag2 cells. Autor Tiffany A. Russell (7828097)

“…(C-E) Fold induction (i) of genes measured by RT-qPCR in Aag2 cells stimulated for 24 h with 1,000 colony forming units (CFU)/cell of heat-inactivated <i>L</i>. …”

Data from: Bacterial Abundance and Antimicrobial Resistance Prevalence Carried by Adult House Flies (Diptera: Muscidae) at Kansas Dairy and Beef Cattle Operations Autor Victoria Pickens (19726672)

“…We enumerated colony forming units (CFUs) of culturable aerobic bacteria and suspected coliforms (SC) from house fly homogenates on nonselective (tryptic soy agar, TSA) and selective (violet-red bile agar, VRBA) media to investigate factors, such as fly sex, farm type, location, and climate, which may be associated with bacterial abundances carried by house flies. …”

Reactivity of Cationic Triruthenium Carbonyl Clusters: From Pyrimidinium Ligands to N-Heterocyclic Carbenes Autor Javier A. Cabeza (1478377)

“…This cationic complex can be reduced to the short-lived radical species <b>4^•</b>, which spontaneously dimerizes by forming an intermolecular C−C bond between the ligands of two such radicals. …”

Thermal Isomerization of the Buchwald Seven-Membered Zirconacyclocumulene and Its Interaction with Acetylenes. Synthesis and Structures of Novel Seven-Membered Zirconacyclocumulene... Autor Vladimir V. Burlakov (1589020)

“…A remarkable peculiarity of complex <b>8</b> is its ability to undergo a rapid degenerate rearrangement at room temperature in toluene solution, as a result of which only two rather than four singlets of the Me₃Si groups are observed in the ¹H NMR spectrum of <b>8</b> under such conditions. …”

File S1 - Two Different Conformations in Hepatitis C Virus p7 Protein Account for Proton Transport and Dye Release Autor Siok Wan Gan (506317)

“…Similar results were obtained for recombinant p7 (not shown). …”

Spin-Crossover Behavior in Cyanide-bridged Iron(II)−Gold(I) Bimetallic 2D Hofmann-like Metal−Organic Frameworks Autor Gloria Agustí (2444860)

“…Although only compounds <b>2</b> and <b>4</b> can be considered strictly isostructurals, all of the components of this family are made up of parallel stacks of corrugated {Fe[Au(CN)₂]₂}_<i>n</i> grids. The grids are formed by edge sharing of {Fe₄[Au(CN)₂]₄} pseudosquare moieties. …”

DataSheet_1_Patient-reported long-term outcome following allogeneic hematopoietic stem cell transplantation in pediatric chronic myeloid leukemia.pdf Autor Oliver Schleicher (13879970)

“…Regular follow-up examinations are mandatory helping to avoid that late secondary neoplasias, CML-relapse, and disorders forming the broad range of possible long-term consequences of HSCT are not detected too late.…”

Specific functions of ADR1 and NRG1 subfamilies during ETI. Autor Svenja C. Saile (9375134)

“…Experiment was done 3 times with similar results. Letters indicate statistically significant differences following ANOVA with Tukey’s test (α = 0.05). …”

Follow-up study of consumer-decides OTC model (Humes et al., 2019) Autor Larry E. Humes (4417477)

“…</div><div><b><br></b></div><div><b>Supplemental Material S2. </b>Data collection forms. </div><div><br></div><div>Humes, L. E., Kinney, D. …”

Carbon Monoxide Coordination and Reversible Photodissociation in Copper(I) Pyridylalkylamine Compounds Autor H. Christopher Fry (1433509)

“…Through solid- and solution-state analyses, we concluded that the photolabile carbonyl species in solution possess a tridentate coordination mode, forming strictly five-membered chelate rings to the copper ion with one dangling arm of the tripodal ligand. …”

Mediastinal Envelope Closure in Total Minimally Invasive Ivor Lewis Esophagectomy Autor Katemanee Burapachaisri (17957204)

“…Next, the gastric conduit was pulled up into the mediastinum and the esophagogastric anastomosis was formed. The stomach was fully tubularized and the final specimen was removed through a wound protector. …”

Silapentadienyl−Iridium−Phosphine Chemistry Autor John R. Bleeke (1887688)

“…In this case, hydride first migrates from iridium to C2 of the silapentadienyl ligand, and then the resulting butenyl group migrates from silicon to iridium, forming an iridacyclopentene product, <b>6</b>. …”

Rapid Three-Step Cleavage of RNA and DNA Model Systems Promoted by a Dinuclear Cu(II) Complex in Methanol. Energetic Origins of the Catalytic Efficacy Autor Zhong-Lin Lu (222370)

“…The first of these is interpreted as a binding step which is linearly dependent on [catalyst] while the second is a unimolecular step independent of [catalyst] proposed to be a rearrangement that forms a doubly Cu(II)-coordinated phosphate. The catalysis of the cleavage of <b>1</b> and <b>3</b> is very strong, the first-order rate constants for formation of <i>p</i>-nitrophenol from the complex being ∼0.7 s^-1 and 2.4 × 10^-3 s^-1, respectively. …”