Formation of C−C, C−N, and C−O Links between Isonitrile, Cyclopentadienyl, and Hydroxide Ligands Bound to Molybdenum(III):  Syntheses and Crystal Structures of μ-Aminocarbyne and μ... 由 Wilfried-Solo Ojo (1727908)

“...When the mixture of <b>2b</b>, (Me₄N)OH (excess), and Bu^tNC (excess) in tetrahydrofuran was heated under reflux for a short time (2 h), complex <b>5b1</b> was formed in good yields. Compounds <b>5b1 </b>and <b>5b2</b> are linkage isomers, which differ only in the mode of coordination of the μ-amino-oxycarbene ligand to the Mo1−Mo2 unit; <b>5b1</b> converts into <b>5b2</b> on prolonged heating. ...”

Influence of the Bite Angle of Dianionic C,N,C-Pincer Ligands on the Chemical and Photophysical Properties of Iridium(III) and Osmium(IV) Hydride Complexes 由 Ruth Castro-Rodrigo (2105221)

“...The study of the reactions of IrH₅(PⁱPr₃)₂ (<b>1</b>) with 2,6-diphenylpyridine and 2-phenoxy-6-phenylpyridine and the photophysical characterization of some of the resulting compounds, as well as their osmium counterparts, reveal that the bite angle of dianionic C,N,C-pincer ligands has a marked influence on the chemical and photophysical properties of iridium­(III) and osmium­(IV) hydride complexes. ...”

Synthesis, Cation Ordering, and Magnetic Properties of the (Sb₁_-<i>_x</i>Pb<i>_x</i>)₂(Mn₁_-<i><sub>y</sub... 由 Artem M. Abakumov (1283724)

“...A replacement of Sb by Pb results in the oxidation of Sb³⁺ to Sb⁵⁺, which in turn replaces Mn²⁺ cations in octahedrally coordinated positions within the infinite rutile-type chains. ...”

Data from: Unusual but consistent latitudinal patterns in macroalgal habitats and their invertebrate communities across two countries 由 Hannah Lloyd (12840758)

“...Main conclusions: Our results support other studies showing that large-scale patterns can emerge from systems where there is high local-scale variability. ...”

ParA_Bb subcellular localization and interaction with ParB_Bb. 由 Jovana Kaljević (17020971)

“...<i>crescentus</i> (grey), which spontaneously forms clusters at the cell poles or septa when produced in <i>E</i>. ...”

Halide Ion Addition to Bismuth-Containing Iron Carbonyl Compounds:  Synthesis and Characterization of the Two Bridged-Butterfly Cluster Compounds [Et₄N][(μ-H)Fe<sub>2</s... 由 Jeffrey R. Eveland (2970981)

“...At stoichiometries greater than 2:1, the previously reported [Fe(CO)₄Bi₂Cl₆]^2- ion is formed....”

Syntheses and Solid State Structures of Tris(pyrazolyl)methane Complexes of Sodium, Potassium, Calcium, and Strontium:  Comparison of Structures with Analogous Complexes of Lead(II... 由 Daniel L. Reger (1444537)

“...The complex {[HC(pz)₃]₂Sr}(BF₄)₂ (<b>4</b>) forms in the reaction of Sr(acac)₂ (acac = acetylacetonate) with HBF₄·Et₂O followed by 2 equiv of HC(pz)₃. ...”

Terrestrial Condition Assessment (TCA) Wildfire Hazard Potential - Moderate 由 U.S. Forest Service (17476914)

“...Higher values have a higher probability of high-intensity fire, with torching, crowning, and other forms of extreme fire behavior. Data used for this metric represent areas classified as “moderate”, “high”, or “very high” wildland hazard potential within fire regime groups I and II*. ...”

Sequential, prior, or simultaneous introduction of <i>S</i>. <i>aureus</i> during <i>L</i>. <i>major</i> infection. 由 Tiffany Y. Borbón (6714227)

“...(Right panel) Live Sa burdens were also measured by counting colony-forming units (CFUs) after overnight growth from ear homogenates. ...”

Nanosized {Pd₄(μ₄‑C)}Pd₃₂(CO)₂₈(PMe₃)₁₄ Containing Tetrahedrally Deformed Pd₄ Cage with Encapsulated Ca... 由 Evgueni G. Mednikov (2095618)

“...The isostructural stabilizations of <b>1</b> and <b>2</b> are then attributed to the similar sizes, shapes, and overall negative charge distributions of the electronically equivalent interior {Pd₄C} and Au₄ entities. This resulting remarkable structural/electronic equivalency between <b>1</b> and <b>2</b> is consistent with the greatly improved performances of commercial palladium catalysts for vinyl acetate synthesis by gold-atom incorporation to suppress carbonization of the Pd atoms, namely, that the extra Au 6s¹ valence electron of each added Au atom provides an effective “negative charge protection” against electron-donating carbon atoms forming Pd carbido species such as {Pd₄C}....”

Organisation of the human KIR cluster. 由 Caroline Besson (69818)

“...A 14 kb stretch of unique sequence separating <i>KIR3DP1</i> from <i>KIR2DL4</i> is the preferred site for reciprocal recombination, a mechanism resulting in the formation of new haplotypes by the reassortment of centromeric and telomeric genes. ...”

Mixed Chloride/Phosphine Complexes of the Dirhenium Core. 3. Novel Structures with Diethylphosphido-bridges and Terminal Diethylphosphines 由 F. Albert Cotton (1781341)

“...The interaction between octachlorodirhenium anions and diethylphosphine has been shown to strongly depend on reaction conditions, mainly the nature of the solvent and the amount of phosphine. As a result, novel dirhenium products with oxidation states ranging from Re^II to Re^IV have been obtained. ...”

First Actinide Complexes of the Nitrogen-Containing Ligands Dinitramide (N(NO₂)₂⁻), 4,5-Dicyano-1,2,3-triazolate (C₄N₅<sup>−<... 由 Margaret-Jane Crawford (2312314)

“...Complex <b>3</b> is the first structurally characterized actinide dicyanamide complex and a rare example of a dinuclear uranyl complex showing a 12 membered U−N−C ring formed by bridging dicyanamide ligands between two uranyl centers. ...”

First Actinide Complexes of the Nitrogen-Containing Ligands Dinitramide (N(NO₂)₂⁻), 4,5-Dicyano-1,2,3-triazolate (C₄N₅<sup>−<... 由 Margaret-Jane Crawford (2312314)

“...Complex <b>3</b> is the first structurally characterized actinide dicyanamide complex and a rare example of a dinuclear uranyl complex showing a 12 membered U−N−C ring formed by bridging dicyanamide ligands between two uranyl centers. ...”

Posttranslational modification of SipB analyzed by mass spectrometry and radiolabeling. 由 Julie P. Viala (3710800)

“...Bacterial two-hybrid assays between SicA and the variant forms of SipB were performed to control the uniformity of the interaction signal with other partners of SipB. ...”

Supplemental Movies Paulo Caldas PhD thesis 由 Paulo Caldas (7883579)

“...The architecture of these FtsZ/FstA co-filaments is typically characterized by dynamic networks of curved filament bundles, forming streams and vortexes. All the components were added to the reaction buffer (50mM Tris-HCl pH=7.5, 150mM KCl, 5mM MgCl2) prior to the addition of 4mM of GTP, which triggers FtsZ polymerization. ...”

Roseburia abundance associates with severity, evolution and outcome of acute ischemic stroke 由 Gu (9523070)

“...We also used BugBase to predict potential microbiome phenotypes, including aerobic, anaerobic, containing mobile elements, facultatively anaerobic, biofilm forming, gram-negative, gram-positive, potentially pathogenic, and stress tolerant....”

Home range and shelter use by Sonoran Desert Tortoises at 2 populations in Arizona 由 Roy Averill-Murray (19796661)

“...We use the term “burrow” specifically to refer to a subsurface cavity >1/2 the tortoise’s length either formed by erosion or excavated by a tortoise or another animal (Burge 1978). ...”

Bidentates versus Monodentates in Asymmetric Hydrogenation Catalysis: Synergic Effects on Rate and Allosteric Effects on Enantioselectivity 由 David W. Norman (2407405)

“...For the cinnamate and acrylate substrates studied, the catalysts derived from the phosphino/phosphonite bidentates <b>L_A,B</b> generally give superior enantioselectivities to the analogous diphosphonites <b>L_2a</b> and <b>L_2b</b>; these results are rationalized in terms of δ/λ-chelate conformations and allosteric effects of the substrates. ...”

Sulfur-Assisted Phenyl Migration from Phosphorus to Platinum in PtW₂ and PtMo₂ Clusters Containing Thioether-Functionalized Short-Bite Ligands of the Bis(diph... 由 Stefano Todisco (1584781)

“...Density functional calculations were performed to study the thermodynamics of the formation of all the new complexes, to evaluate the relative stabilities of the isomeric chelated and bridged forms, and to trace the mechanism of formation of the phosphanido-bridged products <b>3</b>, <b>4</b>, <b>9</b>, and <b>10</b>. ...”