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28081
[Mn<sub>12</sub>O<sub>12</sub>(OMe)<sub>2</sub>(O<sub>2</sub>CPh)<sub>16</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2-</sup> Single-Molecule Magnets and Other Manganese Compounds from...
Pubblicazione 2005“...A new synthetic procedure has been developed in Mn cluster chemistry involving reductive aggregation of permanganate (MnO<sub>4</sub><sup>-</sup>) ions in MeOH in the presence of benzoic acid, and the first products from its use are described. ...”
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28082
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Pubblicazione 2015“...Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. ...”
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28083
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Pubblicazione 2015“...Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. ...”
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28084
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Pubblicazione 2015“...Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. ...”
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28085
E00144: Coptic Stories of the Monks of the Desert, attributed in the text to Paphnouthios, possibly Paphnouthios of Scetis, 4th c., which describe the lives and miracles of two bis...
Pubblicazione 2014“...<br> <br>The second part (fol. 11b–37a) forms a history of the Bishops of Philae, from the see’s foundation to the death of bishop *Pseleusias (who is different from the monk Pseleusius). ...”
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28086
Creative methods and practices to mobilising public health knowledge webinar
Pubblicazione 2025“...</p><p dir="ltr">In the field of public health, mobilising evidence and other forms of knowledge is essential to developing effective, equitable, and sustainable interventions. ...”
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28087
Stereoselectivity in the Formation of Metallomacrocycles from [Mo(NO){HB(3,5-Me<sub>2</sub>C<sub>3</sub>HN<sub>2</sub>)<sub>3</sub>}I<sub>2</sub>] and Ditopic Proligands: The X-ra...
Pubblicazione 1999“...These binuclear complexes are formed under kinetic control so that <i>syn</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2s</b>, forms more rapidly than <i>anti</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2a</b>, but in lower yield. ...”
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28088
Mixed-Metal Cluster Chemistry. 30. Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes
Pubblicazione 2007“...Some insight into the mechanism by which these clusters function as optical limiters has been gleaned from complementary pump−probe studies, with their behavior consistent with a fast nonlinear absorption process followed by reverse saturable absorption involving metastable excited states of greater than nanosecond lifetime....”
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28089
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
Pubblicazione 1997“...The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. ...”
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28090
Eh!woza Learner Doccies
Pubblicazione 2023“...</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. ...”
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28091
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Pubblicazione 2020“...The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product....”
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28092
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Pubblicazione 2025“...Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. ...”
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28093
17- and 19-Electron Complexes [Fe<sup>III</sup>(η<sup>5</sup>-C<sub>5</sub>R<sub>5</sub>)(S<sub>2</sub>CNMe<sub>2</sub>)L]<sup><i>n</i>+</sup> (<i>n</i> = 1, 0): Electronic Struct...
Pubblicazione 1996“...The cyclic voltammogram of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b><sup>+/<b>0</b>/-</sup>, <b>9‘</b><sup>+/<b>0</b>/-</sup>, and solvent (DMF) adducts in 18- and 19e states....”