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28081
[Mn<sub>12</sub>O<sub>12</sub>(OMe)<sub>2</sub>(O<sub>2</sub>CPh)<sub>16</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2-</sup> Single-Molecule Magnets and Other Manganese Compounds from...
Հրապարակվել է 2005“…A new synthetic procedure has been developed in Mn cluster chemistry involving reductive aggregation of permanganate (MnO<sub>4</sub><sup>-</sup>) ions in MeOH in the presence of benzoic acid, and the first products from its use are described. …”
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28082
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Հրապարակվել է 2015“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
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28083
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Հրապարակվել է 2015“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
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28084
New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis
Հրապարակվել է 2015“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b><sub><b>2</b></sub><b>(OH)(OH</b><sub><b>2</b></sub><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru<sup>III</sup>–OH:Ru<sup>III</sup>–OH state species as a resting state. …”
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28085
E00144: Coptic Stories of the Monks of the Desert, attributed in the text to Paphnouthios, possibly Paphnouthios of Scetis, 4th c., which describe the lives and miracles of two bis...
Հրապարակվել է 2014“…<br> <br>The second part (fol. 11b–37a) forms a history of the Bishops of Philae, from the see’s foundation to the death of bishop *Pseleusias (who is different from the monk Pseleusius). …”
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28086
Creative methods and practices to mobilising public health knowledge webinar
Հրապարակվել է 2025“…</p><p dir="ltr">In the field of public health, mobilising evidence and other forms of knowledge is essential to developing effective, equitable, and sustainable interventions. …”
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28087
Stereoselectivity in the Formation of Metallomacrocycles from [Mo(NO){HB(3,5-Me<sub>2</sub>C<sub>3</sub>HN<sub>2</sub>)<sub>3</sub>}I<sub>2</sub>] and Ditopic Proligands: The X-ra...
Հրապարակվել է 1999“…These binuclear complexes are formed under kinetic control so that <i>syn</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2s</b>, forms more rapidly than <i>anti</i>-[Mo(NO)(tp*){1,4-(OCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>}]<sub>2</sub>, <b>2a</b>, but in lower yield. …”
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28088
Mixed-Metal Cluster Chemistry. 30. Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes
Հրապարակվել է 2007“…Some insight into the mechanism by which these clusters function as optical limiters has been gleaned from complementary pump−probe studies, with their behavior consistent with a fast nonlinear absorption process followed by reverse saturable absorption involving metastable excited states of greater than nanosecond lifetime.…”
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28089
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
Հրապարակվել է 1997“…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”
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28090
Eh!woza Learner Doccies
Հրապարակվել է 2023“…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”
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28091
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Հրապարակվել է 2020“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product.…”
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28092
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Հրապարակվել է 2025“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”
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28093
17- and 19-Electron Complexes [Fe<sup>III</sup>(η<sup>5</sup>-C<sub>5</sub>R<sub>5</sub>)(S<sub>2</sub>CNMe<sub>2</sub>)L]<sup><i>n</i>+</sup> (<i>n</i> = 1, 0): Electronic Struct...
Հրապարակվել է 1996“…The cyclic voltammogram of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b><sup>+/<b>0</b>/-</sup>, <b>9‘</b><sup>+/<b>0</b>/-</sup>, and solvent (DMF) adducts in 18- and 19e states.…”